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41. 发明申请

WO2013072216A1 METHOD FOR MANUFACTURING A POLYMER ELECTROLYTE SEPARATOR AND POLYMER ELECTROLYTE SEPARATOR THEREFROM 审中-公开
标题翻译：制造聚合物电解质分离器和聚合物电解质分离器的方法
公开(公告)号：WO2013072216A1
公开(公告)日：2013-05-23
申请号：PCT/EP2012/071881
申请日：2012-11-06
申请人： SOLVAY SPECIALTY POLYMERS ITALY S.P.A.
发明人： ABUSLEME, Julio A. , PIERI, Riccardo , FOSSATI, Paolo
IPC分类号： C08J5/22 , C08F8/00 , C08F8/44 , C08F8/42 , C08F8/12 , C08F214/18 , C08F220/20 , H01M2/16 , H01M8/02 , H01M8/24 , H01M10/052 , H01M10/0565
CPC分类号： H01M10/056 , C08F214/186 , C08F214/225 , C08J5/22 , C08J2327/12 , H01M2/145 , H01M2/166 , H01M10/052
摘要： The invention pertains to a process for manufacturing a polymer electrolyte separator based on a fluoropolymer hybrid organic/inorganic composite, said process comprising: (i) providing a mixture of: - at least one fluoropolymer comprising recurring units derived from at least one (meth)acrylic monomer [monomer (MA)] of formula (I): wherein each of R1, R2, R3, equal or different from each other, is independently a hydrogen atom or a C 1 -C 3 hydrocarbon group, and R OH is a C 1 -C 5 hydrocarbon moiety comprising at least one hydroxyl group [polymer (F)]; - at least one metal compound [compound (M)] of formula: X 4-m AY m wherein m is an integer from 1 to 4, A is a metal selected from the group consisting of Si, Ti and Zr, Y is a hydrolysable group, X is a hydrocarbon group, optionally comprising one or more functional groups; and - at least one electrolyte (E); and - at least one liquid plasticizer (S); (ii) reacting at least a fraction of hydroxyl groups of the ROH groups of said monomer (MA) of said polymer (F) with at least a fraction of said compound (M), so as to obtain a grafted polymer comprising pendant -Y m-1 AX 4-m groups, with m, Y, A and X having same meaning as above detailed; (iii) hydrolyzing and/or polycondensing compound (M) and/or pendant -Y m.-1 AX 4-m groups, as above detailed to yield a liquid mixture comprising fluoropolymer hybrid organic/inorganic composite comprising inorganic domains and incorporating solvent (S) and electrolyte (E); and (iv) casting a film from the liquid mixture obtained in (iii); (v) drying the film obtained in (iv) for obtaining the polymer electrolyte separator.
摘要翻译：本发明涉及一种制备基于含氟聚合物杂化有机/无机复合材料的聚合物电解质隔膜的方法，所述方法包括：（i）提供以下混合物： - 至少一种含有衍生自至少一种（甲基）式（I）的丙烯酸单体[单体（MA）]：其中R1，R2，R3彼此相同或不同的各自独立地为氢原子或C1-C3烃基，ROH为C1-C5 包含至少一个羟基的烃部分[聚合物（F）]; - 至少一种式：X4-mAYm的金属化合物[化合物（M）]，其中m是1至4的整数，A是选自Si，Ti和Zr的金属，Y是可水解基团， X是烃基，任选地包含一个或多个官能团; 和 - 至少一种电解质（E）; 和 - 至少一种液体增塑剂（S）; （ii）将所述聚合物（F）的所述单体（MA）的ROH基团的至少一部分羟基与至少一部分所述化合物（M）反应，以获得包含侧基-Ym的接枝聚合物 -1AX4-m基团，其中m，Y，A和X具有与上述相同的含义; （iii）水解和/或缩聚化合物（M）和/或侧链-Ym-1AX4-m基团，如上所述，以产生包含含有无机结构域并掺入溶剂（S）的含氟聚合物杂化有机/无机复合物的液体混合物，电解质（E）; 和（iv）从（iii）中获得的液体混合物中浇铸薄膜; （v）干燥（iv）中获得的膜以获得聚合物电解质分离器。

42. 发明申请

WO2011015517A1 PROCESS FOR THE PREPARATION OF ETHYLENE/CHLOROTRIFLUOROETHYLENE POLYMER MEMBRANES 审中-公开
标题翻译：乙烯/氯乙烯乙烯聚合物膜的制备方法
公开(公告)号：WO2011015517A1
公开(公告)日：2011-02-10
申请号：PCT/EP2010/061063
申请日：2010-07-29
申请人： SOLVAY SOLEXIS S.p.A. , ABUSLEME, Julio A. , PAGIN, Ivan , BERTASA, Anna Maria
发明人： ABUSLEME, Julio A. , PAGIN, Ivan , BERTASA, Anna Maria
IPC分类号： B01D69/08 , B01D71/32 , B01D67/00
CPC分类号： B01D71/32 , B01D67/0011 , B01D69/08 , B01D2325/32
摘要： The invention relates to a process for the production of membranes based on ethylene/chlorotrifluoroethylene polymers having a melting temperature not exceeding 200°C. The process relies on the diffusion induced phase separation of the ethylene/chlorotrifluoroethylene polymer from a solution and comprises the steps of providing a solution comprising an ethylene/chlorotrifluoroethylene polymer having a melting temperature not exceeding 200°C in a solvent; casting the polymer solution into a film; immersing the film in a non-solvent bath to precipitate the polymer. Membranes made of compositions comprising an ethylene/chlorotrifluoroethylene polymer having a melting temperature not exceeding 200°C and at least one second polymer are also disclosed.
摘要翻译：本发明涉及一种基于熔点不超过200℃的乙烯/三氟氯乙烯聚合物生产膜的方法。该方法依赖于乙烯/氯三氟乙烯聚合物从溶液中扩散诱导的相分离，并且包括在溶剂中提供包含熔点不超过200℃的乙烯/三氟氯乙烯聚合物的溶液的步骤; 将聚合物溶液浇铸成膜; 将膜浸入非溶剂浴中以沉淀聚合物。还公开了由包含熔融温度不超过200℃的乙烯/三氟氯乙烯聚合物和至少一种第二聚合物的组合物制成的膜。

43. 发明申请

WO2008065164A1 ADDITIVES FOR HALOPOLYMERS 审中-公开
标题翻译：卤化剂添加剂
公开(公告)号：WO2008065164A1
公开(公告)日：2008-06-05
申请号：PCT/EP2007/062999
申请日：2007-11-29
申请人： SOLVAY SOLEXIS S.P.A. , ABUSLEME, Julio A. , AVATANEO, Marco , PERFETTI, Giancarlo
发明人： ABUSLEME, Julio A. , AVATANEO, Marco , PERFETTI, Giancarlo
IPC分类号： C08L27/00 , C08L23/00
CPC分类号： C08L23/0892 , C08L23/00 , C08L27/00 , C08L51/08 , C08L53/00 , C08L71/02 , C08L2666/24 , C08L2666/22
摘要： Polymeric compositions comprising: 1) at least one thermoprocessable semicrystalline halo-polymer; 2) an additive in amounts between 0.01 and 10% by weight of 1) one or more (per)fluoropolyether polymers of formula Q-O-[A-B] z -[A-B'] z '-A-Q' (I) wherein: A = -(X) a -O-A'-(X') b - wherein A' is a perfluoropolyether chain; X, X' = -CF 2 -, -CF 2 CF2-, -CF(CF 3 )-; a, b = 0 or 1; B derives from one or more olefins, of which at least one homopolymerizable by radical way, of formula: -[(CR 1 R 2 -CR 3 R 4 ) j (CR 5 R 6 -CR 7 R 8 ) j' ]- (Ia) wherein j = 1-30, j'= 0-29, with the proviso that 2 1 -R 8 = halogen, H, C 1 -C 6 (per)haloalkyl, C 1 -C 6 alkyl, C 1 -C 6 oxy(per)fluoroalkyl; B' = (Ia) but at least one of R 1 -R 8 has a meaning different from that in B, and 2 ≤(j+j') 1 -C 3 perfluoroalkyl; C 1 -C 6 alkyl; or functional end group(s).
摘要翻译：聚合物组合物包括：1）至少一种热可加工半结晶卤代聚合物; 2）0.01至10重量％的添加剂，其量为1）一种或多种式QO- [AB] z - [A-B'] z的（全）氟聚醚聚合物 AQ'（I）其中：A = - （X）a -O-A' - （X'）b - 其中A'为全氟聚醚链; X，X'= -CF 2 - ， - CF 2 CF 2 - ， - CF（CF 3 - ） - ; a，b = 0或1; B衍生自一种或多种烯烃，其中至少一种可以通过基团方式均聚的式如下： - [（CR 1 R 2 -CR 3） SUB> - [R _{4 ）_{Ĵ（CR _{5 - [R _{6 -CR _{7 ř 其中j = 1-30，j'= 0-29，条件是2 <（J + J'） 30; R 1 -R 8 =卤素，H，C 1 -C 6（全）卤代烷基，C 1 -C 8烷基， C 1 -C 6烷基，C 1 -C 6 - 氧基（全）氟烷基; C 1 -C 6烷基，C 1 -C 6 - B'=（Ia），但R 1〜R 8中的至少一个具有与B不同的含义，2 =（j + j'）<30 ; z = 2; z'为0或整数; z，z'使得（I）的数均分子量在500和500,000之间; Q，Q'= C 1 -C 3全氟烷基; C 1 -C 6烷基; C 1 -C 6烷基; 或功能性端基。}}}}}

44. 发明申请

WO2007006646A1 THERMOPLASTIC HALOPOLYMER COMPOSITION 审中-公开
标题翻译：热塑性HOPOPYMER组合物
公开(公告)号：WO2007006646A1
公开(公告)日：2007-01-18
申请号：PCT/EP2006/063589
申请日：2006-06-27
申请人： SOLVAY SOLEXIS S.p.A. , ABUSLEME, Julio A. , BRINATI, Giulio , GUARDA, Pier Antonio
发明人： ABUSLEME, Julio A. , BRINATI, Giulio , GUARDA, Pier Antonio
IPC分类号： C08L27/12 , C08L27/16 , C08L27/18 , C08L71/00
CPC分类号： C08L27/16 , C08L27/18 , C08L71/00 , C08L2205/02 , C08L2205/03 , C08L2666/02
摘要： The invention pertains to a thermoplastic halopolymer composition comprising - at least one thermoplastic halopolymer [polymer (A)]; - from 0.01 to 5 % by weight of (A) of at least one (per)fluoropolyether [polymer (B)]; and - from 0.3 to 10 % by weight of (A) of at least one per(halo)fluoropolymer [polymer (C)]. The addition of a (per)fluoropolyether (B) and of a per(halo)fluoropolymer (C) advantageously enables improvement of rheological behavior of thermoplastic halopolymer (A), making possible processing in less severe conditions and yielding final parts with outstanding surface aspect and good homogeneity and coherency. Still objects of the inventions are the process for manufacturing said thermoplastic halopolymer composition and the articles thereof.
摘要翻译：本发明涉及一种热塑性卤代聚合物组合物，其包含 - 至少一种热塑性卤代聚合物[聚合物（A）]; （A）至少一种（全）氟聚醚[聚合物（B）]的0.01至5重量％和（A）至少一种每（卤代）含氟聚合物[聚合物（C）] 0.3至10重量％。加入（全）氟聚醚（B）和全（卤）氟聚合物（C）有利地有助于改善热塑性卤代聚合物（A）的流变行为，使得在较不严格的条件下可能的加工，并产生具有突出表面方面的最终部件良好的均匀性和一致性。本发明的另一个目的是制造所述热塑性卤代聚合物组合物及其制品的方法。

45. 发明申请

WO2007065881A1 WATER-BASED FLUOROPOLYMER COMPOSITION 审中-公开
标题翻译：水基荧光体组合物
公开(公告)号：WO2007065881A1
公开(公告)日：2007-06-14
申请号：PCT/EP2006/069282
申请日：2006-12-04
申请人： SOLVAY SOLEXIS S.p.A. , POLASTRI, Fabio , POGGIO, Tiziana , ABUSLEME, Julio A.
发明人： POLASTRI, Fabio , POGGIO, Tiziana , ABUSLEME, Julio A.
IPC分类号： C09D123/08 , C09D127/12 , C08K5/06
CPC分类号： C09D127/12 , C08K5/04 , C08K5/05 , C08K5/053 , C08K5/06 , C09D127/16 , C09D127/18 , Y10T428/3154 , C08L27/12
摘要： The invention relates to a fluoropolymer composition comprising : - at least one thermoplastic partially fluorinated fluoropolymer [polymer (F)]; - water; - less than 15 % wt (based on total weight of composition) of a water-soluble solvent mixture [mixture (M)] comprising : - at least one alcohol solvent [solvent (A)]; - at least one glycol derivative solvent having a boiling point of at least 1000C [solvent (GD)], wherein the solvent (GD) is a derivative of a compound comprising at least two hydroxyl group, wherein at least one of the hydroxyl group has been derivatized to yield an ether or an ester bond. Another object of the present invention is a process for manufacturing said composition. Still another object of the invention is the use of the composition of the invention for coating. Still another object of the invention is a coated article, obtained using the composition of the invention.
摘要翻译：本发明涉及含氟聚合物组合物，其包含： - 至少一种热塑性部分氟化含氟聚合物[聚合物（F）]; - 水; - 低于15重量％（基于组合物的总重量）水溶性溶剂混合物[混合物（M）]，其包含： - 至少一种醇溶剂[溶剂（A）]; - 至少一种沸点为至少1000℃的乙二醇衍生物溶剂[溶剂（GD）]，其中溶剂（GD）是包含至少两个羟基的化合物的衍生物，其中至少一个羟基具有衍生化得到醚或酯键。本发明的另一个目的是制备所述组合物的方法。本发明的另一个目的是使用本发明的组合物进行涂覆。本发明的另一个目的是使用本发明的组合物获得的涂层制品。

46. 发明申请

WO2011121078A1 FLUOROPOLYMER-BASED HYBRID ORGANIC/INORGANIC COMPOSITES 审中-公开
标题翻译：基于荧光聚合物的混合有机/无机复合材料
公开(公告)号：WO2011121078A1
公开(公告)日：2011-10-06
申请号：PCT/EP2011/055019
申请日：2011-03-31
申请人： SOLVAY SOLEXIS S.P.A. , ABUSLEME, Julio A. , PIERI, Riccardo , PAGIN, Ivan
发明人： ABUSLEME, Julio A. , PIERI, Riccardo , PAGIN, Ivan
IPC分类号： C08F214/18
CPC分类号： C08F214/18 , B01D67/0079 , B01D69/148 , B01D71/022 , B01D71/027 , B01D71/34 , B01D71/70 , B01D2323/38 , B82Y30/00 , C08F8/00 , C08F214/182 , C08F214/186 , C08F214/225 , C08F214/245 , C08F220/06 , C08F220/20 , C08F2800/10 , C08F2810/20 , C08F2810/50 , C08J5/005 , C08J5/2281 , C08J2333/10 , C08K3/346 , C09D127/16 , H01M2/145 , H01M2/166 , H01M8/1046 , Y02P70/56 , C08F8/12 , C08F8/42 , C08F210/02 , C08K3/36
摘要： The invention pertains to a process for manufacturing a fluoropolymer hybrid organic/inorganic composite, said process comprising: (i) providing a mixture of: - at least one fluoropolymer comprising recurring units derived from at least one (meth)acrylic monomer [monomer (MA)] of formula: wherein each of R1, R2, R3, equal or different from each other, is independently a hydrogen atom or a C 1 -C 3 hydrocarbon group, and R OH is a hydrogen atom or a C 1-C 5 hydrocarbon moiety comprising at least one hydroxyl group [polymer (F)]; and - at least one metal compound [compound (M)] of formula: X 4-m AY m wherein m is an integer from 1 to 4, and, according to certain embodiments, from 1 to 3, A is a metal selected from the group consisting of Si, Ti and Zr, Y is a hydrolysable group, X is a hydrocarbon group, optionally comprising one or more functional groups; - reacting at least a fraction of hydroxyl groups of the ROH groups of said monomer (MA) of said polymer (F) with at least a fraction of said compound (M), so as to obtain a grafted polymer comprising pendant -Y m-1 AX 4-m groups, with m, Y, A and X having same meaning as above detailed; - hydrolyzing and/or polycondensing compound (M) and/or pendant -Y m-1 AX 4-m groups, as above detailed to yield a fluoropolymer hybrid organic/inorganic composite comprising inorganic domains, to fluoropolymer hybrid organic/inorganic composites obtained therefrom and to the use of the same in several fields of use.
摘要翻译：本发明涉及一种制备含氟聚合物杂化有机/无机复合材料的方法，所述方法包括：（i）提供以下混合物： - 至少一种含有至少一种（甲基）丙烯酸单体衍生的重复单元的含氟聚合物[单体（MA ）]，其中R 1，R 2，R 3彼此相同或不同，各自独立地为氢原子或C1-C3烃基，ROH为氢原子或C 1 -C 5烃部分，其包含在至少一个羟基[聚合物（F）]; 和 - 至少一种式：X4-mAYm的金属化合物[化合物（M）]，其中m是1至4的整数，并且根据某些实施方案，从1至3，A是选自以下的金属：的Si，Ti和Zr，Y是可水解基团，X是烃基，任选地包含一个或多个官能团; - 将所述聚合物（F）的所述单体（MA）的ROH基团的至少一部分羟基与至少一部分所述化合物（M）反应，以获得包含侧基-Ym-1AX4的接枝聚合物 -m组，m，Y，A和X具有与上述相同的含义; - 水解和/或缩聚化合物（M）和/或侧基-Ym-1AX4-m基团，如上所述，以产生含有无机结构域的含氟聚合物杂化有机/无机复合材料，由其获得的含氟聚合物杂化有机/无机复合材料和在几个使用领域使用相同。

47. 发明申请

WO2009068635A1 FLUOROELASTOMER COMPOSITION 审中-公开
标题翻译：荧光体组合物
公开(公告)号：WO2009068635A1
公开(公告)日：2009-06-04
申请号：PCT/EP2008/066393
申请日：2008-11-28
申请人： SOLVAY SOLEXIS S.p.A. , COMINO, Giovanni , ABUSLEME, Julio A. , ALBANO, Margherita
发明人： COMINO, Giovanni , ABUSLEME, Julio A. , ALBANO, Margherita
IPC分类号： C08L27/12 , C08L27/16 , C08L27/18 , C08L71/02
CPC分类号： C08L27/18 , C08L27/12 , C08L27/16 , C08L71/02 , C08L2205/02 , C08L2205/03 , C08L2666/22 , C08L2666/02 , C08L2666/04
摘要： The invention pertains to a fluoroelastomer composition comprising: - at least one fluoroelastomer [fluoroelastomer (A)]; - from 0.1 to 25 phr (with respect to fluoroelastomer (A)) of at least one melt-processable per(halo)fluoropolymer having a melting point of at most 250°C [polymer (F)]; and - optionally at least one (per)fluoropolyether [(per)fluoropolyether (E)]. The Applicant has surprisingly found that the incorporation in the fluoroelastomer composition of the polymer (F) as above described enables easier processing of the fluoroelastomer composition, both in injection moulding and extrusion moulding technologies, yielding improved behaviour in mould release, mould fouling and aspect surface of the moulded parts.
摘要翻译：本发明涉及含氟弹性体组合物，其包含： - 至少一种含氟弹性体[含氟弹性体（A）]; 至少一种可熔融加工的每个（卤）含氟聚合物的熔点至多为250℃[聚合物（F）]的0.1至25phr（相对于含氟弹性体（A））; 和 - 任选地至少一种（全）氟聚醚[（全）氟聚醚（E）]。申请人惊奇地发现，如上所述在聚合物（F）的含氟弹性体组合物中的引入使得能够在注射成型和挤出成型技术中更容易地处理含氟弹性体组合物，从而在脱模，模具污染和方面表面上产生改善的行为的模制件。

48. 发明申请

WO2007096348A1 CABLES HAVING A LOW SMOKE RELEASE 审中-公开
标题翻译：具有低烟雾释放的电缆
公开(公告)号：WO2007096348A1
公开(公告)日：2007-08-30
申请号：PCT/EP2007/051592
申请日：2007-02-20
申请人： SOLVAY SOLEXIS S.P.A. , ABUSLEME, Julio A. , ARCELLA, Vincenzo , ZANGARA, Anthony V
发明人： ABUSLEME, Julio A. , ARCELLA, Vincenzo , ZANGARA, Anthony V
IPC分类号： C08L27/12 , C08K3/00 , H01B3/44
CPC分类号： H01B3/445
摘要： Cables comprising: primary cables coated by a perfluoropolymer; and a jacket formed of a polymeric composition comprising: (A) an ethylene, tetrafluoroethylene (TFE) and/or chlorotrifluoroethylene (CTFE) copolymer, and one or more hydrogenated monomers; (B) one or more inorganic fire-retardants, optionally treated with dispersing agents.
摘要翻译：电缆包括：由全氟聚合物涂覆的主电缆; 和由聚合物组合物形成的护套，其包含：（A）乙烯，四氟乙烯（TFE）和/或三氟氯乙烯（CTFE）共聚物和一种或多种氢化单体; （B）一种或多种无机阻燃剂，任选用分散剂处理。

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