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31. 发明申请

WO2005040089A2 WATER RESISTANT CATALYST FOR THE PRODUCTION OF DIARYL CARBONATES VIA THE DIRECT CARBONYLATION OF PHENOLIC COMPOUNDS 审中-公开
标题翻译：通过苯酚化合物的直接碳化生产二氧化碳的耐水催化剂
公开(公告)号：WO2005040089A2
公开(公告)日：2005-05-06
申请号：PCT/US2004/030610
申请日：2004-09-17
申请人： GENERAL ELECTRIC COMPANY , SOLOVEICHIK, Grigoril, Lev , CHUCK, Timothy, Leigh , SHALYAEV, Kirill, Vladimirovich , PRESSMAN, James, Eric , BONITATEBUS, Peter, John, Jr.
发明人： SOLOVEICHIK, Grigoril, Lev , CHUCK, Timothy, Leigh , SHALYAEV, Kirill, Vladimirovich , PRESSMAN, James, Eric , BONITATEBUS, Peter, John, Jr.
IPC分类号： C07C68/00
CPC分类号： B01J31/0268 , B01J31/0237 , B01J31/0239 , B01J31/2234 , B01J31/26 , B01J2231/34 , B01J2531/16 , B01J2531/46 , B01J2531/824 , C07C68/005 , C07C69/96
摘要： A method of increasing the amount of diphenylcarbonate produced per amount of catalyst consumed in a phenol carbonylation process is described. Phenolic carbonylation produces water as a reaction product which reduces the turnover number (TON) of the catalyst. A mixture of a phenolic precursor, a base containing catalyst and co-catalyst components and at least one chemical additive comprising a halide or hydroxide of alkali metal or alkaline earth metal when carbonylated together under specific conditions increases the turnover number (TON) and water resistivity of a palladium catalyst. The metal halide likely makes the catalyst less susceptible to degradation by water hence increasing the reaction yield per weight of catalyst consumed.
摘要翻译：描述了在苯酚羰基化方法中增加每消耗的催化剂生产的碳酸二苯酯的量的方法。酚醛羰基化产生水作为反应产物，其降低催化剂的周转数（TON）。当在特定条件下一起羰基化时，酚前体，含碱催化剂和助催化剂组分的混合物和至少一种包含碱金属或碱土金属的卤化物或氢氧化物的化学添加剂增加了周转数（TON）和水电阻率的钯催化剂。金属卤化物可能使得催化剂不易受水的降解，因此增加每消耗催化剂重量的反应产率。

32. 发明申请

WO02048088A2 PROCESS FOR THE PRODUCTION OF DIARYL CARBONATES 审中-公开
标题翻译：生产二氧化碳的方法
公开(公告)号：WO02048088A2
公开(公告)日：2002-06-20
申请号：PCT/US2001/047205
申请日：2001-11-13
IPC分类号： C07B61/00 , C07C68/00 , C07C69/96
CPC分类号： C07C68/005 , C07C69/96
摘要： A process for catalytic production of diaryl carbonates by oxidative carbonylation of aromatic hydroxy compounds with carbon monoxide and oxygen achieves water removal during reaction by a process comprising the steps of: removing a liquid stream from an oxidative carbonylation reaction mixture in a reaction vessel (1), subjecting the liquid stream to reduced pressure, and returning at least a portion of dried liquid stream to the reaction vessel (1). Typical catalyst systems for oxidative carbonylation contain (A) at least one Group 8, 9, or 10 metal having an atomic number of at least 44 or a compound thereof; (B) at least one alkali metal salt; (C) at least one metal co-catalyst; (D) at least one activating organic solvent; and (E) optionally, at least one base.
摘要翻译：通过芳族羟基化合物与一氧化碳和氧气的氧化羰基化催化生产碳酸二芳酯的方法通过包括以下步骤的方法在反应过程中实现水去除：在反应容器（1）中从氧化羰基化反应混合物中除去液体物流，，使液体物流减压，并将至少一部分干燥的液体物流返回到反应容器（1）。用于氧化羰基化的典型催化剂体系包含（A）至少一种原子数为至少44的第8,9或10族金属或其化合物; （B）至少一种碱金属盐; （C）至少一种金属助催化剂; （D）至少一种活化有机溶剂; 和（E）任选的至少一个碱。

33. 发明申请

WO0244122A2 METHOD AND CATALYST SYSTEM FOR PRODUCING AROMATIC CARBONATES 审中-公开
标题翻译：生产芳香族碳酸盐的方法和催化剂体系
公开(公告)号：WO0244122A2
公开(公告)日：2002-06-06
申请号：PCT/US0150668
申请日：2001-10-19
申请人： GEN ELECTRIC
发明人： SHALYAEV KIRILL VLADIMIROVICH , SOLOVEICHIK GRIGORII LEV , JOHNSON BRUCE FLETCHER
IPC分类号： B01J31/26 , B01J31/22 , B01J31/28 , B01J31/30 , B01J31/38 , B01J37/04 , C07B61/00 , C07C68/00 , C07C69/96
CPC分类号： B01J31/1616 , B01J23/44 , B01J23/8926 , B01J31/2234 , B01J31/26 , B01J31/28 , B01J31/30 , B01J31/38 , B01J2231/4288 , B01J2531/16 , B01J2531/46 , B01J2531/80 , B01J2531/824 , C07C68/005 , C07C69/96
摘要： A method and catalyst system for economically producing aromatic carbonates from aromatic hydroxy compounds is disclosed. In one embodiment, the present invention provides a method of carbonylating aromatic hydroxy compounds by contacting at least one aromatic hydroxy compound with oxygen and carbon monoxide in the presence of a carbonylation catalyst system that includes an effective amount of at least one Group 8, 9, or 10 metal source; an effective amount of at least one bromide composition; an effective amount of at least one activating organic solvent; an effective amount of a combination of inorganic co-catalysts comprising at least one titanium source and at least one copper source, and an effective amount of at least one base.
摘要翻译：公开了一种从芳族羟基化合物经济生产芳族碳酸酯的方法和催化剂体系。在一个实施方案中，本发明提供了一种通过使至少一种芳族羟基化合物与氧气和一氧化碳在羰基化催化剂体系存在下接触来羰基化芳族羟基化合物的方法，所述羰基化催化剂体系包含有效量的至少一种第8,9，或10金属源; 有效量的至少一种溴化物组合物; 有效量的至少一种活化有机溶剂; 有效量的包含至少一种钛源和至少一种铜源的无机助催化剂和有效量的至少一种碱的组合。

34. 发明申请

WO02038271A1 METHOD FOR RECYCLE OF BROMIDE-CONTAINING CATALYST CONSTITUENTS 审中-公开
标题翻译：含有含羧酸的催化剂组分的回收方法
公开(公告)号：WO02038271A1
公开(公告)日：2002-05-16
申请号：PCT/US2001/032291
申请日：2001-10-16
IPC分类号： B01J38/60 , B01J31/26 , B01J31/40 , B01J38/00 , C07C68/00 , C07C68/08
CPC分类号： C07C68/08 , C07C68/005 , Y02P20/584 , C07C69/96
摘要： Bromide source such as alkali metal bromide or onium bromide, present as part of a catalyst mixture in an organic oxidative carbonylation mixture further comprising diaryl carbonate and a hydroxyaromatic compound, is often at least partially converted to organic bromide such as bromophenols. The bromide source can be recycled after reaction through treatment with an aqueous acidic bromide solution such as hydrogen bromide, preferably after removal of a major proportion of a major proportion of hydroxyaromatic compound such as phenol.
摘要翻译：在进一步包含碳酸二芳基酯和羟基芳族化合物的有机氧化羰基化混合物中作为催化剂混合物的一部分存在的溴化物源如溴化金属或溴化物通常至少部分转化成有机溴化物，如溴酚。溴化物源可以通过用酸性溴化氢水溶液如溴化氢处理反应后，优选在除去主要比例的主要比例的羟基芳族化合物如苯酚之后再循环。

35. 发明申请

WO0179149A3 CATALYST COMPOSITION AND METHOD FOR PRODUCING DIARYL CARBONATES, USING BISPHOSPHINES 审中-公开
标题翻译：催化剂组合物和使用双磷酸盐生产二元碳酸盐的方法
公开(公告)号：WO0179149A3
公开(公告)日：2002-03-28
申请号：PCT/US0140036
申请日：2001-02-06
申请人： GEN ELECTRIC
发明人： PATEL BEN PURUSHOTAM , SOLOVEICHIK GRIOGORII LEV , OFORI JOHN YAW
IPC分类号： C07C68/00 , B01J31/24 , C07C69/96
CPC分类号： C07C68/005 , C07C69/96
摘要： Hydroxyaromatic compounds such as phenol are carbonylated with oxygen and carbon monoxide in the presence of a catalyst system comprising a Group VIIIB metal, preferably palladium; an iodide salt, preferably sodium iodide; and at least one organic bisphosphine such as 1,3-bis(diphenylphosphino)propane or 1,4-bis(diphenylphosphino)butane. The catalyst system also preferably contains a compound of cerium or lead.
摘要翻译：在含有VIIIB族金属，优选钯的催化剂体系的存在下，用氧和一氧化碳将羟基芳族化合物如苯酚羰基化; 碘化物盐，优选碘化钠; 和至少一种有机双膦，如1,3-双（二苯基膦基）丙烷或1,4-双（二苯基膦基）丁烷。催化剂体系还优选含有铈或铅的化合物。

36. 发明申请

WO01079149A2 CATALYST COMPOSITION AND METHOD FOR PRODUCING DIARYL CARBONATES, USING BISPHOSPHINES 审中-公开
标题翻译：催化剂组合物和使用双磷酸盐生产二元碳酸盐的方法
公开(公告)号：WO01079149A2
公开(公告)日：2001-10-25
申请号：PCT/US2001/040036
申请日：2001-02-06
IPC分类号： C07C68/00 , B01J27/185 , C07C69/96
CPC分类号： C07C68/005 , C07C69/96
摘要： Hydroxyaromatic compounds such as phenol are carbonylated with oxygen and carbon monoxide in the presence of a catalyst system comprising a Group VIIIB metal, preferably palladium; an iodide salt, preferably sodium iodide; and at least one organic bisphosphine such as 1,3-bis(diphenylphosphino)propane or 1,4-bis(diphenylphosphino)butane. The catalyst system also preferably contains a compound of cerium or lead.
摘要翻译：在含有VIIIB族金属，优选钯的催化剂体系的存在下，用氧和一氧化碳将羟基芳族化合物如苯酚羰基化; 碘化物盐，优选碘化钠; 和至少一种有机双膦，如1,3-双（二苯基膦基）丙烷或1,4-双（二苯基膦基）丁烷。催化剂体系还优选含有铈或铅的化合物。

37. 发明申请

WO00066531A1 METHOD AND CATALYST SYSTEM FOR PRODUCING AROMATIC CARBONATES 审中-公开
标题翻译：用于生产芳族碳酸盐的方法和催化剂体系
公开(公告)号：WO00066531A1
公开(公告)日：2000-11-09
申请号：PCT/US2000/008961
申请日：2000-04-05
IPC分类号： B01J31/22 , B01J23/60 , B01J31/26 , C07B61/00 , C07C68/00 , C07C69/96
CPC分类号： B01J31/2234 , B01J23/60 , B01J31/0231 , B01J31/0239 , B01J31/0251 , B01J31/0271 , B01J2231/34 , B01J2531/16 , B01J2531/26 , B01J2531/38 , B01J2531/46 , B01J2531/48 , B01J2531/54 , B01J2531/62 , B01J2531/72 , B01J2531/821 , B01J2531/822 , B01J2531/824 , B01J2531/842 , B01J2531/845 , B01J2531/847 , C07C68/005 , C07C69/96
摘要： A method and catalyst system for economically producing aromatic carbonates from aromatic hydroxy compounds. In one embodiment, the present invention provides a method of carbonylating aromatic hydroxy compounds by contacting at least one aromatic hydroxy compound with oxygen and carbon monoxide in the presence of a carbonylation catalyst system that includes a catalytic amount of an inorganic co-catalyst containing zinc. In various alternative embodiments, the carbonylation catalyst system can include an effective amount of a palladium source and an effective amount of a halide composition. Further alternative embodiments can include catalytic amounts of various inorganic co-catalyst combinations.
摘要翻译：用于从芳族羟基化合物经济地生产芳族碳酸酯的方法和催化剂体系。在一个实施方案中，本发明提供了一种通过在包含催化量的含锌无机助催化剂的羰基化催化剂体系的存在下使至少一种芳族羟基化合物与氧和一氧化碳接触而使芳族羟基化合物羰基化的方法。在各种替代实施方案中，羰基化催化剂体系可以包括有效量的钯源和有效量的卤化物组合物。另外的替代实施方案可以包括催化量的各种无机助催化剂组合。

38. 发明申请

WO00037415A1 PROCESS FOR THE PRODUCTION OF DIARYL CARBONATES 审中-公开
标题翻译：生产二氧化碳的方法
公开(公告)号：WO00037415A1
公开(公告)日：2000-06-29
申请号：PCT/US1999/022839
申请日：1999-10-01
IPC分类号： B01J31/04 , C07B61/00 , C07C68/00 , C07C69/96
CPC分类号： C07C68/005 , C07C69/96
摘要： The method of the present invention comprises reaction of a gaseous mixture of oxygen and carbon monoxide with an aromatic hydroxy compound in the presence of a catalyst under controlled pressure, wherein the partial pressure of oxygen is optimized to effect increased yields at reduced overall pressure.
摘要翻译：本发明的方法包括氧气和一氧化碳的气体混合物与芳族羟基化合物在催化剂存在下在受控压力下的反应，其中氧气的分压被优化以在降低的总压力下实现增加的产率。

39. 发明申请

WO9908786A8 SUPPORTED CATALYSTS CONTAINING A PLATINUM GROUP METAL AND METHOD FOR PRODUCING DIARYLCARBONATES 审中-公开
标题翻译：含铂载体催化剂和制备碳酸二芳基酯的方法
公开(公告)号：WO9908786A8
公开(公告)日：1999-05-14
申请号：PCT/EP9804861
申请日：1998-08-05
申请人： BAYER AG , HESSE CARSTEN , NOTHEIS ULRICH , RECHNER JOHANN
发明人： HESSE CARSTEN , NOTHEIS ULRICH , RECHNER JOHANN
IPC分类号： B01J23/68 , B01J23/56 , B01J23/63 , B01J23/656 , B01J37/03 , C07C68/00 , C07C69/96
CPC分类号： B01J37/036 , B01J23/56 , B01J23/6562 , C07C68/005 , C07C69/96
摘要： The invention relates to supported catalysts containing a metal from the platinum group. The catalyst supports contain mixed oxides of metals, transition metals and semiconducting elements which can act as redox catalysts in reaction conditions, and were produced in a sol-gel process. The invention also relates to the use of the supported catalysts in methods for producing diarylcarbonates by reacting aromatic hydroxy compounds with carbon monoxide and oxygen.
摘要翻译：本发明涉及的铂金属含载体催化剂，用于制备含有金属，过渡金属和半导体元件的混合氧化物，其可以充当反应的条件下为氧化还原催化剂和在溶胶 - 凝胶方法制备的支持，并在工艺中使用负载型催化剂的碳酸二芳基酯通过芳香族羟基化合物与一氧化碳和氧的反应而得到。

40. 发明申请

WO99006142A1 CATALYST AND PROCESS FOR THE PREPARATION OF AROMATIC CARBONATES 审中-公开
标题翻译：催化剂和制备芳族碳酸盐的方法
公开(公告)号：WO99006142A1
公开(公告)日：1999-02-11
申请号：PCT/JP1998/003473
申请日：1998-08-04
IPC分类号： B01J23/00 , B01J23/56 , B01J23/656 , B01J23/89 , C07C68/00 , B01J23/44 , B01J23/64 , C07C69/96
CPC分类号： C07C68/005 , B01J23/002 , B01J23/56 , B01J23/6562 , B01J23/8933 , B01J2523/00 , C07C69/96 , B01J2523/44 , B01J2523/48 , B01J2523/24 , B01J2523/3706 , B01J2523/3712 , B01J2523/72 , B01J2523/845 , B01J2523/3725 , B01J2523/25 , B01J2523/17 , B01J2523/3718 , B01J2523/824
摘要： Aromatic carbonates can be prepared economically and efficiently by reacting an aromatic hydroxyl compound with carbon monoxide and oxygen in the presence of a catalyst which comprises a perovskitic composite oxide represented by the following general formula (1): M(1-x)M'xM''Oy (wherein M is a group IIIB metal; x is a number of 0 to 1; M' is a metal having an ionic radius of 0.90 ANGSTROM or above; M'' is Mn, Cr, Co, Fe, Ni or Cu; and y is a number of 2.5 to 3.5) or formula (1'): L(1-x)L'xL''Oy (wherein L is a group IIA or IVA metal taking a divalent state in the form of an oxide; x is a number of 0 to 1; L' is a metal having an ionic radius of 0.90 ANGSTROM or above; L'' is a group IVA, IVB or IIIB metal taking a tetravalent state in the form of an oxide; and y is a number of 2.5 to 3.5) and a palladium compound supported on the composite oxide and in which palladium accounts for 0.01 to 15 % by weight of the catalyst.
摘要翻译：芳香族碳酸酯可以通过使芳族羟基化合物与一氧化碳和氧在催化剂存在下反应来制备，所述催化剂包含由以下通式（1）表示的钙钛矿型复合氧化物：M（1-x）M'xM 'Oy（其中M是IIIB族金属; x是0-1的数; M'是离子半径为0.90或更大的金属; M“是Mn，Cr，Co，Fe，Ni或 Cu; y为2.5〜3.5的数）或式（1'）：L（1-x）L'xL'Oy（其中L为IIA或IVA族金属，氧化物; x为0〜1的数; L'为离子半径为0.90以上的金属，L“为氧化物呈四价状态的IVA，IVB，IIIB族金属， y为2.5〜3.5的数）和负载在复合氧化物上的钯化合物，其中钯占催化剂的0.01〜15重量％。

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