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1. 发明申请

WO2005083378A2 SHIELD FOR USE IN DEHYDROGENATION REACTORS 审中-公开
标题翻译：用于脱氢反应器的屏蔽
公开(公告)号：WO2005083378A2
公开(公告)日：2005-09-09
申请号：PCT/GB2005/000755
申请日：2005-02-28
申请人： BOREALIS AS , JACKSON, Robert , ROTERUD, Per , JENS, Klaus, J. , ARNESEN, Tore , EDWIN, Emil
发明人： ROTERUD, Per , JENS, Klaus, J. , ARNESEN, Tore , EDWIN, Emil
IPC分类号： G01K1/00
CPC分类号： B01J8/025 , B01J2208/00061 , G01K1/10 , G01K1/12
摘要： A protective device, such as a thermowell, in which at least a thick exterior portion is made of an aluminium containing stainless steel alloy. Some of the aluminium within the alloy reacts with oxygen to form a thin layer of aluminium oxide on the exterior of the shield. This layer provides protection against the extreme heat found within the catalyst. The portion of aluminium containing alloy is sufficiently thick that after formation of the aluminium oxide layer a quantity of unreacted aluminium is left in the thermowell which allows the layer to be self healing if scratched. In addition the layer is thin enough to allow an thermocouple positioned within the shield to give an accurate indication of the temperature in the reactor.
摘要翻译：一种保护装置，例如热套管，其中至少厚的外部部分由含铝的不锈钢合金制成。合金中的一些铝与氧气反应，在屏蔽外部形成一层薄薄的氧化铝。该层提供了防止催化剂内发现的极端热量的保护。含铝合金的部分足够厚，在形成氧化铝层之后，一定量的未反应的铝留在热电偶套管中，这允许该层在被划伤时自愈。此外，该层足够薄以允许位于屏蔽内的热电偶准确地指示反应器中的温度。

2. 发明申请

WO0047638A3 AN alpha -OLEFIN POLYMERIZATION CATALYST SYSTEM AND ITS USE FOR THE POLYMERIZATION OF alpha -OLEFINS 审中-公开
标题翻译：一种α-烯烃聚合催化剂体系及其在α-烯烃聚合中的应用
公开(公告)号：WO0047638A3
公开(公告)日：2000-12-07
申请号：PCT/FI0000098
申请日：2000-02-11
申请人： BOREALIS AS , ALASTALO KAUNO , LESKINEN PAULI
发明人： ALASTALO KAUNO , LESKINEN PAULI
IPC分类号： C08F4/655 , C08F4/44 , C08F4/657 , C08F10/00
CPC分类号： C08F10/00 , C08F2/44 , C08F4/6492 , C08F4/6491
摘要： In the invention, a catalyst system for the polymerization of alpha -olefins has been prepared by a process including a catalyst activation comprising the contacting of a solid transition metal compound with an organoaluminium compound, and a catalyst prepolymerization comprising the polymerization of a premonomer in the presence of the activated catalyst. High activity, low fines polymerization is accomplished if the catalyst activation comprises a first step of contacting the solid transition metal compound with a first organoaluminium compound in the presence of an oil to give a first reaction mixture, and a second step of contacting the first reaction mixture with a second organoaluminium compound to give a second reaction mixture, the second organoaluminium compound being the same as or different from the first organoaluminium compound.
摘要翻译：在本发明中，已经通过包括催化剂活化的方法制备用于α-烯烃聚合的催化剂体系，该方法包括使固体过渡金属化合物与有机铝化合物接触，以及催化剂预聚合，该催化剂预聚合包括在活化催化剂的存在。如果催化剂活化包括在油存在下使固体过渡金属化合物与第一有机铝化合物接触以得到第一反应混合物的第一步骤，以及使第一反应接触第二步骤的第二步骤，则实现高活性，低细粒聚合与第二有机铝化合物混合以得到第二反应混合物，第二有机铝化合物与第一有机铝化合物相同或不同。

3. 发明申请

WO0047637A3 A MULTI-STAGE PROCESS FOR THE PREPARATION OF alpha -OLEFIN POLYMERS HAVING CONTROLLED STEREOREGULARITY AND PRODUCTS PREPARED THEREOF 审中-公开
标题翻译：用于制备具有可控立体异构性的α-烯烃聚合物的多阶段方法及其制备的产品
公开(公告)号：WO0047637A3
公开(公告)日：2000-12-07
申请号：PCT/FI0000097
申请日：2000-02-11
申请人： BOREALIS AS , HUOVINEN PAEIVI , LESKINEN PAULI , GAROFF THOMAS
发明人： HUOVINEN PAEIVI , LESKINEN PAULI , GAROFF THOMAS
IPC分类号： C08J5/00 , C08F2/00 , C08F4/44 , C08F4/64 , C08F4/657 , C08F10/00 , C08F10/06 , C08F110/06 , C08F297/06
CPC分类号： C08F10/06 , C08F10/00 , C08F110/06 , C08F4/642 , C08F4/6465 , C08F4/6492 , C08F2/001 , C08F2500/12
摘要： The invention relates to the preparation of an alpha -olefin polymer product having controlled stereoregularity, comprising the successive steps of: (i) producing a first polymerization product by contacting under polymerization conditions an alpha -olefin monomer with a polymerization catalyst system comprising a transition metal compound, a first organometal compound and a stereoregulating external electron donor to give a first polymerization reaction mixture; (ii) producing a second polymerization product by contacting additional alpha -olefin monomer with the first polymerization reaction mixture. The controlled stereoregularity is achieved in such a way that in step (ii) the second polymerization product is produced in the presence of a stereoregularity controlling agent. The stereoregularity controlling agent is e.g. a second organometal compound which contains, on an atom basis, more halogen per metal than the first organometal compound, and/or 0.01-1.2 % of an olefin which is not said alpha -olefin monomer, calculated on the total molar amount of olefin and alpha -olefin monomer.
摘要翻译：本发明涉及具有受控立构规整性的α-烯烃聚合物产物的制备，该方法包括以下连续步骤：（i）通过在聚合条件下使α-烯烃单体与包含过渡金属的聚合催化剂体系接触来制备第一聚合产物化合物，第一有机金属化合物和立体调节外部电子给体以得到第一聚合反应混合物; （ii）通过使另外的α-烯烃单体与第一聚合反应混合物接触来生产第二聚合产物。以步骤（ii）中的第二聚合产物在有规立构性控制剂存在下制备的方式获得受控的有规立构性。立构规整性控制剂是例如第二种有机金属化合物，其每个金属原子上含有比第一种有机金属化合物更多的卤素，和/或0.01-1.2％不是所述α-烯烃单体的烯烃，以烯烃的总摩尔量计，和 α-烯烃单体。

4. 发明申请

WO0047636A3 A MULTI-STAGE PROCESS FOR THE PREPARATION OF A HIGHLY STEREOREGULAR AND MELT PROCESSABLE alpha -OLEFIN POLYMER PRODUCT 审中-公开
标题翻译：一种用于制备高度立体和可熔融加工的α-烯烃聚合物产品的多阶段方法
公开(公告)号：WO0047636A3
公开(公告)日：2000-11-30
申请号：PCT/FI0000096
申请日：2000-02-11
申请人： BOREALIS AS , GAROFF THOMAS , LESKINEN PAULI
发明人： GAROFF THOMAS , LESKINEN PAULI
IPC分类号： C08F4/657 , C08F10/00 , C08F10/06 , C08F110/06 , C08F210/06 , C08F297/08 , C08L23/12 , C08L23/14 , C08F4/44
CPC分类号： C08F10/00 , C08F10/06 , C08F110/06 , C08F210/06 , C08F297/08 , C08F297/083 , C08L23/12 , C08L23/142 , C08L2207/02 , C08L2308/00 , Y02P20/52 , C08F4/642 , C08F2/00 , C08L2666/04 , C08F2500/12 , C08F2500/04 , C08F210/16 , C08F2500/18 , C08F2500/17 , C08F2500/03
摘要： The invention relates to a process for the preparation of a highly stereoregular and melt processable alpha -olefin polymer product. The product is obtained by (i) producing a low melt flow rate polymerization product by contacting an alpha -olefin under polymerization conditions with a first high activity polymerization catalyst system comprising a transition metal compound, a first organometal compound and a stereoregulating external electron donor, and little or no hydrogen termination agent; (ii) producing in one or more steps a high melt flow rate polymerization product by contacting an alpha -olefin under polymerization conditions with a second high activity polymerization catalyst system comprising a transition metal compound, a second organometal compound and a stereoregulating external electron donor, and a hydrogen termination agent; and (iii) integrating or combining the low and high melt flow rate polymerization products. A surprisingly good yield of the high melt flow rate polymerization product is achieved if the second organometal compound contains, on an atom basis, more halogen per metal than the first organometal compound.
摘要翻译：本发明涉及制备高度有规立构和可熔融加工的α-烯烃聚合物产品的方法。（i）通过在聚合条件下使α-烯烃与包含过渡金属化合物，第一有机金属化合物和有规立构外给电子体的第一高活性聚合催化剂体系接触，生产低熔体流动速率聚合产物，少量或不含氢终止剂; （ii）通过在聚合条件下使α-烯烃与包含过渡金属化合物，第二有机金属化合物和立体调节外部电子给体的第二高活性聚合催化剂体系接触，在一个或多个步骤中生产高熔体流动速率聚合产物，和氢终止剂; 和（iii）整合或组合低熔体流动速率聚合产物和高熔体流动速率聚合产物。如果第二有机金属化合物在原子基础上比第一有机金属化合物每个金属含有更多的卤素，则实现了高熔体流动速率聚合产物的令人惊讶的良好收率。

5. 发明申请

WO9965949A2 OLEFIN POLYMERIZATION PROCESS 审中-公开
标题翻译： OLEFIN聚合方法
公开(公告)号：WO9965949A2
公开(公告)日：1999-12-23
申请号：PCT/GB9901916
申请日：1999-06-16
申请人： BOREALIS AS , COCKBAIN JULIAN , FOLLESTAD ARILD , SALMINEN HANNU
发明人： FOLLESTAD ARILD , SALMINEN HANNU
IPC分类号： C08F2/34 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F210/16 , C08F
CPC分类号： C08F10/00 , C08F4/65904 , C08F4/65912 , C08F4/65925 , C08F210/16 , Y02P20/582 , Y10S526/901 , Y10S526/905 , Y10S526/943 , C08F2/001 , C08F4/65916 , C08F2/38 , C08F210/14 , C08F2500/12
摘要： A process for olefin polymerization comprising polymerising at least one alpha -olefin in a continuous reactor in the presence of hydrogen and an olefin polymerization catalyst the hydrogen consumption rate being controlled during the polymerization whereby to control the molecular weight of the polymer product.
摘要翻译：一种用于烯烃聚合的方法，其包括在氢气和烯烃聚合催化剂的存在下在连续反应器中聚合至少一种α-烯烃，在聚合期间控制氢消耗速率，从而控制聚合物产物的分子量。

6. 发明申请

WO0047639A3 A PROCESS FOR PREPARING A HYDROGEN SENSITIVE alpha -OLEFIN POLYMERIZATION CATALYST SYSTEM, A POLYMERIZATION CATALYST SYSTEM PREPARED BY THE PROCESS AND ITS USE FOR THE POLYMERIZATION OF alpha -OLEFINS 审中-公开
标题翻译：一种制备氢敏敏α-烯烃聚合催化剂体系的方法，该方法制备的聚合催化剂体系及其用于α-烯烃聚合的方法
公开(公告)号：WO0047639A3
公开(公告)日：2000-12-14
申请号：PCT/FI0000099
申请日：2000-02-11
申请人： BOREALIS AS , GAROFF THOMAS , LESKINEN PAULI , VESTBERG TORVALD
发明人： GAROFF THOMAS , LESKINEN PAULI , VESTBERG TORVALD
IPC分类号： C08F4/654 , C08F10/00 , C08F110/06 , C08F4/646
CPC分类号： C08F10/00 , C08F110/06 , C08F4/6465 , C08F4/651 , C08F4/6543 , C08F2500/12 , C08F2500/15
摘要： In the invention, improved isotacticity and melt processability of poly- alpha -olefins have been achieved by means of a novel polymerization and a catalyst system therefor. The catalyst system has been prepared by a process in which magnesium dichloride or a complex thereof, titanium tetrachloride, and internal donor, a first organoaluminium compound, and an external donor are contacted to form a contacting product. The contacting product is then contacted with a second organoaluminium compound which, on an atom basis, contains more halogen per aluminium than the first organoaluminium compound.
摘要翻译：在本发明中，聚-α-烯烃的改进的全同立构规整度和熔融加工性已经通过新的聚合和催化剂体系来实现。催化剂体系已经通过二氯化镁或其配合物，四氯化钛和内部供体，第一有机铝化合物和外部供体接触以形成接触产物的方法制备。然后使接触产物与第二有机铝化合物接触，第二有机铝化合物在原子基础上含有比第一有机铝化合物更多的卤素/铝。

7. 发明申请

WO0034341A2 PROCESS 审中-公开
标题翻译：处理
公开(公告)号：WO0034341A2
公开(公告)日：2000-06-15
申请号：PCT/GB9904124
申请日：1999-12-07
申请人： BOREALIS AS , PEROXID CHEMIE GMBH , COCKBAIN JULIAN , ANDELL OVE , KALLIO KALLE , KNUUTTILA HILKKA
发明人： ANDELL OVE , KALLIO KALLE , KNUUTTILA HILKKA
IPC分类号： C08F4/64 , C08F4/642 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F10/02 , C08F110/02 , C08F210/16
CPC分类号： C08F10/02 , C08F4/65912 , C08F4/65916 , C08F4/6592 , C08F110/02 , C08F210/16 , Y10S526/943 , C08F4/65927 , C08F4/65925 , C08F2500/03 , C08F2500/18 , C08F210/14 , C08F2500/12
摘要： Olefin polymerisation may be catalysed by a wide range of catalytic materials. Described herein is a heterogeneous olefin polymerization catalyst comprising a porous particulate support material having impregnated therein a metallocene catalyst the metal atom whereof is bound to an amide group which is not bound to an eta -ligand of the metallocene, or the reaction product of a said metallocene catalyst and a co-catalyst.
摘要翻译：烯烃聚合可以由各种催化材料催化。本文描述的是一种非均相烯烃聚合催化剂，其包含多孔颗粒载体材料，其中浸渍有茂金属催化剂，其金属原子结合到不与金属茂的等离子体结合的酰胺基或所述茂金属催化剂的反应产物茂金属催化剂和助催化剂。

8. 发明申请

WO2004113072A1 FOOD PACKAGING 审中-公开
标题翻译：食品包装
公开(公告)号：WO2004113072A1
公开(公告)日：2004-12-29
申请号：PCT/GB2004/002611
申请日：2004-06-18
申请人： BOREALIS AS , TOMMEN GRAM HOLDING AS , KVAMME, Lars, Inge , MULLER, Finn, Robert
发明人： KVAMME, Lars, Inge , MULLER, Finn, Robert
IPC分类号： B32B27/32
CPC分类号： B32B27/08 , B32B27/32 , B32B2323/043 , B32B2323/10 , B32B2439/70
摘要： The use of a polyolefin film comprising a polypropylene polymer and a polyethylene polymer for the packaging of fresh produce.
摘要翻译：使用包含聚丙烯聚合物和聚乙烯聚合物的聚烯烃膜用于新鲜农产品的包装。

9. 发明申请

WO0050170A3 A NEW TRANSITION METAL COMPLEX, ITS PREPARATION AS WELL AS A CATALYST SYSTEM BASED THEREUPON AND ITS USE FOR THE POLYMERIZATION OF OLEFINS 审中-公开
标题翻译：一种全新的过渡金属络合物，其制备方法也是基于催化剂体系的基础及其用于烯烃聚合反应
公开(公告)号：WO0050170A3
公开(公告)日：2000-12-07
申请号：PCT/FI0000136
申请日：2000-02-22
申请人： BOREALIS AS , ANDELL OVE , MAARANEN JANNE , KETOLA LASSE
发明人： ANDELL OVE , MAARANEN JANNE , KETOLA LASSE
IPC分类号： B01J31/18 , C07F7/00 , C07F11/00 , C08F10/00 , C07D487/18 , C08F4/602
CPC分类号： B01J31/182 , B01J31/1805 , B01J2531/46 , B01J2531/48 , B01J2531/62 , B01J2531/842 , C07F7/006 , C07F11/005 , C08F10/00 , C08F110/02 , C08F210/16 , C08F4/64089 , C08F4/69224
摘要： The invention relates to new triaza transition metal complexes and their use as polymerization catalysts. They have the formula (1): LnMXm-n, wherein each L is independently a ligand which is multidentate by adjacent cooordinating atoms, M is the central atom which is a metal selected from Groups 4-8 of the Periodic Table of the Elements (IUPAC 1990), each X is independently a unidentate organic or halogen ligand, m is the coordination number or number of coordination sites on the central atom M, and n is the number of the ligands L which is an integer from 1 to m. At least one of the ligands L has formula (2), wherein each of R1-R6 is independently selected from hydrogen and organic groups having from 1 to 10 carbon atoms and the ligand L is coordinated to the central atom M by one to four of the three nitrogen atoms and/or the carbon atom of the ligand L according to formula (2).
摘要翻译：本发明涉及新的三氮杂过渡金属络合物及其作为聚合催化剂的用途。它们具有式（1）：LnMXm-n，其中每个L独立地是由相邻共配原子多齿的配体，M是选自元素周期表第4-8族的金属的中心原子（ IUPAC 1990），每个X独立地是单齿有机或卤素配体，m是中心原子M上的配位点的配位数或数目，n是1至m的整数的配体L的数目。配体L中的至少一个具有式（2），其中R 1 -R 6各自独立地选自氢和具有1至10个碳原子的有机基团，并且配体L与中心原子M配位1至4个根据式（2）的配体L的三个氮原子和/或碳原子。

10. 发明申请

WO9940126A9 A CATALYST FOR THE (CO)POLYMERISATION OF ETHYLENE AND A METHOD FOR THE PREPARATION THEREOF 审中-公开
标题翻译：乙烯（共）聚合催化剂及其制备方法
公开(公告)号：WO9940126A9
公开(公告)日：1999-10-21
申请号：PCT/NO9900043
申请日：1999-02-09
申请人： BOREALIS AS , FOLLESTAD ARILD , ALMQUIST VIDAR , PALMQVIST ULF , HOKKANEN HARRI
发明人： FOLLESTAD ARILD , ALMQUIST VIDAR , PALMQVIST ULF , HOKKANEN HARRI
IPC分类号： C08F4/639 , C08F4/6392 , C08F4/659 , C08F4/6592 , C08F4/69 , C08F10/00 , C08F10/02 , C08F110/02 , C08F210/16
CPC分类号： C08F10/00 , C08F4/63912 , C08F4/63916 , C08F4/63925 , C08F4/65912 , C08F4/65925 , C08F10/02 , C08F110/02 , C08F210/16 , C08F4/63904 , C08F4/24 , C08F2500/12 , C08F2500/17 , C08F2500/07 , C08F210/14 , C08F2500/02
摘要： A particulate, modified chromium oxide catalyst for the polymerisation of ethylene or ethylene with alpha -olefins, comprising: a) a chromium-oxide catalyst, b) a transition metal compound, and c) a catalyst activator. A method for the preparation of the catalyst comprises the steps of: a) subjecting a chromium oxide catalyst precursor, which comprises a chromium oxide compound combined with an inorganic support, to a temperature in the range of from 400 to 950 DEG C under oxidising conditions, and b) impregnating the obtained chromium catalyst with a catalyst activator and with a transition metal compound which comprises at least one cyclopentadienylic ring bonded to said transition metal and at least ligand selected from the group comprising alkoxy, amido and hydrocarbyl radicals, halogen and hybride bonded to said transition metal, which cyclopentadienylic ring may contain hetero atoms, be unsubstituted or substituted, be bonded to said transition metal through a bridge, and optionally annealed to other substituted or unsubstituted ring structures, and if two cyclopentadienyl rings are present they may be bonded to each other through a bridge, and c) subjecting the thus obtained particulate catalyst to drying conditions. This catalyst is suitable for producing polyethylenes under conditions of continuous feeding of all reactants.
摘要翻译：一种用于乙烯或乙烯与α-烯烃聚合的微粒改性氧化铬催化剂，包括：a）氧化铬催化剂，b）过渡金属化合物，和c）催化剂活化剂。用于制备催化剂的方法包括以下步骤：a）在氧化条件下，使包含与无机载体结合的氧化铬化合物的氧化铬催化剂前体的温度在400-950℃的范围内，和b）用催化剂活化剂和过渡金属化合物浸渍得到的铬催化剂，所述过渡金属化合物包含至少一个与所述过渡金属键合的环戊二烯基环和至少选自烷氧基，酰氨基和烃基的配体，卤素和混合基键合到所述过渡金属上，该环戊二烯基环可以含有杂原子，未被取代或被取代，通过桥键与所述过渡金属键合，并且任选地与其它取代或未取代的环结构退火，并且如果存在两个环戊二烯基环，它们可以是通过桥键相互键合，以及c）对由此获得的颗粒进行催化 st至干燥条件。该催化剂适用于在连续加入所有反应物的条件下生产聚乙烯。

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