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31. 发明申请

WO2017167705A1 METHOD FOR THE MANUFACTURE OF FLUORINATED COMPOUNDS 审中-公开
标题翻译：制备氟化合物的方法
公开(公告)号：WO2017167705A1
公开(公告)日：2017-10-05
申请号：PCT/EP2017/057238
申请日：2017-03-28
申请人： SOLVAY SPECIALTY POLYMERS ITALY S.P.A.
发明人： GALIMBERTI, Marco , TORTELLI, Vito , ANTENUCCI, Emanuela , MARCHIONNI, Giuseppe
IPC分类号： C07C68/00 , C07C51/41 , C07C69/96 , C07C59/135
摘要： A method for the manufacture of perfluorinated compounds is herein disclosed. In particular, the method is useful for the manufacture of perfluorooxyalkyl carboxylic acid salts which can be used as surfactants. The method envisages the fluorination or a fluoroformate of an alcohol comprising a -CH 2 OCH 2 -moiety at a temperature equal to or higher than 20°C and allows obtaining high yields and selectivity.
摘要翻译：本文公开了一种用于制造全氟化合物的方法。特别地，该方法可用于制造可用作表面活性剂的全氟氧基烷基羧酸盐。该方法设想了在等于或高于20℃的温度下氟化或包含-CH 2 OCH 2 - 部分的醇的氟甲酸酯，并且允许获得高收率和选择性。

32. 发明申请

WO2015155264A1 PROCESS FOR THE MANUFACTURE OF ALPHA-IODOPERFLUOROALKANES AND ALPHA,OMEGA-DIIODOPERFLUOROALKANES 审中-公开
标题翻译：阿尔法 - 碘酸盐和阿尔法，欧米伽二氧化物歧化酶的制备方法
公开(公告)号：WO2015155264A1
公开(公告)日：2015-10-15
申请号：PCT/EP2015/057655
申请日：2015-04-09
申请人： SOLVAY SPECIALTY POLYMERS ITALY S.P.A.
发明人： ANTENUCCI, Emanuela , BRAGANTE, Letanzio , GALIMBERTI, Marco , TORTELLI, Vito
IPC分类号： C07C17/278
CPC分类号： C07C17/278 , C07C17/087 , C07C17/272 , Y02P20/142 , C07C19/16
摘要： The invention relates to a process for the manufacture of a-iodoperfluoroalkanes and α,ω-diiodoperfluoroalkanes of general formula: (l) A(C 2 F 4 ) n l, wherein: A is selected from F, CF 3 and I and n is an integer equal to or higher than 1, with the proviso that, when A is F, n is an integer higher than 1 said process comprising heating a mixture [mixture (M1)] containing: - a compound selected from I 2 , CF 3 I, CF 3 CF 2 I and C 2 F 4 I 2 ; - TFE; - and CO 2 at definite temperatures and concentrations of CO 2 .
摘要翻译：本发明涉及一种制备α-碘全氟烷烃和通式为（1）A（C 2 F 4）nl的α，ω-二碘全氟烷烃的方法，其中：A选自F，CF 3和I，n是等于或高于1，条件是当A为F时，n为高于1的整数，所述方法包括加热含有： - 选自I2，CF3I，CF3CF2I和C2F4I2的化合物的混合物[混合物（M1）]; - TFE; - 和二氧化碳在确定的温度和二氧化碳浓度。

33. 发明申请

WO2014023611A1 ALLYL-BEARING FLUORINATED IONOMERS 审中-公开
标题翻译： ALLYL轴承氟化离子
公开(公告)号：WO2014023611A1
公开(公告)日：2014-02-13
申请号：PCT/EP2013/065980
申请日：2013-07-30
申请人： SOLVAY SPECIALTY POLYMERS ITALY S.P.A.
发明人： MERLO, Luca , TORTELLI, Vito , WLASSICS, Ivan , OLDANI, Claudio
IPC分类号： C07C209/00 , C08J5/22 , C08F216/14
CPC分类号： C07C217/46 , C07C41/30 , C07C43/17 , C07C213/02 , C08F216/1466 , C08G65/007 , C08J5/2237 , C08F214/262 , C08F216/125
摘要： The present invention provides a fluorinated ionomer [polymer (I)] comprising recurring units derived from at least the following monomers: (i) 5 to 50 % by weight of a fluorinated monomer [monomer (A)] containing at least one -SO 2 X functionality, preferably having the formula of CF 2 =CF-O-(CF 2 CF(CF 3 )O) m -(CF 2 ) n SO 2 X (I) wherein m is 0 or 1, n is an integer between 0-10, and X is selected from F, OH, and O - Me + , wherein Me + indicates an alkali metal ion or an ammonium cation of formula NR 4 + where each R independently represents a hydrogen atom or a monovalent organic radical selected from aliphatic radicals having from 1 to 8 carbon atoms and arylic or alicyclic radicals having from 3 to 8 carbon atoms; (ii) a non-functional fluorinated monomer [monomer (B)] having at least one ethylene unsaturation; and (iii) a fluorinated polyfunctional compound having the general formula: (CR 1 R 2 =CFCF 2 -O) a -R f -((O) c -CF=CR 3 R 4 ) b (ll) wherein: a is an integer equal to or larger than 1, preferably a is 1, 2, or 3; b is 0 or 1 and the sum of a and b is an integer equal to or larger than 2; c is 0 or 1; R 1 , R 2 , R 3 and R 4 are independently selected from F, H, alkyl, alkoxy, polyoxy alkyl, perfluoroalkyl, perfluoroalkoxy or perfluoropolyoxy alkyl, preferably F; and R f represents a hydrocarbon or fluorocarbon group having at least two carbon atoms. The low-EW perfluorinated ionomers made of polymer (I) are adapted to be processed into thin films, which are found to have superior physical stability than the existing products and are thus well suited for low humidity or high temperature electrochemical applications. Moreover, these low-EW ionomers are melt processable and have limited loss of volatile substances at their melt processing temperatures.
摘要翻译：本发明提供了含至少以下单体的重复单元的氟化离聚物[聚合物（I）]：（i）5-50重量％含有至少一个-SO 2 X官能团的氟化单体[单体（A）] 优选具有CF 2 = CF-O-（CF 2 CF（CF 3）O）m - （CF 2）n SO 2 X（I）的式（其中m为0或1），n为0-10之间的整数，X选自F ，OH和O-Me +，其中Me +表示式NR4 +的碱金属离子或铵阳离子，其中每个R独立地表示氢原子或选自具有1至8个碳原子的脂肪族基团的一价有机基团和芳基或具有3至8个碳原子的脂环族基团; （ii）具有至少一个乙烯不饱和度的非官能的氟化单体[单体（B）]; 和（iii）具有以下通式的氟化多官能化合物：（CR 1 R 2 = CFCF 2 -O）a -R f - （（O）c -CF = CR 3 R 4）b（II）其中：a是等于或大于1的整数优选a为1,2或3; b为0或1，a和b的和为等于或大于2的整数; c为0或1; R 1，R 2，R 3和R 4独立地选自F，H，烷基，烷氧基，聚氧烷基，全氟烷基，全氟烷氧基或全氟聚氧烷基，优选F; Rf表示具有至少2个碳原子的碳氢化合物或碳氟化合物。由聚合物（I）制成的低EW全氟化离聚物适于加工成薄膜，发现它们比现有产品具有优异的物理稳定性，因此非常适合于低湿度或高温电化学应用。此外，这些低EW离子聚合物是可熔融加工的，并且在其熔融加工温度下具有有限的挥发性物质损失。

34. 发明申请

WO2013087501A1 CROSSLINKABLE COMPOSITIONS BASED ON VINYLIDENE FLUORIDE-TRIFLUOROETHYLENE POLYMERS 审中-公开
标题翻译：基于乙烯基氟化物 - 三氟乙烯聚合物的交联组合物
公开(公告)号：WO2013087501A1
公开(公告)日：2013-06-20
申请号：PCT/EP2012/074632
申请日：2012-12-06
申请人： SOLVAY SPECIALTY POLYMERS ITALY S.p.A.
发明人： TORTELLI, Vito , MARRANI, Alessio , WLASSICS, Ivan , FALCO, Ivan
IPC分类号： C08K5/28
CPC分类号： C08F214/22 , C08J5/18 , C08J2327/24 , C08K5/28 , C08K5/43 , C08L27/16
摘要： The present invention relates to crosslinkable compositions comprising vinylidene fluoride (VDF)/trifluoroethylene (TrFE) polymers and a fluorine-containing crosslinking agent of formula (A) [agent (Cz)]: {N 3 [S(O) g1 ] s1 } na -(R H ) nh -R f -(R' H ) nh' -{[S(O) g2 ] s2 N 3 } na' formula (A) wherein each of g1 and g2, equal to or different from each other, is 1 or 2, each of s1 and s2, equal to or different from each other, is 0 or 1, each of na and na' is independently zero or an integer of 1 to 3, provided that the sum na+na' is at least 2, each of R H and R' H , equal to or different from each other, is a C 1 -C 12 hydrocarbon group free of fluorine atoms, nh and nh', equal or different from each other are independently 0 or 1, and R f is selected from the group consisting of i) a C 3 -C 20 fluorocarbon group, possibly comprising one or more ethereal oxygen atoms, ii) an oligomer comprising copolymerized units of vinylidene fluoride and trifluoroethylene, to a process for the manufacture of said compositions, to a method for curing the same, and to the use of said copolymers in electrical and electronic devices.
摘要翻译：本发明涉及包含偏二氟乙烯（VDF）/三氟乙烯（TrFE）聚合物和式（A）的含氟交联剂[试剂（Cz）]的交联组合物：{N 3 [S（O）g1] s1} - （RH）nh-Rf-（R'H）nh' - {[S（O）g2] s2N3} na'式（A）其中g1和g2各自相同或不同，为1或如图2所示，s1和s2中的每一个彼此等于或不同，为0或1，na和na'各自独立为0或1至3的整数，条件是和na + na'为至少2 RH和R'H彼此相同或不同，为不含氟原子的C1-C12烃基，nh和nh'彼此相同或不同，独立地为0或1，并且选择Rf 包括i）可能包含一个或多个醚性氧原子的C 3 -C 20碳氟化合物基团，ii）包含偏二氟乙烯和三氟乙烯的共聚单元的低聚物，用于制备所述组合物的方法，固化方法，以及在电气和电子设备中使用所述共聚物。

35. 发明申请

WO2012000853A1 PROCESS FOR THE SYNTHESIS OF TRIFLUOROETHYLENE 审中-公开
标题翻译：三氟乙烯合成方法
公开(公告)号：WO2012000853A1
公开(公告)日：2012-01-05
申请号：PCT/EP2011/060400
申请日：2011-06-22
申请人： SOLVAY SOLEXIS S.p.A. , MILLEFANTI, Stefano , TORTELLI, Vito , MARCHIONNI, Giuseppe
发明人： MILLEFANTI, Stefano , TORTELLI, Vito , MARCHIONNI, Giuseppe
IPC分类号： C07C17/23 , C07C21/18
CPC分类号： B01J23/44 , B01J21/18 , B01J23/42 , B01J35/023 , B01J35/1023 , B01J35/1028 , B01J37/0009 , B01J37/18 , C07C17/23 , C07C21/18
摘要： A catalytic process for the synthesis of trifluoroethylene from chlorotrifluoroethylene which comprises contacting chlorotrifluoroethylene with hydrogen in the presence of a catalyst consisting of palladium or platinum supported on extruded activated carbon.
摘要翻译：用于从三氟氯乙烯合成三氟乙烯的催化方法，其包括在负载在挤出的活性炭上的由钯或铂组成的催化剂存在下使氯三氟乙烯与氢接触。

36. 发明申请

WO2009150091A1 METHOD FOR MANUFACTURING PERFLUOROVINYLETHERS 审中-公开
标题翻译：制备全氟尿嘧啶的方法
公开(公告)号：WO2009150091A1
公开(公告)日：2009-12-17
申请号：PCT/EP2009/056858
申请日：2009-06-04
申请人： SOLVAY SOLEXIS S.P.A. , MILLEFANTI, Stefano , TORTELLI, Vito , MARCHIONNI, Giuseppe
发明人： MILLEFANTI, Stefano , TORTELLI, Vito , MARCHIONNI, Giuseppe
IPC分类号： C07C17/35 , C07C17/00 , C07C19/08
CPC分类号： C07C41/24 , C07D317/34 , C07C43/17
摘要： The invention pertains to a process for the manufacture of a perfluorovinylether by hydrodehalogenation of a halofluoroether (HFE) having general formula (I-A) or (I-B): R f O-CR f 'X-CR f ''R f '''X' (I-A) wherein R f represents a C 1 -C 6 perfluoro(oxy)alkyl group; R f ', R f " and R f "' equal or different from each other, independently represent fluorine atoms or C 1 -C 5 perfluoro(oxy)alkyl groups; X and X', equal or different from each other, are independently chosen among Cl, Br or I; formula (I-B); wherein R f * and R f *', equal or different from each other, independently represent fluorine atoms or C 1 -C 3 perfluoro(oxy)alkyl groups; Y 1 and Y 2 , equal or different from each other, independently represent fluorine atoms or C 1 -C 3 perfluoroalkyl groups; X and X' are as above defined; said process comprising contacting said halofluoroether (HFE) with hydrogen in the presence of a catalyst comprising at least one transition metal of group VIII B at a temperature of at most 340°C.
摘要翻译：本发明涉及通过具有通式（IA）或（IB）的卤代氟醚（HFE）的加氢脱卤制备全氟乙烯基醚的方法：RfO-CRf'X-CRf''Rf“'X'（IA），其中 Rf表示C1-C6全氟（氧）烷基; Rf'，Rf“和Rf”'彼此相同或不同，独立地表示氟原子或C1-C5全氟（氧）烷基; X和X'彼此相同或不同，独立地选自Cl，Br或I; 式（I-B）; 其中Rf *和Rf *'彼此相同或不同，独立地表示氟原子或C1-C3全氟（氧）烷基; Y1和Y2彼此相同或不同，独立地表示氟原子或C1-C3全氟烷基; X和X'如上所定义; 所述方法包括在包含至少一种第ⅧB族过渡金属的催化剂存在下，在至多340℃的温度下使所述卤代氟醚（HFE）与氢气接触。

37. 发明申请

WO2009087067A1 PROCESS FOR THE SYNTHESIS OF PERFLUOROBUTADIENE 审中-公开
标题翻译：过氧化物合成方法
公开(公告)号：WO2009087067A1
公开(公告)日：2009-07-16
申请号：PCT/EP2008/068288
申请日：2008-12-24
申请人： SOLVAY SOLEXIS S.P.A. , TORTELLI, Vito , MILLEFANTI, Stefano , CARELLA, Serena
发明人： TORTELLI, Vito , MILLEFANTI, Stefano , CARELLA, Serena
IPC分类号： C07C21/20 , C07C17/281 , C07C19/10 , C07C17/04 , C07C17/23 , C07C17/25
CPC分类号： C07C21/20 , C07C17/04 , C07C17/23 , C07C17/25 , C07C17/281 , Y02P20/582 , C07C19/10
摘要： Process for preparing perfluoro-1,3-butadiene, comprising the following steps : A) preparation of fluoro-halo-butanes of formula : CF 2 Y I -CFY II CFY II CF 2 Y I (V) in which Y I and Y II which may be identical or different, may be H, C1 or Br, with the condition that Y I and Y II are not simultaneously hydrogen; starting with a chloroolefin having the formula : CY'Y = CY'C1 (II) in which Y, Y', Y', which may be identical or different, are H, C1 or Br, with the condition that Y, Y', Y' are not simultaneously hydrogen; and performing the following steps : - a fluorodimerization, and - a fluorination with elemental fluorine, the order of the two steps also possibly being inverted, - a dehalogenation or dehydrohalogenation step being performed between the two steps, B) dehalogenation or dehydrohalogenation of the fluoro-halo compounds of formula (V) to give the compound perfluoro-1,3-butadiene.
摘要翻译：制备全氟-1,3-丁二烯的方法，包括以下步骤：A）制备其中可以相同或不同的YI和YII可以相同或不同的式：CF2YI-CFYIICFYIICF2 YI（V）的氟代 - H，C1或Br，条件是YI和YII不同时为氢; 以具有下式的CYIY = CY'C1（II）的氯烯烃开始，其中可以相同或不同的Y，Y'，Y'为H，C1或Br，条件是Y，Y' ，Y'不同时为氢; 并进行以下步骤： - 氟代二聚化和 - 用元素氟进行氟化，两个步骤的顺序也可能被反转， - 在两个步骤之间进行脱卤或脱卤化氢步骤，B）氟化脱卤或脱卤化氢（V）的卤代化合物，得到化合物全氟-1,3-丁二烯。

38. 发明申请

WO2010003931A1 PROCESS FOR THE MANUFACTURE OF FLUOROSURFACTANTS 审中-公开
标题翻译：制造氟化物的方法
公开(公告)号：WO2010003931A1
公开(公告)日：2010-01-14
申请号：PCT/EP2009/058536
申请日：2009-07-07
申请人： SOLVAY SOLEXIS S.p.A. , MARCHIONNI, Giuseppe , TORTELLI, Vito
发明人： MARCHIONNI, Giuseppe , TORTELLI, Vito
IPC分类号： C07C59/135 , C07C51/04
CPC分类号： C07C51/04 , C07C51/367 , C07C51/412 , C07C51/58 , C07C59/135
摘要： This invention pertains to a novel process for the manufacture of a perfluorooxycarboxylate of formula (I): R f O-CF 2 CF 2 -O-CF 2 -COOX a (I) wherein R f is a perfluoro(oxy)alkyl group, and Xa is H, a monovalent metal or an ammonium group of formula NR N 4 , with R N , equal or different at each occurrence, being H or a C 1-6 hydrocarbon group, said process comprising: (A) reacting a perfluorovinylether of formula R f -O-CF=CF 2 with an ethylene glycol derivative selected among ethylene glycol (HO-CH 2 CH 2 -OH), glycolic acid (HO-CH 2 -COOH), glycolaldheyde (HO-CH 2 -CHO) and protected derivatives thereof, so as to yield the corresponding addition product of formula R f -O-CFH-CF 2 -O-CH 2 -E, with R f having the same meaning as above detailed, and E being selected among -CH 2 OH, -COOH and -CHO; (B) optionally protecting functional group E with suitable chemistry; (C) fluorinating said (protected) addition product to yield the corresponding perfluorinated addition product; (D) optionally deprotecting said perfluorinated addition product to yield corresponding acyl fluoride of formula R f -O-CF 2 -CF 2 -O-CF 2 -C(O)F; (E) hydrolyzing and, optionally, neutralizing, said acyl fluoride for yielding the perfluorooxycarboxylate of formula (I).
摘要翻译：本发明涉及制备式（I）的全氟氧化羧酸酯的新方法：RfO-CF 2 CF 2 -O-CF 2 -COOa（I）其中Rf是全氟（氧）烷基，Xa是H，一价金属或NRN 4的铵基团，其中RN在每次出现时相同或不同，为H或C 1-6烃基，所述方法包括：（A）使式Rf-O-CF = CF 2的全氟乙烯基醚与选自乙二醇（HO-CH 2 CH 2 -OH），乙醇酸（HO-CH 2 -COOH），乙二醇醛（HO-CH2-CHO）及其保护的衍生物的乙二醇衍生物，得到相应的式Rf- O-CFH-CF2-O-CH2-E，其Rf具有与上述相同的含义，E选自-CH 2 OH，-COOH和-CHO; （B）任选地用合适的化学保护官能团E; （C）氟化所述（保护）加成产物以产生相应的全氟化加成产物; （D）任选地使所述全氟化加成产物脱保护，得到相应的式Rf-O-CF2-CF2-O-CF2-C（O）F的酰基氟; （E）水解和任选地中和所述酰氟以产生式（I）的全氟氧基羧酸酯。

39. 发明申请

WO2010003929A1 METHOD FOR MANUFACTURING FLUOROPOLYMERS 审中-公开
标题翻译：制造荧光体的方法
公开(公告)号：WO2010003929A1
公开(公告)日：2010-01-14
申请号：PCT/EP2009/058530
申请日：2009-07-06
申请人： SOLVAY SOLEXIS S.p.A. , MARCHIONNI, Giuseppe , TORTELLI, Vito , WLASSICS, Ivan , KAPELIOUCHKO, Valeri
发明人： MARCHIONNI, Giuseppe , TORTELLI, Vito , WLASSICS, Ivan , KAPELIOUCHKO, Valeri
IPC分类号： C08F14/18 , C07D317/10
CPC分类号： C07D317/34 , C07D317/42 , C08F14/18 , C08F114/26 , C08F2/24
摘要： The invention pertains to a method for making a fluoropolymer comprising an aqueous emulsion polymerization of one or more fluorinated monomers wherein said aqueous emulsion polymerization is carried out in the presence of at least one cyclic fluorocompound of the following formula (I): wherein X 1 , X 2 , X 3 , equal or different from each other are independently selected among H, F, and C 1-6 (per)fluoroalkyl groups, optionally comprising one or more catenary or non-catenary oxygen atoms; L represents a bond or a divalent group; R F is a divalent fluorinated C 1-3 bridging group; Y is a hydrophilic function selected among anionic functionalities, cationic functionalities and non-ionic functionalities.
摘要翻译：本发明涉及一种制备含氟聚合物的方法，该方法包括一种或多种氟化单体的水乳液聚合，其中所述水乳液聚合在至少一种下式（I）的环状氟化合物的存在下进行：其中X1，X2 各自独立地选自H，F和C 1-6（全）氟烷基，任选地包含一个或多个悬链或非链状氧原子的X 3相同或不同。 L表示键或二价基团; RF是二价氟化C1-3桥联基团; Y是选自阴离子官能团，阳离子官能团和非离子官能团的亲水性功能。

40. 发明申请

WO2009083451A1 ADDITION REACTION TO FLUOROALLYLFLUOROSULFATE 审中-公开
标题翻译：添加反应对氟氟草酸盐
公开(公告)号：WO2009083451A1
公开(公告)日：2009-07-09
申请号：PCT/EP2008/067714
申请日：2008-12-17
申请人： SOLVAY SOLEXIS S.P.A. , MARCHIONNI, Giuseppe , TORTELLI, Vito
发明人： MARCHIONNI, Giuseppe , TORTELLI, Vito
IPC分类号： C07D317/42 , C07C43/17 , C07C303/30 , C07C305/26 , C08F261/06 , C08F214/18
CPC分类号： C07D317/42 , C07C41/24 , C07C51/58 , C07C303/24 , C08F214/18 , C08F259/08 , C07C59/135 , C07C305/26 , C07C43/126
摘要： The invention pertains to a process for preparing compounds of formula (I-A) or (I-B) here below: by reaction of perfluoroallylfluorosulfate (FAFS) of formula (II): with at least one hypofluorite of formula (II-A) or (II-B): wherein: R F in formulae (I-A) and (II-A) is a monovalent fluorocarbon C 1 -C 20 group, optionally comprising oxygen catenary atoms, optionally comprising functional groups comprising heteroatoms (e.g. -SO 2 F groups); R' F in formulae (I-B) and (II-B) is a divalent fluorocarbon C- 1 -C 6 group, preferably a group of formula (III): wherein X 1 and X 2 , equal to or different from each other, are independently a fluorine atom or a C 1 -C 3 fluorocarbon group. The FAFS-hypofluohte adducts of formulae (I-A) and (I-B) can be produced with high selectivity so as to access useful intermediates which can further be reacted taking advantage of the un-modified fluorosulfate group chemistry.
摘要翻译：本发明涉及如下制备式（IA）或（IB）化合物的方法：通过式（II）的全氟代氟代硫酸盐（FAFS）与至少一种式（II-A）的次氟酸盐或（II- B）：其中：式（IA）和（II-A）中的RF是任选包含氧连接原子的任选包含杂原子的官能团（例如-SO 2 F基团）的单价碳氟化合物C1-C20基团; 式（IB）和（II-B）中的R'F是二价碳氟化合物C-1-C6基团，优选式（III）的基团：其中X1和X2彼此相同或不同，独立地为氟原子或C1-C3碳氟化合物基团。可以以高选择性制备式（I-A）和（I-B）的FAFS-低氧加合物，以便进入有用的中间体，其可以利用未改性的氟硫酸盐基团化学进一步反应。

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