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    • 44. 发明申请
    • AGENT FOR DYEING KERATIN CONTAINING FIBERS
    • 手段垂死角蛋白纤维
    • WO0209662A3
    • 2002-06-27
    • PCT/EP0108656
    • 2001-07-26
    • HENKEL KGAAROSE DAVIDNAUMANN FRANKMEINIGKE BERNDHOEFFKES HORST
    • ROSE DAVIDNAUMANN FRANKMEINIGKE BERNDHOEFFKES HORST
    • A61K8/49A61Q5/10D06P1/642A61K7/13
    • A61Q5/10A61K8/494
    • The invention relates to an agent for dyeing keratin containing fibers which comprises as the developer at least one compound of the general formula (I), wherein R1 and R2 are the same or different and represent hydrogen, C1-4 alkyl or C1-4 hydroxyalkyl, and R3 represents a group of the formula (II), wherein R4 represents a piperazinyl group or a group -NR7(CH2)n-NR7, wherein R7 represents hydrogen or C1-4 alkyl and n is an integer of from 1 to 4, R5 and R6 are the same or different and represent hydrogen, C1-4 alkyl or C1-4 hydroxyalkyl, or else R3 represents a group (III), or a group (IV), wherein R9 represents hydrogen, C1-4 alkyl or C1-4 hydroxyalkyl, Y represents a direct bond or a straight-chain or branched C1-5 alkylene group, and A represents a saturated or unsaturated 5-, 6- or 7-membered ring optionally containing one or more heteroatoms, a group -CO-NH2, a C1-4 alkoxy group or a C1-4 dialkylamino group, wherein A may be linked with any carbon atom of the alkylene group Y.
    • 有权利用于着色包含角蛋白的纤维,其包括组合物,如显影剂部件的至少一个具有通式(I)可以是相同的或不同的,其中R1和R2,并且表示氢,C 1-4烷基或C 1-4化合物 羟烷基和R 3是具有其中R 4表示哌嗪基或基团的式(II)的基团-NR 7(CH 2)n的NR 7,其中R 7是氢或C 1-4烷基,n是从一个整数 1至4可以是,R 5和R 6可以相同或不同,是氢,C 1-4烷基或C 1-4羟基烷基,基团(III)或一组(IV)其中R9是氢,C1 -4-烷基或C 1-4 - 羟基烷基,Y为直接键或直链或支链C 1-5 - 亚烷基,a是一个为饱和或不饱和的,任选地含有杂原子或更多5,6或7元环 中,基团-CO-NH 2,C 1-4烷氧基或一个 ÈC1-4二烷基氨基,其中,A可以被链接到所述的亚烷基Y的任何碳原子
    • 45. 发明申请
    • AGENT FOR DYEING KERATIN CONTAINING FIBERS
    • 手段垂死角蛋白纤维
    • WO0197764A3
    • 2002-05-23
    • PCT/EP0106690
    • 2001-06-13
    • HENKEL KGAAOBERKOBUSCH DORISHOEFFKES HORSTMOELLER HINRICHGROSS WIBKEMARTIN HANS DIETER
    • OBERKOBUSCH DORISHOEFFKES HORSTMOELLER HINRICHGROSS WIBKEMARTIN HANS-DIETER
    • A61K8/35A61K8/49A61Q5/06A61K7/13
    • A61K8/35A61K8/494A61Q5/065
    • The invention relates to an agent for dyeing keratin containing fibers, especially human hair, comprising at least one cyclopentaquinoxalinium derivative of the formula (I), wherein R , R , R independently represent a hydrogen atom or a C1-C4 alkyl group, and R and R together may form a ring, X and X represent an oxygen or sulfur atom or together a 1,2-arylenediimino group that in turn can be substituted in the aromatic group by halogen atoms, C1-C4 alkyl, C1-C4 alkoxy, nitro, amino, C1-C4 alkyl, C1-C4 alkylamino, hydroxy, carboxy, or sulfo groups or an additional condensed aromatic ring and is quaternated on one of the nitrogen atoms by a C1-C6 alkyl, aralkyl, aryl, C2-C4 alkenyl, or C1-C6 hydroxyalkyl, or carboxyalkyl group, and wherein the additional condensed aromatic ring may be substituted by halogen atoms, in halogen atoms, C1-C4 alkyl, C1-C4 alkoxy, nitro, amino, C1-C4 alkyl, C1-C4 alkylamino, hydroxy, carboxy, or sulfo groups. The invention further relates to the tautomeric forms or the physiologically acceptable salts of the inventive derivative.
    • 它是用于染色角蛋白纤维,特别是人的头发,权利要求的试剂,含有其中R <1>,R <2>,R <3>独立地表示氢原子或式(I)中的至少一个环己烯酮衍生物 C1-C4烷基基团,其中R可以<1>和R <2>一起形成环,X <1>和X <2>为氧,硫原子或一起形成1,2- Arylendiiminogruppe,反过来,在 被卤原子,C1-C4烷基,C1-C4烷氧基,硝基,氨基,C1-C4烷基,C1-C4烷基氨基,羟基,羧基,磺基或另一种稠合芳族的芳族化合物 取代的环和,羧基烷基可以在由一个C1-C6烷基,芳烷基,芳基,C2-C4链烯基或C1-C6羟基烷基,其中所述稠合进一步被卤素原子的芳族环中的氮原子中的一个季铵化, 在卤原子,C1-C4烷基,C1-C4烷氧基,硝基,氨基,C1-C4烷基,C1-C4烷基氨基,羟基,羧基,磺 ogruppen可被取代,或它的互变异构形式或它们的生理学可耐受的盐。
    • 47. 发明申请
    • COLOURING COMBINATION BASED ON A M-PHENYLENEDIAMINE DERIVATIVE
    • DYE组合基于阿间苯二胺衍生物
    • WO0141716A3
    • 2002-04-04
    • PCT/EP0012096
    • 2000-12-01
    • HENKEL KGAAROSE DAVIDHOEFFKES HORSTMEINIGKE BERND
    • ROSE DAVIDHOEFFKES HORSTMEINIGKE BERND
    • A61K8/41A61K8/49A61Q5/10A61K7/13
    • A61K8/494A61K8/411A61K8/415A61Q5/10
    • The invention relates to oxidative colouring agents for colouring keratin fibres, in particular human hair, which contain, in a medium suitable for colouring, (a) at least one m-phenylenediamine derivative of formula (I) as coupling component, where R = a branched or unbranched C1- to C8-alkyl group and R = a branched or unbranched C1 to C8 alkyl group or a phenyl group, optionally substituted by one or several C1 to C4 alkyl group(s) or, by one or several halogen atom(s), or a physiologically acceptable salt thereof; (b) at least one developing component selected from 4-amino-2-((diethylamino)methyl)phenol, 2-chloro-4-aminophenol, 2,6-dichloro-4-aminophenol, 4-amino-3-methylphenol, 1-(2'-hydroxyethyl)-2,5-diaminobenzene, 1,10-bis-(2,5-diaminophenyl)-1,4,7,10-tetraoxadecane, bis-(2-hydroxy-5-aminophenyl)-methane, 2-aminomethyl-4-aminophenol, N,N'-bis-(4-aminophenyl)-1,4-diazacycloheptane, 1,3-bis-(N-(2-hydroxyethyl)-N-(4-aminophenylamino))-2-propanol, N,N-bis-(2-hydroxyethyl)-p-phenylendiamine, 4,5-diamino-1-(
    • 本发明涉及角蛋白纤维,特别是人的毛发的氧化染色的,包括(a)在培养基中适当用于染色,作为偶合剂成分的至少一种式(I)其中R <1>为支链或的间苯二胺衍生物 无支链的C1至C8烷基和R <2>是支链或无支链的C1至C8烷基或苯基基团,其是任选取代的(被一个或多个C1-C4烷基基团或由一个或多个卤素原子 e)可以被取代,或其生理学上可接受的盐中的一种,和(b)至少一种显色剂组分由4-氨基-2-选择 - ((二乙基氨基)甲基)苯酚,2-氯-4-氨基苯酚,2,6-二氯 -4-氨基苯酚,4-氨基-3-甲基苯酚,1-(2'-羟乙基)-2,5-二氨基苯,1,10-双(2,5-二氨基苯基)-1,4,7,10- 四氧杂癸,双 - (2-羟基-5-氨基苯基)甲烷,2- Aminomehtyl -4-氨基苯酚,N,N'-双(4-氨基苯基)-1,4- diazacycl oheptan,1,3-双(N(2-羟乙基)-N(4-氨基苯基氨基)) - 2-丙醇,N,N-双(2-羟乙基) - 对苯二胺,4,5-二氨基 1-(β-羟乙基)吡唑和邻氨基苯酚含有。 通过突出的着色性质,本发明的组合物的特征特别在于。
    • 48. 发明申请
    • OXIDATION DYEING AGENT CONTAINING 2-HYDROXY-5-AMINOBENZYL PIPERAZINES
    • 含有2-羟基-5-氨基苄基 - 哌嗪的氧化着色剂
    • WO0197763A8
    • 2002-01-24
    • PCT/EP0106558
    • 2001-06-09
    • HENKEL KGAAROSE DAVIDMEINIGKE BERNDHOEFFKES HORST
    • ROSE DAVIDMEINIGKE BERNDHOEFFKES HORST
    • A61K8/49A61K8/67A61Q5/08A61Q5/10A61K7/13
    • A61Q5/10A61K8/494A61K8/673A61Q5/08
    • The invention relates to the paraaminophenol derivatives of formula (I), wherein R , R , R and R independently represent hydrogen, a C1-C4 alkyl group, a C2-C4 hydroxyalkyl group, R and R further represent fluoro, chloro, bromo, a C1-C4 alkoxy group or a hydroxy C2-C4 alkoxy group, R may also represent an acyl group having 1-8 C atoms or a group of formula (II), and R represents a hydrogen atom, an alkyl group, a C2-C4 hydroxyalkyl group, fluoro, chloro, bromo or a C1-C4 alkoxy group, and to their water-soluble salts, which are suitable as a developer component for producing an oxidative coloration. The preferred compounds are binuclear compounds, wherein R represents a group of formula (II). The inventive oxidation colorants for keratin fibers, especially hair, contain the compounds of formula (I) preferably combined with further developers and/or coupling components and optionally combined with direct dyes.
    • 式(I)的对氨基苯酚衍生物,其中R <1>,R <2>,R <3>,和R <5>独立地是氢,C1-C4烷基,C2-C4羟烷基 ,R <2>和R <3>另外,氟,氯,溴,C1-C4的烷氧基或羟基-C 2 -C 4 - 烷氧基,R <5>和酰基具有1-8个C- 是代表一个氢原子,一个烷基,一个C 2 -C 4羟烷基,氟,氯,溴和C1-C4烷氧基可以是原子或基团式(II)和R <4>。 和水溶性的盐是作为显影剂组分用于生产氧化着色是有用的。 双核是优选的,其中R <5>是一组式(II)的化合物。 氧化着色剂用于角蛋白纤维,特别是对头发,含有式(I)优选在与其他开发者和/或偶合剂组分和,任选地,用直接染料组合的化合物。