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61. 发明申请

WO01021573A1 PROCESS FOR TERMINAL CHLORINATION OF FLUORINATED COMPOUNDS 审中-公开
标题翻译：氟化合物的终端氯化方法
公开(公告)号：WO01021573A1
公开(公告)日：2001-03-29
申请号：PCT/JP2000/006371
申请日：2000-09-19
IPC分类号： C07B39/00 , C07C17/20 , C07C43/17 , C07C67/307 , C07C69/708 , C07C67/287 , C07C19/10 , C07C41/22 , C07C43/12 , C07C43/13
CPC分类号： C07C69/708 , C07B39/00 , C07C17/204 , C07C43/17 , C07C67/307
摘要： A process for terminal chlorination of fluorinated compounds which enables easy and relatively inexpensive preparation of fluorinated monomers having cyano or other functional groups. This process is characterized by reacting a fluorinated organic compound having an iodine atom at the molecular end as represented by general formula (I) RfCX2I (wherein Rf is a fluorinated organic group; and X is hydrogen or chloro) with chlorine gas at 150 to 180 DEG C under irradiation with light to thereby replace the iodine atom by a chlorine atom through cleavage of the C-I bond.
摘要翻译：用于氟化化合物的末端氯化的方法，其使得能够容易且相对便宜地制备具有氰基或其它官能团的氟化单体。该方法的特征在于：使通式（I）所示的具有碘原子的氟化有机化合物，其中RfCX2I（其中Rf是氟化有机基团，X是氢或氯）与氯气在150至180℃ 在光照射下，通过Cl键的切割，用氯原子代替碘原子。

62. 发明申请

WO00006610A2 POLYMER PRODUCTION 审中-公开
标题翻译：聚合物生产
公开(公告)号：WO00006610A2
公开(公告)日：2000-02-10
申请号：PCT/GB1999/002448
申请日：1999-07-26
IPC分类号： C07C69/50 , C07C69/347 , C07C69/54 , C07C69/708 , C07C211/21 , C07C211/62 , C07C211/63 , C07C215/08 , C07C215/40 , C07C215/90 , C07C233/05 , C07C233/09 , C07C233/11 , C07C233/56 , C07C235/08 , C07C235/46 , C07C237/06 , C07C255/19 , C07C271/12 , C07C311/03 , C07F7/18 , C08F20060101 , C08F2/46 , C08F26/02 , C08F26/04 , C08F36/20 , C08F126/00 , C08F
CPC分类号： C07C69/50 , C07C69/54 , C07C69/708 , C07C211/21 , C07C215/10 , C07C233/05 , C07C233/09 , C07C233/11 , C07C233/65 , C07C235/06 , C07C235/46 , C07C237/06 , C08F26/02 , C08F26/04 , C08F283/00 , C08F283/04
摘要： A method for producing a polymeric material, said method comprising subjecting a starting material which includes two multiple bonds which are activated so that they will take part in a polymerisation reaction and wherein the multiple bonds are sufficiently close togeter to ensure that cyclopolymerisation will preferentially occur; to suitable conditions under which said polymerisation reaction will occur, provided that the starting marerial is other than triallyamine hydrochloride. The method can be used to produce polymers for various processes including adhesives, network polymers, liquid crystal polymers etc.
摘要翻译：一种制备聚合材料的方法，所述方法包括使包含两个多重键的起始材料进行活化，以使它们参与聚合反应，并且其中多个键足够接近以确保优先发生环聚合; 到达发生所述聚合反应的合适条件，条件是起始母体不同于盐酸三烯丙胺。该方法可用于生产各种工艺的聚合物，包括粘合剂，网状聚合物，液晶聚合物等。

63. 发明申请

WO00006533A2 MONOMERS AND NETWORK POLYMERS OBTAINED THEREFROM 审中-公开
标题翻译：由所述单体获得的单体和高分子聚合物
公开(公告)号：WO00006533A2
公开(公告)日：2000-02-10
申请号：PCT/GB1999/002416
申请日：1999-07-26
IPC分类号： C07D341/00 , C07C69/007 , C07C69/347 , C07C69/50 , C07C69/708 , C07C211/09 , C07C211/21 , C07C211/63 , C07C217/08 , C07C229/20 , C07C233/05 , C07C233/06 , C07C233/09 , C07C233/18 , C07C233/36 , C07C233/89 , C07C235/06 , C07C239/06 , C07C271/20 , C07C275/20 , C07D487/22 , C07F7/10 , C08F2/38 , C08F2/46 , C08F36/22 , C08F38/00 , C08F246/00 , C08F290/06 , C09D4/00 , C07C235/00
CPC分类号： C08F246/00 , C07C69/007 , C07C69/50 , C07C69/708 , C07C211/21 , C07C233/05 , C07C233/09 , C07C233/18 , C07C233/36 , C07C239/06 , C07C271/20 , C07C275/20 , C07C2601/14 , C08F2/38 , C09D4/00 , C08F226/02
摘要： A compound of formula (I) where R is CH and R is a bond, or R and R together form an electron withdrawing group; R and R are independently selected from (CR R )n, or a group CR R , -(CR R CR R )- or -(CR R CR R )- where n is 0,1 or 2, R and R are independently selected from hydrogen or alkyl, and either one of R or R is hydrogen and the other is an electron withdrawing group, or R and R together form an electron withdrawing group, and R and R are independently selected from CH or CR where R is an electron withdrawing group; the dotted lines indicate the presence or absence of a bond, and X is a group CX X where the dotted line bond to which it is attached is absent and a group CX where the dotted line bond to which it is attached is present, Y is a group CY Y where the dotted line bond to which it is attached is absent and a group CY where the dotted line bond to which it is attached is present, and X , X , Y and Y are independently selected from hydrogen and fluorine; R is a bridging group of valency r and r is an integer of 2 or more, subject to the following provisos: (i) that at least one of (a) R and R or (b) R and R or (c) R and R includes an electron withdrawing group. These compounds are useful in the production of network polymers, for example for coatings or binders.
摘要翻译：本发明涉及式（I）的化合物，其中R 1是CH并且R 6是键，或者R 1和R 6一起形成电子受体基团; [R <2>和R <3>独立地选自（CR <7> - [R <8>）n或一个CR <9>基团R中选择<10>， - （CR <7> - [R <8 > CR <9> - [R <10>） - 或 - （CR <9> - [R <10> CR <7> - [R <8>） - （其中n是0,1或2，R <7>和R <8> 独立地选自氢或烷基，并且R 9和R 10无差别地为一个氢，另一个为电子受体基团或一起形成电子受体基团）。并且R 4和R 5独立地选自CH或CR 11，其中R 11是电子受体基团; 虚线表示链接的存在或不存在，并且X 1是基团CX 2 X 3，其中它所连接的虚线链接不存在且CX <基团 2>，其中存在其所连接的虚线键，Y 1是基团CY 2 Y 3，其中它所连接的虚线键不存在并且基团CY 其中存在其所连接的虚线键，并且X 2，X 3，Y 2和Y 3独立地选自氢和氟; R 16是价键r和r是等于至少2的整数的桥基，条件是至少a）R 1和R 6，或b）R 2和 R 3或c）R 4和R 5包括电子受体基团。这些化合物可用于生产用于例如涂料或粘合剂中的交联聚合物。

64. 发明申请

WO98054120A1 OLIGOMERS OF FATTY ACIDS 审中-公开
标题翻译：脂肪酸的低聚物
公开(公告)号：WO98054120A1
公开(公告)日：1998-12-03
申请号：PCT/EP1998/002900
申请日：1998-05-16
IPC分类号： C07C59/305 , C07C69/708
CPC分类号： C07C69/708 , C07C59/305
摘要： The present invention relates to compositions comprising a compound of formula (A), wherein R , R , m, n, p and q have the meanings given in the description, and k is a number between 1 and 3, provided that the total number of carbon atoms in the compound of formula (A) is between 12(k+1) and 22(k+1). When k is 1, the composition comprises at least 35 %, preferably at least 60 %, or even 90 % of the compound of formula (A), whereas when k is > 1, it comprises at least 15 %, preferably at least 30 %, or even 45 % of said compound. Also disclosed are a process for the preparation of said compositions as well as their use as building blocks in subsequent further processing for use for polymers, paints, inks, etc.
摘要翻译：本发明涉及包含式（A）化合物的组合物，其中R 1，R 2，m，n，p和q具有在说明书中给出的含义，并且k是1和3之间的数字条件是式（A）化合物中的碳原子总数在12（k + 1）和22（k + 1）之间。当k为1时，组合物包含至少35％，优选至少60％，甚至90％的式（A）化合物，而当k> 1时，其包含至少15％，优选至少30 ％，甚至45％的所述化合物。还公开了制备所述组合物的方法以及它们作为后续进一步加工中用作聚合物，油漆，油墨等的结构单元的用途。

65. 发明申请

WO98047844A1 SINGLE-STAGE METHOD FOR PRODUCING alpha -HYDROXY ETHERS BY OXIDIZING C=C-UNSATURATED COMPOUNDS WITH HYDROPEROXIDES 审中-公开
标题翻译：单级方法用于生产α-羟基醚氧化制备C = C与氢过氧化物的不饱和化合物
公开(公告)号：WO98047844A1
公开(公告)日：1998-10-29
申请号：PCT/EP1998/001632
申请日：1998-03-20
IPC分类号： C07C43/13 , C07B61/00 , C07C41/01 , C07C41/03 , C07C41/05 , C07C67/31 , C07C69/708 , C07C303/24 , C07C305/10 , C07F9/09 , C07C41/04
CPC分类号： C07C303/24 , C07C41/05 , C07C67/31 , C07C2601/14 , C07F9/091 , C07C69/708 , C07C305/10 , C07C41/03 , C07C43/13 , C07C43/196 , C07C43/137 , C07C43/11
摘要： The invention relates to a single-stage method for producing alpha -hydroxy ethers corresponding to formulae (I) and (II), by oxidizing olefinic substrates with organic hydroperoxides and opening the resulting oxirane ring by means of monovalent or polyvalent alcohols. Molybdenum compounds in combination with boron trifluoride or aluminum oxide or 1.8-diazabicyclo-[5.4.0]-undec-7-ene or 1.4-diazabicyclo-[2.2.2]-octane can be used as a catalyst system.
摘要翻译：本发明涉及一种用于α--Hydroxyethern的制备一个步骤过程中，对应于式（I）和（II）中，通过一元或多元醇，所述催化剂体系的钼化合物与有机氢过氧化物并将得到的环氧乙烷环的开烯烃底材的氧化与三氟化硼或氧化铝或1,8-二氮杂双环[5.4.0]十一碳-7-烯或1,4-二氮杂双环组合可用于[2.2.2]辛烷。

66. 发明申请

WO1998000388A1 2-SUBSTITUTED SUCCINATE ESTERS 审中-公开
标题翻译： 2替代的成功的ESTERS
公开(公告)号：WO1998000388A1
公开(公告)日：1998-01-08
申请号：PCT/GB1997001742
申请日：1997-06-27
申请人： BP CHEMICALS LIMITED , GRACEY, Benjamin, Patrick , HALLETT, Christopher
发明人： BP CHEMICALS LIMITED
IPC分类号： C07C69/708
CPC分类号： C09D131/04 , C07C67/31 , C07C69/708 , C08F22/20 , C09D7/20 , C07C69/734
摘要： This invention relates to a process for producing 2-substituted succinate esters of formula (I) by reacting (a) a dicarboxylic compound with a first alcohol R'O[CHR''.CH2O]xH where x is 0 or an integer from 1-6 in the presence of a catalyst to form a hydrocarbyl ester or, when x = 1-6, a hydrocarbyloxy alkylene ester of maleic and/or fumaric acid and (b) the ester from step (a) with an alkaline earth metal alkoxide in the presence of a second alcohol R.OH to form the 2-substituted succinate ester of formula (I). The esters and paint formulations based thereon are also claimed.
摘要翻译：本发明涉及通过使（a）二羧酸化合物与第一个醇R'O [CHR“CH 2 O] x H反应生成2-取代琥珀酸酯的方法，其中x为0或1的整数 -6在催化剂存在下形成烃基酯，或当x = 1-6时，马来酸和/或富马酸的烃氧基亚烷基酯和（b）来自步骤（a）的酯与碱土金属醇盐在第二个醇R.OH的存在下，形成式（I）的2-取代的琥珀酸酯。基于此的酯和油漆制剂也被要求保护。

67. 发明申请

WO8704427A3 PROSTAGLANDIN SYNTHESIS 审中-公开
标题翻译：前列腺素合成
公开(公告)号：WO8704427A3
公开(公告)日：1987-12-03
申请号：PCT/GB8700019
申请日：1987-01-15
申请人： NAT RES DEV
发明人： JONES ROBERT LESLIE , WILSON NORMAN HAPPER
IPC分类号： C07C69/03 , C07B61/00 , C07C51/00 , C07C51/353 , C07C59/125 , C07C59/205 , C07C59/80 , C07C67/00 , C07C67/347 , C07C231/00 , C07C231/02 , C07C231/12 , C07C235/82 , C07C325/00 , C07C327/24 , C07C405/00 , C07D493/08 , C07C69/708
CPC分类号： C07D493/08 , C07C59/80 , C07C405/0091
摘要： A process for the preparation of a compound of formula (I), wherein X and X' each represents hydrogen or together represent a bridging group -CH2-, -CH2-CH2- or -O-; R1 is a 6-carboxyhex-2-enyl group or a modification thereof in which the group is altered by one, or an appropriate combination of two or more, of the following: (a) alteration of the position of the double bond, with the proviso that in the modified group the double bond is not in the alpha-beta position relative to the ring; (b) reduction of the double bond; (c) alteration of the chain length through a decrease of one or two methylene groups or an increase of one to six methylene groups; (d) replacement of one or two methylene groups each separately by an oxygen or sulphur atom, with the proviso that in the modified group no oxygen or sulphur atom is in an alpha position relative to either a doubly bonded carbon atom or to the carboxy group or a derivative thereof and that at least 2 carbon atomes separate any pair of oxygen and/or sulphur atoms; and (e) formation of an amide, ester or salt derivative of the carboxy group; R2 is an aliphatic hydrocarbon group or an aliphatic hydrocarbon group substituted by an aromatic group directly or through an oxygen or sulphur atom; and R3, R4, R5 and R6 are each hydrogen, or R3 and R4 together and/or R5 and R6 together represent the second bond of a carbon-carbon double bond; comprises effecting a Diels Alder reaction between a diene of formula (II) and a dienophile of formula (III), wherein X, X' and R2 are as defined for (I); Y is R1 or a precursor therefor in which a double bond is present and/or the terminal group is in different form, either being a free carboxy group rather than the carboxy group derivative present in R1 or being a carboxy group derivative rather than the free carboxy group present in R1; and R and R' are either each hydrogen or together represent the third bond of a carbon-carbon triple bond; and where appropriate thereafter, in either order, reducing the double bond or bonds in the ring of the Diels Alder adduct and/or converting the group Y to the group R1. The compounds prepared by this process are of value as intermediates for the preparation of biologically active compounds.
摘要翻译：制备式（I）化合物的方法，其中X和X'各自代表氢或一起代表桥基-CH 2 - ， - CH 2 -CH 2 - 或-O-; R1是6-羧基己-2-烯基或其修饰，其中该基团被以下的一个或两个或更多个的适当组合改变：（a）改变双键的位置，与条件是在修饰基团中双键不在相对于环的α-β位; （b）减少双键; （c）通过减少一个或两个亚甲基或增加一个至六个亚甲基而改变链长; （d）分别用氧或硫原子分别置换一个或两个亚甲基，条件是在修饰基团中氧或硫原子相对于双键碳原子或羧基处于α位或其衍生物，并且至少2个碳原子分离任何一对氧原子和/或硫原子; 和（e）形成羧基的酰胺，酯或盐衍生物; R2是直接或通过氧或硫原子被芳基取代的脂族烃基或脂族烃基; 并且R3，R4，R5和R6各自为氢，或者R3和R4一起和/或R5和R6一起表示碳 - 碳双键的第二键; 包括在式（II）的二烯与式（III）的亲二烯体之间进行狄尔斯阿尔德反应，其中X，X'和R2如对（I）所定义; Y是R 1或其中存在双键的前体和/或末端基团是不同形式，或者是游离羧基而不是存在于R 1中的羧基衍生物或者是羧基衍生物而不是游离的存在于R1中的羧基; 并且R和R'各自为氢或一起表示碳 - 碳三键的第三键; 然后以任意次序，减少Diels Alder加合物的环中的双键或键和/或将基团Y转化为基团R1。通过该方法制备的化合物作为制备生物活性化合物的中间体是有价值的。

68. 发明申请

WO2023058754A1 フッ素化ポリエーテルの製造方法审中-公开
公开(公告)号：WO2023058754A1
公开(公告)日：2023-04-13
申请号：PCT/JP2022/037645
申请日：2022-10-07
申请人：株式会社レゾナック
发明人：梅谷　将隆 , 大澤　信夫 , 加藤　剛 , 柳生　大輔 , 黒田　拓麻
IPC分类号： C07C67/307 , C07C69/708
摘要： [課題]原料のポリエーテル化合物の数平均分子量から算出される理論通りの数平均分子量のフッ素化ポリエーテルを、高収率で製造しうる方法を提供する。 [解決手段]分子量分布を表すＭｗ／Ｍｎが１．３０以下である式（Ｘ）で表される原料化合物、不活性ガス、フッ素ガス、および溶媒を反応器に導入して、前記原料化合物をフッ素化する工程（１）を含むことを特徴とする、フッ素化ポリエーテルの製造方法。Ｒ４－Ｏ－（Ｒ１－Ｏ）ｘ－Ｒ５　（Ｘ）（Ｒ１は炭素原子数２～５の２価の炭化水素基；Ｒ４およびＲ５はそれぞれ独立に、水酸基の保護基；ｘは平均重合度を表し、２．７～１５の実数である。）

69. 发明申请

WO2023008354A1 レジスト組成物、及びそれを用いたレジスト膜形成方法审中-公开
公开(公告)号：WO2023008354A1
公开(公告)日：2023-02-02
申请号：PCT/JP2022/028576
申请日：2022-07-25
申请人：三菱瓦斯化学株式会社
发明人：岡田　拓巳 , 星野　良輔 , 佐藤　英之 , 片桐　誠之 , 鈴木　周 , 越後　雅敏
IPC分类号： C07C39/19 , C07C309/06 , C07C381/12 , C08F20/10 , C08F220/28 , G03F7/004 , G03F7/023 , G03F7/039 , G03F7/20 , C07C69/54 , C07C69/675 , C07C69/708
摘要：本発明によれば、樹脂（Ａ）、及び下記一般式（ｂ－１）で表される化合物（Ｂ１）を含む溶媒（Ｂ）を含有するレジスト組成物であって、前記レジスト組成物の全量基準での有効成分の含有量が４５質量％以下である、レジスト組成物を提供することができる。〔上記式（ｂ－１）中、Ｒ１は、炭素数１～１０のアルキル基である。〕

70. 发明申请

WO2022119070A1 카보네이트 유도체 제조용 셀레늄계 촉매 시스템 및 그를 이용한 카보네이트 유도체의 제조방법 审中-公开
公开(公告)号：WO2022119070A1
公开(公告)日：2022-06-09
申请号：PCT/KR2021/008715
申请日：2021-07-08
申请人： 한국생산기술연구원
发明人： 김용진 , 백자연 , 이혜진
IPC分类号： B01J27/057 , B01J31/02 , C07C67/37 , C07C69/708
摘要： 본 발명은 셀레늄(Se); 및 구조식 1로 표시되는 피리딘 아민 화합물;을 포함하는 카보네이트 유도체 제조용 촉매 시스템에 관한 것이다. 본 발명의 카보네이트 유도체 제조용 촉매 시스템 및 그를 이용한 카보네이트 유도체의 제조방법은 셀레늄계 촉매 시스템을 사용하여 알코올의 산화성 카르보닐화 공정을 수행함으로써, 기존 카르보닐화 공정에 비해 경제적이면서, 실현가능한 수율로 디알킬카보네이트를 수득할 수 있다.

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