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31. 发明申请

WO0245854A3 METHOD FOR PREPARING A CATALYST SUPPORT AND POLYMERIZATION WITH SUPPORTED CATALYSTS 审中-公开
标题翻译：用于制备催化剂支持的方法和具有支持的催化剂的聚合
公开(公告)号：WO0245854A3
公开(公告)日：2002-10-17
申请号：PCT/US0144939
申请日：2001-11-30
申请人： UNIVATION TECH LLC
发明人： PETERSON THOMAS HENRY , LUCAS ERIC
IPC分类号： C08F4/646 , B01J31/14 , B01J31/16 , B01J31/22 , B01J37/02 , C08F4/02 , C08F4/642 , C08F4/659 , C08F4/6592 , C08F210/16
CPC分类号： C08F210/16 , B01J31/143 , B01J31/1616 , B01J31/2295 , B01J37/0209 , B01J2531/48 , B01J2531/49 , C08F4/659 , C08F4/65912 , C08F4/6592 , C08F4/65925 , C08F4/02 , C08F4/65916 , C08F210/14
摘要： This invention relates to a method to support one or more catalyst compounds comprising contacting the catalyst compounds with a pretreatment agent comprising an aluminium alkyl and or an alumoxane in solution and thereafter contacting the combination with a supported activator.
摘要翻译：本发明涉及一种支持一种或多种催化剂化合物的方法，包括使催化剂化合物与包含烷基铝和铝氧烷的溶液中的预处理剂接触，然后使该组合与负载的活化剂接触。

32. 发明申请

WO0238629A8 POLYMERIZATION PROCESS 审中-公开
标题翻译：聚合工艺
公开(公告)号：WO0238629A8
公开(公告)日：2002-10-10
申请号：PCT/US0151006
申请日：2001-11-07
申请人： UNIVATION TECH LLC
发明人： MAWSON SIMON , SZUL JOHN FRANCIS , GOODE MARK GREGORY , WILLIAMS CLARK C
IPC分类号： C08F2/01 , C08F2/00 , C08F2/34 , C08F10/00 , C08F110/02
CPC分类号： B01J8/1827 , B01J4/002 , B01J2219/00108 , C08F10/00 , C08F110/02 , Y10S526/901 , C08F2/34 , C08F2500/12 , C08F2500/24
摘要： The present invention relates to a method to polymerize monomer comprising contacting one or more monomer(s) with a catalyst system in a gas phase reactor having a plenum and a recycle system for removing a recycle gas and unreacted monomer(s) from the reactor and returning the recycle gas and fresh monomers(s) to the reactor, the method comprising the steps of: (a) cooling the recycle gas to form a cooled recycle gas; (b) optionally combining the cooled recycle gas with additional recycle gas; and (c) injecting the cooled recycle gas into the gas phase reactor through the plenum.
摘要翻译：本发明涉及一种聚合单体的方法，包括使一种或多种单体与催化剂体系在气相反应器中接触，所述气相反应器具有充气室和用于从反应器中除去循环气体和未反应单体的再循环系统，将循环气体和新鲜单体返回反应器，该方法包括以下步骤：（a）冷却循环气体以形成冷却的循环气体; （b）任选地将冷却的再循环气体与另外的再循环气体组合; 和（c）通过增压室将冷却的再循环气体注入气相反应器。

33. 发明申请

WO0230993A3 METHOD AND APPARATUS FOR REDUCING STATIC CHARGES DURING POLYMERIZATION OF OLEFINS IN A FLUIDIZED BEDREACTOR 审中-公开
标题翻译：在流化床反应器中烯烃聚合中减少静电荷的方法和装置
公开(公告)号：WO0230993A3
公开(公告)日：2002-08-08
申请号：PCT/US0130459
申请日：2001-09-28
申请人： UNIVATION TECH LLC
发明人： BARTILUCCI MARK PETER , DAVIS EARNEST R JR , EGAN BRIAN J , HAGERTY ROBERT O , HUSBY PER K
IPC分类号： B01J8/00 , B01J8/24 , C08F2/00 , C08F2/34 , C08F10/00
CPC分类号： C08F10/00 , B01J8/003 , B01J8/1809 , B01J8/1872 , B01J2208/00256 , B01J2208/00274 , B01J2208/00734 , B01J2219/00186 , B01J2219/00202 , B01J2219/00213 , B01J2219/00231 , C08F2410/02 , C08F2/005 , C08F2/34
摘要： The present invention relates to a method and apparatus for controlling static charges in a fluidized bed olefin polymerization reactor. Static charges that develop in the polymer products are measured and, if they fall outside a predetermined range, static charge control agents are introduced into the reactor. By controllin the static charges in the reactor, sheeting and drooling can be controlled.
摘要翻译：本发明涉及在流化床烯烃聚合反应器中控制静电荷的方法和装置。测量在聚合物产品中产生的静电荷，并且如果它们落在预定范围之外，则将静电荷控制剂引入反应器中。通过控制反应器中的静电荷，可以控制片剂和流口水。

34. 发明申请

WO0246250A2 CATALYST COMPOSITION, METHOD OF POLYMERIZATION AND POLYMER THEREFROM 审中-公开
标题翻译：催化剂组合物，聚合方法和聚合物
公开(公告)号：WO0246250A2
公开(公告)日：2002-06-13
申请号：PCT/US0144394
申请日：2001-11-28
申请人： UNIVATION TECH LLC
发明人： SZUL JOHN FRANCIS , KWALK TAE HOON , SCHRECK DAVID JAMES , MAWSON SIMON , MCKEE MATTHEW GARY , TERRY KERSTEN ANNE , GOODE MARK GREGORY , WHITEKER GREGORY T , LUCAS ERIC
IPC分类号： C08J5/18 , C08F4/642 , C08F4/646 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F10/02 , C08F210/16 , C08L23/08
CPC分类号： C08F10/02 , C08F4/659 , C08F4/65912 , C08F4/65925 , C08F210/16 , C08L23/0815 , C08L2314/06 , Y10S526/943 , C08F2/34 , C08F4/65916 , C08F4/65904 , C08L2666/04 , C08F210/14 , C08F2500/12 , C08F2500/26
摘要： This invention relates to a process to polzmeriye olefin(s) comprising combining a solution, slurry or solid comprising one or more bulky ligand metallocenen catalyst compounds, an optional support, and one or more activator(s) with a solution comprising one or more phenoxide catalyst compounds, and thereafter, introducing one or more olefin(s) and the combination into a polymerization reactor. This invention also relates to a polymer of ethylene wherein the polymer has a density of 0.910 to 0.930 g/cc, an I2 melt index of 0.3 to 2.0 dg/min, and a 15 to 35 mu m thick film of the polymer has a 45 DEG gloss of 60 or more, a haze of 7 percent or less, and a dart impact of 600 g or more.
摘要翻译：本发明涉及一种聚合烯烃的方法，包括将包含一种或多种庞大配体金属茂催化剂化合物，任选的载体和一种或多种活化剂的溶液，浆料或固体与包含一种或多种酚盐催化剂化合物，然后将一种或多种烯烃和组合引入聚合反应器中。本发明还涉及一种乙烯聚合物，其中聚合物的密度为0.910至0.930g / cc，I2熔体指数为0.3至2.0dg / min，并且15至35μm厚的该聚合物膜具有45 DEG光泽度为60以上，雾度为7％以下，落镖冲击为600g以上。

35. 发明申请

WO0238629A2 POLYMERIZATION PROCESS 审中-公开
标题翻译：聚合工艺
公开(公告)号：WO0238629A2
公开(公告)日：2002-05-16
申请号：PCT/US0151006
申请日：2001-11-07
申请人： UNIVATION TECH LLC
发明人： MAWSON SIMON , SZUL JOHN FRANCIS , GOODE MARK GREGORY , WILLIAMS CLARK C
IPC分类号： C08F2/01 , C08F2/00 , C08F2/34 , C08F10/00 , C08F110/02
CPC分类号： B01J8/1827 , B01J4/002 , B01J2219/00108 , C08F10/00 , C08F110/02 , Y10S526/901 , C08F2/34 , C08F2500/12 , C08F2500/24
摘要： The present invention relates to a method to polymerize monomer comprising contacting one or more monomer(s) with a catalyst system in a gas phase reactor having a plenum and a recycle system for removing a recycle gas and unreacted monomer(s) from the reactor and returning the recycle gas and fresh monomers(s) to the reactor, the method comprising the steps of: (a) cooling the recycle gas to form a cooled recycle gas; (b) optionally combining the cooled recycle gas with additional recycle gas; and (c) injecting the cooled recycle gas into the gas phase reactor through the plenum.
摘要翻译：聚合单体的方法本发明涉及聚合单体的方法，该方法包括使一种或多种单体与催化剂体系接触，该气相反应器具有用于从反应器中除去循环气体和未反应单体的再循环系统，将再循环气体和新鲜单体返回到反应器中，所述方法包括以下步骤：（a）冷却循环气体以形成冷却的循环气体; （b）任选地将冷却的再循环气体与另外的再循环气体组合; 和（c）通过气室将冷却的循环气体注入气相反应器。

36. 发明申请

WO0037511A3 OLEFIN POLYMERIZATION CATALYST SYSTEM, POLYMERIZATION PROCESS AND POLYMER THEREFROM 审中-公开
标题翻译：烯烃聚合催化剂体系，聚合工艺及其聚合物
公开(公告)号：WO0037511A3
公开(公告)日：2000-11-09
申请号：PCT/US9927502
申请日：1999-11-19
申请人： UNIVATION TECH LLC
发明人： MURRAY REX E , MAWSON SIMON , WILLIAMS CLARK C , SCHRECK DAVID JAMES
IPC分类号： C08F2/34 , C08F4/64 , C08F4/659 , C08F10/00 , C08F210/16 , C08F4/60
CPC分类号： C08F210/16 , C08F4/65912 , C08F4/659 , C08F4/65904 , C08F210/14 , C08F2500/05 , C08F2500/12 , C08F2500/10
摘要： This invention relates to an olefin polymerization catalyst system comprising at least one activator and one of: a) at least two transition metal catalysts based on bidentate ligands containing pyridine or quinoline moieties, as described below as represented by formula (I), (II), (III) or (IV); b) the product of the combination of an activator and a transition metal catalyst based on bidentate ligands containing pyridine or quinolines moieties, such as those described as represented by formula (III) or (IV), that has been allowed to react prior to the introduction into the reactor, preferably for at least 15 minutes, and/or c) the product of combination of an additive and a transition metal catalyst based on bidentate ligands containing pyridine or quinoline moieties, such as those described below as represented by formula (I) or (II). This invention further relates to a polymer produced therefrom, particularly to unique polyethylene resins, more preferably bimodal high density polyethylene resins produced by this invention.
摘要翻译：本发明涉及烯烃聚合催化剂体系，其包含至少一种活化剂和以下物质中的一种：a）至少两种基于含吡啶或喹啉部分的二齿配体的过渡金属催化剂，如下式（I），（II），（III）或（IV）; b）活化剂和基于含吡啶或喹啉部分的二齿配体的活化剂和过渡金属催化剂的组合产物，例如由式（III）或（IV）表示的那些，其已经被允许在引入反应器中，优选至少15分钟，和/或c）基于含吡啶或喹啉部分的二齿配体的添加剂和过渡金属催化剂的组合产物，例如下式（I）所示的那些：）或（II）。本发明进一步涉及由其生产的聚合物，特别是涉及独特的聚乙烯树脂，更优选由本发明生产的双峰高密度聚乙烯树脂。

37. 发明申请

WO0037512A3 OLEFIN POLYMERIZATION CATALYSTS, THEIR PRODUCTION AND USE 审中-公开
标题翻译： OLEFIN聚合催化剂，其生产和使用
公开(公告)号：WO0037512A3
公开(公告)日：2000-10-19
申请号：PCT/US9929755
申请日：1999-12-14
申请人： UNIVATION TECH LLC
发明人： WHITEKER GREGORY T , SMITH JACK A
IPC分类号： C08F4/44 , C08F4/659 , C08F10/02 , C08F110/02 , C08F4/642
CPC分类号： C08F10/02 , C08F4/65908 , C08F4/65912 , C08F4/65916 , C08F110/02 , C08F210/16 , C08F4/64048 , C08F4/659 , C08F210/14
摘要： This invention relates to a catalyst system comprising an activator and one or more heteroatom substituted phenoxide group 3 to 10 transition metal or lanthanide metal compounds wherein the metal is bound to the oxygen of the phenoxide group and provided that: a) if more than one heteroatom substituted phenoxide is present it is not bridged to the other heteroatom substituted phenoxide; b) if the metal is a group 4 metal then the carbon adjacent to the carbon bound to the oxygen of the phenoxide may not be bound to an aldehyde or an ester c) the carbon ortho to the carbon bound to the oxygen of the phenoxide may not be bound to C1 carbon in group represented by formula: (I), wherein R and R are independently hydrogen, halogen, a hydrocarbon group, a heterocyclic compound residue, an oxygen containing group, a nitrogen containing group, a boron containing group, a sulfur containing group, a phosphorus containing group, a silicon containing group, a germanium containing group, or a tin containing group, and R and R may be bonded to each other to form a ring. The activator may be an aluminum alkyl, an alumoxane, a modified alumoxane, a non-coordinating anion, a borane, a borate or a mixture thereof.
摘要翻译：本发明涉及一种催化剂体系，其包括活化剂和一种或多种杂原子取代的苯酚基团3-10过渡金属或镧系元素金属化合物，其中金属与酚氧基团的氧结合，并且条件是：a）如果多于一个的杂原子存在取代的酚盐，其不与其它杂原子取代的苯酚交联; b）如果金属是4族金属，则与结合到酚氧的氧上的碳相邻的碳可能不与醛或酯结合c）与苯酚氧结合的碳的邻位碳可以不与式（I）表示的基团中的C1碳键合，其中R 6和R 7独立地是氢，卤素，烃基，杂环化合物残基，含氧基团，含氮基团，含硼基团，含硫基团，含磷基团，含硅基团，含锗基团或含锡基团，并且R 1和R 2可以彼此键合形成戒指。活化剂可以是烷基铝，铝氧烷，改性铝氧烷，非配位阴离子，硼烷，硼酸盐或它们的混合物。

38. 发明申请

WO0035967A3 CATALYST MODIFIER AND ITS USE IN THE POLYMERIZATION OF OLEFIN(S) 审中-公开
标题翻译：催化剂改性剂及其在烯烃聚合中的应用
公开(公告)号：WO0035967A3
公开(公告)日：2000-10-19
申请号：PCT/US9928185
申请日：1999-11-29
申请人： UNIVATION TECH LLC
发明人： WENZEL TIMOTHY T , SCHRECK DAVID JAMES , PETERSON THOMAS H
IPC分类号： C08F2/00 , C08F2/38 , C08F2/40 , C08F2/42 , C08F4/64 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F110/02
CPC分类号： C08F110/02 , C08F4/65912 , C08F4/65916 , C08F4/65927 , C08F10/00 , C08F2/40 , C08F4/6094 , C08F2/38
摘要： The present invention relates to the use of at least one solid compound that when used with a polymerization catalyst in a polymerization process results in a phase change of the solid compound to a liquid that renders the polymerization catalyst substantially or completely inactive.
摘要翻译：本发明涉及至少一种固体化合物在聚合过程中与聚合催化剂一起使用时导致固体化合物相变成使聚合催化剂基本上或完全失活的液体的用途。

39. 发明申请

WO2015123165A3 PRODUCING POLYOLEFIN PRODUCTS WITH IMPROVED STIFFNESS, TOUGHNESS, AND PROCESSABILITY 审中-公开
标题翻译：生产具有改善的刚性，韧性和可加工性的聚烯烃产品
公开(公告)号：WO2015123165A3
公开(公告)日：2015-10-08
申请号：PCT/US2015015120
申请日：2015-02-10
申请人： UNIVATION TECH LLC
发明人： LUE CHING-TAI , RIX FRANCIS C , BOLLER TIMOTHY M , GIESBRECHT GARTH R , GOODE MARK G , KAO SUN-CHUEH , LI DONGMING , PEQUENO R ERIC , ZILKER JR DANIEL P
IPC分类号： C08F2/34 , C08F4/6592 , C08F210/02 , C08F210/16 , C08J5/18
CPC分类号： C08F210/16 , C07F17/00 , C08F4/65904 , C08F4/65912 , C08F4/65916 , C08F4/65925 , C08F4/65927 , C08F4/76 , C08F210/02 , C08F210/08 , C08F210/14 , C08F2410/02 , C08F2420/00 , C08F2420/01 , C08F2500/01 , C08F2500/02 , C08F2500/08 , C08F2500/09 , C08F2500/10 , C08F2500/11 , C08F2500/12 , C08F2500/13 , C08F2500/18 , C08F2800/20 , C08L23/0815 , C08F2/00 , C08F2/34 , C08F2500/03
摘要： Polymers, and systems and methods for making and using the same are described herein. A polymer includes ethylene and at least one alpha olefin having from 4 to 20 carbon atoms. The polymer is formed by a trimmed catalyst system including a supported catalyst including bis(n-propylcyclopentadienyl) hafnium (R1)(R2) and a trim catalyst comprising meso-O(SiMe2lnd)2Zr2(R1)(R2), wherein R1 and R2 are each, independently, methyl, chloro, fluoro, or a hydrocarbyl group.
摘要翻译：本文描述了聚合物，以及制造和使用它们的系统和方法。聚合物包括乙烯和至少一种具有4-20个碳原子的α-烯烃。该聚合物通过包括含有双（正丙基环戊二烯基）铪（R1）（R2）的负载型催化剂和含有内消旋-O（SiMe2Ind）2Zr2（R1）（R2）的修饰催化剂的修整催化剂体系形成，其中R1和R2 各自独立地为甲基，氯，氟或烃基。

40. 发明申请

WO2014144397A2 HAFNOCENE CATALYZED POLYETHYLENE FILMS HAVING RAPID CLING DEVELOPMENT 审中-公开
标题翻译：具有快速发展的HAFNOCENE催化聚乙烯薄膜
公开(公告)号：WO2014144397A2
公开(公告)日：2014-09-18
申请号：PCT/US2014028790
申请日：2014-03-14
申请人： UNIVATION TECH LLC
发明人： FARLEY JAMES M , ADETUNJI PHILIP ADETOKUNBO , MIRAMS STEPHEN JAMES , BECKTON GERALD LINDEN
IPC分类号： C08J5/18
CPC分类号： C08F210/16 , B29C47/0021 , B29C47/0054 , B29C47/06 , B29K2023/06 , B29K2023/0625 , B29K2023/0633 , B29K2105/0088 , B29K2995/0081 , B29K2995/0098 , B29L2007/008 , B29L2009/00 , C08F4/65912 , C08F4/65925 , C08J5/18 , C08J2323/04 , C08J2323/08 , C08F4/65916 , C08F210/14 , C08F2500/12 , C08F2500/08 , C08F2500/26
摘要： Polyethylene films may include a polyethylene copolymer polymerized in the presence of a hafnium-based metallocene catalyst, wherein the polyethylene comprises a solubility distribution breadth index (SDBI) less than or equal to 23°C; a melt index (12) less than 1.5; a flow index (121) of from about 16 to about 28; and a melt flow ratio (121/12) of from about 18 to about 23. The film has a cling value that is at least 60% of a cling value the film has at 48 hours after time zero, and wherein time zero is equal to less than 24 hours.
摘要翻译：聚乙烯膜可以包括在铪基金属茂催化剂存在下聚合的聚乙烯共聚物，其中聚乙烯包含小于或等于23℃的溶解度分布宽度指数（SDBI）; 熔体指数（12）小于1.5; 流量指数（121）为约16至约28; 和熔体流动比（121/12）为约18至约23.薄膜的粘附值为薄膜在时间零点后48小时具有的粘附值的至少60％，其中时间零度相等至少24小时。

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