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    • 33. 发明申请
    • MULTICOMPONENT NANOPARTICLES FORMED USING A DISPERSING AGENT
    • 用分散剂形成多组分纳米粒子
    • WO2007001418A2
    • 2007-01-04
    • PCT/US2005037545
    • 2005-10-19
    • HEADWATERS NANOKINETIX INCZHOU BINGPARASHER SUKESHRUETER MICHAEL
    • ZHOU BINGPARASHER SUKESHRUETER MICHAEL
    • B01J23/00
    • B01J35/0013B01J21/18B01J23/8906B01J23/8933B01J23/8946B01J35/006B01J37/0203B01J37/18B82Y30/00B82Y40/00
    • Nanoparticles include a plurality of two or more dissimilar components selected from the group of noble metals, base transition metals, alkali earth metals, and rare earth metals and/or different groups of the periodic table of elements. The two or more dissimilar components are dispersed using a dispersing agent such that the nanoparticles have a substantially uniform distribution of the two or more dissimilar components. The dispersing agents can be poly functional small organic molecules, polymers, or oligomers, or salts of these. The molecules of the dispersing agent bind to the particle atoms to overcome same-component attractions, thereby allowing dissimilar components to form heterogeneous manoparticles. Dissimular components such as iron and platinum can be complexed using the dispersing agent to form sbstantially uniform heterogeneous nanoparticles. The nanoparticles can be used alone or applied to a support. At least a portion of the dispersing agent can be removed by reduction and/or oxidation.
    • 纳米颗粒包括多种选自贵金属,碱过渡金属,碱土金属和稀土金属和/或元素周期表的不同基团的两种或更多种不同组分。 使用分散剂分散两种或更多种不同组分,使得纳米粒子具有两种或更多种不同组分的基本均匀分布。 分散剂可以是多官能小有机分子,聚合物或低聚物或这些的盐。 分散剂的分子与粒子原子结合以克服相同成分的吸引力,由此允许不相似的组分形成不均匀的人造粒子。 可以使用分散剂使异物组分如铁和铂复合以形成基本均匀的非均相纳米粒子。 纳米颗粒可以单独使用或应用于支持物。 至少一部分分散剂可以通过还原和/或氧化除去。
    • 37. 发明申请
    • CATALYST FOR PURIFYING ENGINE EXHAUST GASES
    • 用于净化发动机排气的催化剂
    • WO2004073856A1
    • 2004-09-02
    • PCT/RU2004/000008
    • 2004-01-14
    • B01J23/89
    • B01J23/8933B01D53/945B01J23/002B01J23/63B01J23/64B01J23/648B01J23/656B01J35/0006B01J2523/00Y02T10/22B01J2523/11B01J2523/25B01J2523/3706B01J2523/3712B01J2523/55B01J2523/68B01J2523/72B01J2523/69B01J2523/845B01J2523/23B01J2523/48B01J2523/54B01J2523/56B01J2523/22B01J2523/44B01J2523/847
    • The inventive catalyst for purifying gasoline and diesel engine sulfur oxide-containing exhaust gases comprises a modular porous carrier or filter provided with a catalytically active layer. In order to increase the catalyst stability, in addition to platinum and palladium, complex oxides of base metals like lithium, potassium, magnesium, barium, lead, lanthanum, cerium and bismuth, and of transition metals like nickel, cobalt, manganese, vanadium, niobium, molybdenum and tungsten are added into the catalytically active layer, the modular carrier being formed from acid-resistant porous ceramics based on aluminium, boron, phosphorus and silicium oxides embodied in the form of a module or filter. The inventive technical solution combines the functions of a stable three-functional catalyst and a filter-accumulator of smoke black particles and sulphuric-acid compounds, and carries out the catalytic regeneration of the filter at a normal and high engine load. The inventive catalyst can be used for reducing the emission of most toxic exhaust gases and solid particles of a diesel engine when it is combined with partial recirculation of purified exhaust gases.
    • 用于净化汽油和柴油机含硫氧化物的废气的本发明催化剂包括设置有催化活性层的模块化多孔载体或过滤器。 为了提高催化剂稳定性,除了铂和钯之外,还可以使用诸如锂,钾,镁,钡,铅,镧,铈和铋的贱金属的复合氧化物,以及过渡金属如镍,钴,锰,钒, 铌,钼和钨被添加到催化活性层中,模块化载体由基于以模块或过滤器形式体现的铝,硼,磷和氧化硅的耐酸性多孔陶瓷形成。 本发明的技术方案结合了稳定的三功能催化剂和烟黑颗粒和硫酸化合物的过滤器的功能,并在正常和高的发动机负荷下进行过滤器的催化再生。 当本发明的催化剂与净化废气的部分再循环相结合时,可用于减少柴油发动机的大部分有毒废气和固体颗粒的排放。