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    • 23. 发明申请
    • LIGHT MODULATING DEVICE HAVING A SILICON-CONTAINING MATRIX
    • 具有含硅基质的光调制装置
    • WO1995004791A1
    • 1995-02-16
    • PCT/US1994007360
    • 1994-06-30
    • MINNESOTA MINING AND MANUFACTURING COMPANY
    • MINNESOTA MINING AND MANUFACTURING COMPANYNERAD, Bruce, A.VESLEY, George, F.
    • C09K19/54
    • C09K19/544Y10T428/1068
    • In one aspect, an optically responsive film in which liquid crystal is dispersed in a matrix that includes siloxane linkages. The film has a transmissivity at -20 DEG C that is substantially the same as the transmissivity at 20 DEG C and a V90 at -20 DEG C that is less than twice the value at 20 DEG C. In another aspect, an optically responsive film in which liquid crystal is dispersed in a matrix that includes the polymerization product of at least one mercapto-functional siloxane. In another aspect, an optically responsive film in which liquid crystal is dispersed in a matrix that includes the polymerization product of at least one multi-functional ene and at least one multi-functional silicon hydride. In another aspect, an optically responsive film in which liquid crystal is dispersed in a matrix that includes the reaction product of at least one multi-functional vinyl silane and at least one multi-functional thiol.
    • 在一个方面,其中液晶分散在包含硅氧烷键的基质中的光学响应膜。 膜在-20℃下的透射率与20℃下的透过率和-20℃下的V90基本相同,小于20℃时的值的两倍。另一方面,光学响应性膜 其中液晶分散在包含至少一个巯基官能的硅氧烷的聚合产物的基质中。 在另一方面,一种光学响应性膜,其中液晶分散在包含至少一种多官能烯和至少一种多官能氢化硅的聚合产物的基质中。 在另一方面,一种光学响应性膜,其中液晶分散在包含至少一种多官能乙烯基硅烷和至少一种多官能硫醇的反应产物的基质中。
    • 25. 发明申请
    • ELECTRO-OPTICAL LIQUID CRYSTAL SYSTEM
    • 电光液晶系统
    • WO1991005029A1
    • 1991-04-18
    • PCT/EP1990001649
    • 1990-10-01
    • MERCK PATENT GESELLSCHAFT MIT BESCHRÄNKTER ...COATES, DavidMARDEN, ShirleySMITH, GrahamFINKENZELLER, UlrichREIFFENRATH, VolkerHITTICH, ReinhardWILHELM, Stefan
    • MERCK PATENT GESELLSCHAFT MIT BESCHRÄNKTER ...
    • C09K19/00
    • C09K19/12C09K19/3003C09K19/3028C09K19/42C09K19/44C09K19/544
    • An electro-optical liquid crystal system of the type P.D.L.C., N.C.A.P. or P.N. comprises a dielectrically positive liquid crystal mixture and another optically transparent medium between two electrodes which may be mounted on substrate plates. The liquid crystal mixture contains one or more compounds of formula (I), where Q is (a), (b) and (c) independently stand for trans-1,4-cyclohexylene, 1,4-phenylene, 2-fluor-1,4-phenylene, 3-fluor-1,4-phenylene and one of A and, if present, A also stands for pyridine-2,5-diyl, pyrimidine-2,5-diyl, 1,3-dioxane-2,5-diyl, tetrahydropyrane-2,5-diyl or naphthalene-2,6-diyl, Z and Z independently stand for a single bond, -CH2CH2-, -COO-, -OCO-, -C=C-, -CH2O- or any combination of these bridge groups, Y and X independently stand for H or F, one of X and Y also stands for Cl, W stands for -CN, -Cl, -F, -CF3, -OCF3, -OCHF2, -NCS or R , R and R independently stand for alkyl with 1 to 12 C atoms in which one or 2 non-neighbouring CH2 groups can also be replaced by -O- or -HC=CH-, and m = 0, 1 or 2.
    • 一种P.D.L.C.,N.C.A.P.的电光液晶体系。 或P.N. 包括介电正极液晶混合物和可以安装在基板上的两个电极之间的另一光学透明介质。 液晶混合物含有一种或多种式(I)化合物,其中Q 1是(a),(b)和(c)独立代表反式-1,4-亚环己基,1,4-亚苯基,2 1-氟-1,4-亚苯基,3-氟-1,4-亚苯基和A 1之一,如果存在,A 2也代表吡啶-2,5-二基,嘧啶-2,5 - 二基,1,3-二恶烷-2,5-二基,四氢吡喃-2,5-二基或萘-2,6-二基,Z 1和Z 2独立地表示单键,-CH 2 CH 2 - ,-COO-,-OCO-,-C = C-,-CH2O-或这些桥基的任何组合,Y和X独立地代表H或F,X和Y之一也代表Cl,W代表 - CN,-Cl,-F,-CF 3,-OCF 3,-OCHF 2,-NCS或R 2,R 1和R 2独立地代表具有1至12个C原子的烷基,其中一个或两个非 - - 相邻的CH2基团也可以被-O-或-HC = CH-取代,并且m = 0,1或2。
    • 27. 发明申请
    • ACRYLATE POLYMER-DISPERSED LIQUID CRYSTAL MATERIAL AND DEVICES MADE THEREFROM
    • 丙烯酸聚合物分散液晶材料及其制品
    • WO1989006371A2
    • 1989-07-13
    • PCT/US1988004150
    • 1988-11-21
    • HUGHES AIRCRAFT COMPANY
    • HUGHES AIRCRAFT COMPANYMILLER, Leroy, J.YAMAGISHI, Frederick, G.
    • G02F01/133
    • C09K19/544Y10T428/10
    • A composite material (22) includes droplets (24) of a liquid crystal material dispersed within a matrix (26) of a photopolymerized polymer. The material (22) is prepared by forming a solution of the liquid crystal material and a monomer, and then polymerizing the monomer with light. The solubility of the liquid crystal material in the polymer is less than in the monomer. As polymerization progresses, a portion of the liquid crystal material separates as a second phase in the polymer matrix (26). The liquid crystal can be any suitable such material that is soluble in the monomer and less so in the polymer, and the monomer is a polymerizable acrylate or methacrylate. Liquid crystal devices are prepared by forming the composite material between two electrically conducting substrates.
    • 复合材料(22)包括分散在光聚合聚合物的基体(26)内的液晶材料的液滴(24)。 通过形成液晶材料和单体的溶液,然后用光聚合单体来制备材料(22)。 液晶材料在聚合物中的溶解度小于单体中的溶解度。 随着聚合的进行,一部分液晶材料在聚合物基质(26)中作为第二相分离。 液晶可以是可溶于单体的任何合适的这种材料,而且在聚合物中较少,并且单体是可聚合的丙烯酸酯或甲基丙烯酸酯。 通过在两个导电基板之间形成复合材料来制备液晶装置。