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21. 发明申请

WO1989008649A1 HETEROCYCLIC 1,2-DIFLUOROBENZENE DERIVATIVES 审中-公开
标题翻译：杂环1,2-二氟苯甲醛衍生物
公开(公告)号：WO1989008649A1
公开(公告)日：1989-09-21
申请号：PCT/EP1989000190
申请日：1989-02-28
申请人： MERCK PATENT GESELLSCHAFT MIT BESCHRÄNKTER ... , REIFFENRATH, Volker , KRAUSE, Joachim , WÄCHTLER, Andreas , GEELHAAR, Thomas
发明人： MERCK PATENT GESELLSCHAFT MIT BESCHRÄNKTER ...
IPC分类号： C07D285/12
CPC分类号： C07D213/30 , C07D213/65 , C07D239/26 , C07D239/34 , C07D285/12 , C09K19/3444 , C09K19/3458 , C09K19/3497
摘要： Heterocyclic 1,2-difluorobenzene derivatives of formula (I), where R1 and R2 each denote, independently of each other, an alkyl group with 1 to 15 C atoms, in which one or more CH2 groups can also be replaced by a divalent residue chosen from the group consisting of -O-, -S-, -CO-, -O-CO-, -CO-O-, -CH=CH- and -C=C-, no two heteroatoms being directly linked to each other, A1 and A2 each denote, independently of each other, an unsubstituted 1,4-phenyl group or a 1,4-phenyl group substituted with one or more fluorine atoms, in which one or two CH groups can be replaced by N, a 1,3,4-thiadiazol-2,5-diyl group or a trans-1,4-cyclohexylene group, m and n are each equal to 0 or 2, o is equal to 0 or 1, and p is equal to 0, 1 or 2, whereby (o + p) is equal to 1, 2 or 3 and, when p = 2, the groups A2 and n can be identical or different, provided that at least one of the groups A1 and A2 is a 1,3,4-thiadiazol-2,5-diyl group or an unsubstituted or substituted 1,4-phenyl group, in which one or two CH groups are replaced by N, are suitable as components of liquid crystal phases.

22. 发明申请

WO1989008136A1 MECHANICAL STRUCTURAL MEMBER 审中-公开
标题翻译：机械结构件
公开(公告)号：WO1989008136A1
公开(公告)日：1989-09-08
申请号：PCT/EP1989000141
申请日：1989-02-16
申请人： MERCK PATENT GESELLSCHAFT MIT BESCHRÄNKTER ... , EIDENSCHINK, Rudolf
发明人： MERCK PATENT GESELLSCHAFT MIT BESCHRÄNKTER ...
IPC分类号： C09K19/00
CPC分类号： C10M171/00 , C09K19/00
摘要： A mechanical structural member is composed of mutually movable solid bodies with changing frictional force mutually separated by an organic fluid. The changes in frictional force are caused by phasse transitions between various thermotropic liquid crystal phases or between a thermotropic liquid crystal phase and an isotropic phase.
摘要翻译：机械结构构件由具有由有机流体相互分离的改变的摩擦力的相互移动的固体组成。摩擦力的变化是由各种热致液晶相之间或热致液晶相和各向同性相之间的晶界转变引起的。

23. 发明申请

WO1989005303A1 PROCESS FOR PRODUCING METALLIC ALKYL COMPOUNDS 审中-公开
标题翻译：生产金属烷基化合物的方法
公开(公告)号：WO1989005303A1
公开(公告)日：1989-06-15
申请号：PCT/EP1988001130
申请日：1988-12-09
申请人： MERCK PATENT GESELLSCHAFT MIT BESCHRÄNKTER ... , REIER, Friedrich-Wilhelm , SCHUMANN, Herbert , WOLFRAM, Peter
发明人： MERCK PATENT GESELLSCHAFT MIT BESCHRÄNKTER ...
IPC分类号： C07F05/00
CPC分类号： C07F5/00 , C07F5/062
摘要： Process producing metallic alkyl compounds of formula (I): MR3, where M stands for In, Ga or Al, and R stands for C1-10 alkyl, which may be branched chain, cyclic or unsaturated, and C6-10 aryl, whereby said compounds can be obtained with high yield and of particularly high purity suitable for epitaxy.

24. 发明申请

WO1989003867A1 IMPROVED LIQUID CRYSTAL MIXTURE 审中-公开
标题翻译：改进的液体混合物
公开(公告)号：WO1989003867A1
公开(公告)日：1989-05-05
申请号：PCT/EP1988000928
申请日：1988-10-15
申请人： CASIO COMPUTER COMPANY LIMITED , MERCK PATENT GESELLSCHAFT MIT BESCHRÄNKTER ... , YOSHIDA, Tetsushi , SCHEUBLE, Bernhard , OYAMA, Takamasa
发明人： CASIO COMPUTER COMPANY LIMITED , MERCK PATENT GESELLSCHAFT MIT BESCHRÄNKTER ...
IPC分类号： C09K19/02
CPC分类号： C09K19/0208 , C09K19/42
摘要： The invention relates to a twisted nematic liquid crystal display device operating in the high multiplex mode and having a high contrast, the improvement wherein the liquid crystal mixture has a ratio of the elastic constants K3/K1 as small as possible but not more than 0.9 and a ratio of DELTA epsilon / epsilon | of at most +0.3.
摘要翻译：本发明涉及以高复用模式操作并具有高对比度的扭曲向列型液晶显示装置，改进之处在于液晶混合物的弹性常数K3 / K1尽可能小但不超过0.9， DELTA epsilon / epsilon |的比率最多+0.3。

25. 发明申请

WO1989002425A1 FLUORINATED OLIGOPHENYLS AND THEIR USE IN LIQUID CRYSTAL MATERIALS 审中-公开
标题翻译：氟化玻璃及其在液晶材料中的应用
公开(公告)号：WO1989002425A1
公开(公告)日：1989-03-23
申请号：PCT/EP1988000724
申请日：1988-08-13
申请人： MERCK PATENT GESELLSCHAFT MIT BESCHRÄNKTER ... , GRAY, George, William , HIRD, Michael , LACEY, David , TOYNE, Kenneth, Johnson , REIFFENRATH, Volker , WÄCHTLER, Andreas , KRAUSE, Joachim , FINKENZELLER, Ulrich , GEELHAAR, Thomas
发明人： MERCK PATENT GESELLSCHAFT MIT BESCHRÄNKTER ...
IPC分类号： C07C25/18
CPC分类号： C09K19/12 , C09K19/126
摘要： This invention relates to fluorinated oligophenyls of formula (I), in which a is 0 or 1 and in which the terminal substituents R , R and R are each independently an alkyl or alkenyl residue each with up to 15 C atoms, optionally substituted by CN or by at least one halogen atom, and wherein one or more non adjacent CH2 groups of these residues may be replaced by -O-, -S-, -CO-, -O-CO-, -CO-O-, -O-CO-O- or -C=C-, one of the residues R and R may also denote a group of formula (II), any one of the following pairs of lateral substituents are both fluorine: (A, B), (C, D), (D, E), (C, E), (B, C), (D, J), (D, K), (A, C), (C, J), (C', D'), (D', E), (D', A), (C', E), (C', A), (D', J'), (D', K'), (C', J'), (B, G), (A, G), all of the other lateral substituents being hydrogen or fluorine, and to their use as components of liquid crystalline compositions.
摘要翻译：本发明涉及式（I）的氟化低聚苯基，其中a为0或1，其中末端取代基R 1，R 2和R 3各自独立地为烷基或烯基残基，各自独立地为至少15个C原子，任选地被CN或至少一个卤素原子取代，并且其中这些残基的一个或多个非相邻的CH 2基团可被-O - ， - S - ， - CO-，-O-CO- ，-CO-O-，-O-CO-O-或-C = C-，残基R 1和R 2之一也可以表示式（II）的基团，以下任何一个（A，B），（C，D），（D，E），（C，E），（B，C），（D，J），（D，K）（A，C），（C，J），（C'，D'），（D'，E），（D'，A），（C'，E），（C' '，J'），（D'，K'），（C'，J'），（B，G），（A，G），所有其它横向取代基是氢或氟，液晶组合物的组分。

26. 发明申请

WO1988007516A1 ETHINE DERIVATIVES AS COMPOUNDS OF LIQUID CRYSTAL PHASES 审中-公开
标题翻译：乙烯衍生物作为液晶相的化合物
公开(公告)号：WO1988007516A1
公开(公告)日：1988-10-06
申请号：PCT/EP1988000246
申请日：1988-03-25
申请人： MERCK PATENT GESELLSCHAFT MIT BESCHRÄNKTER ... , KURMEIER, Hans-Adolf , REIFFENRATH, Volker , POETSCH, Eike , KRAUSE, Joachim , WEBER, Georg
发明人： MERCK PATENT GESELLSCHAFT MIT BESCHRÄNKTER ...
IPC分类号： C07C43/225
CPC分类号： C07D213/30 , C07C13/28 , C07C23/18 , C07C25/24 , C07C43/215 , C07C43/225 , C07C255/00 , C07D213/16 , C07D213/65 , C07D231/16 , C07D237/08 , C07D237/12 , C07D239/26 , C07D239/34 , C07D241/16 , C09K19/3059 , C09K19/3098 , C09K19/321 , C09K19/3444 , C09K19/3455 , C09K19/3461
摘要： Ethine derivatives of the formula R -(A -Z )m-A -C=C-A -(Z -A )n-R , in which R = -OCF3'-OC2F4H or -OC2F5 are suitable as components of liquid crystal phases.
摘要翻译：式R 1 - （A 1 -Z 1）mA 3 -C = CA 4 - （Z 2 -A 2）n R 2的乙炔衍生物在其中R 2 = -OCF 3'-OC 2 F 4 H或-OC 2 F 5适合作为液晶相的组分。

27. 发明申请

WO1988007514A1 TOLANES 审中-公开
标题翻译：二苯乙炔
公开(公告)号：WO1988007514A1
公开(公告)日：1988-10-06
申请号：PCT/DE1988000133
申请日：1988-03-10
申请人： MERCK PATENT GESELLSCHAFT MIT BESCHRÄNKTER ... , REIFFENRATH, Volker , KRAUSE, Joachim , WEBER, Georg , HITTICH, Reinhard
发明人： MERCK PATENT GESELLSCHAFT MIT BESCHRÄNKTER ...
IPC分类号： C07C25/24
CPC分类号： C07C255/00 , C07C15/54 , C07C25/24 , C07C43/215 , C07C43/225 , C07C43/30 , C09K19/0216 , C09K19/12 , C09K19/18 , C09K19/3059 , C09K19/3068 , C09K19/3402 , C09K19/42 , C09K2019/3422
摘要： Tolanes having the formula (I): R -(A -Z )m-A -C=C-A -(A )n-R , in which R , A , Z , m, A , A , A , n and R are as given in claim (1), and application of said tolanes as components of liquid crystal phases, particularly as components of liquid crystal phases for electyro-optical display elements based on the ECB effect.
摘要翻译：具有式（I）的摩尔：R 1 - （A 1 -Z 1）mA 3 -C = CA 4 - （A 2）n R 2，其中R <1>，A 1，Z 1，m，A 3，A 4，A 2，n和R 2如权利要求（1）中所给出，并且所述作为液晶相的成分，特别是作为基于ECB效应的电子光学显示元件的液晶相的成分。

28. 发明申请

WO1988006178A1 ELECTRO-OPTICAL DISPLAY ELEMENT 审中-公开
标题翻译：电光显示元件
公开(公告)号：WO1988006178A1
公开(公告)日：1988-08-25
申请号：PCT/EP1988000090
申请日：1988-02-08
申请人： MERCK PATENT GESELLSCHAFT MIT BESCHRÄNKTER ... , WEBER, Georg , SCHEUBLE, Bernhard , EIDENSCHINK, Rudolf , WÄCHTLER, Andreas
发明人： MERCK PATENT GESELLSCHAFT MIT BESCHRÄNKTER ...
IPC分类号： C09K19/30
CPC分类号： C09K19/3491 , C09K19/3001 , C09K19/3098 , C09K19/3402 , C09K2019/3422
摘要： Compounds of formula (I): R1-A1-Z1-A-O-R2, where R1 and R2 are each independently alkyl with 1 to 9 carbon atoms, in which one or two CH2 groups may be replaced by -O-, -CO-, -O-CO-, -CO-O- and/or -CH=CH-, whereby two O atoms are not directly linked to each other, one of the two groups R1 and R2 is also H, Z1 is -CH2-O-, -OCH2-, -CH2CH2- or a simple bond, A1 is trans-1,4-cyclohexylene, in which one or two non-adjacent CH2 groups may be replaced by O and/or S, or 1,4-cyclohexenylene, and A is unsubstituted or fluorine-substituted 1,4-phenylene, can be used as components of crystalline liquid dielectrics with at least three crystalline liquid compounds for reduction of the turn-on time Ton of electro-optical display elements based on a TN-cell during commutation of a first voltage, which is less than or approximately equal to the threshold voltage, to a second voltage, which lies on the positive slope of the electro-optical charcteristic curve.

29. 发明申请

WO1988005803A1 LIQUID CRYSTALLINE MIXTURE 审中-公开
标题翻译：液晶混合
公开(公告)号：WO1988005803A1
公开(公告)日：1988-08-11
申请号：PCT/EP1988000048
申请日：1988-01-25
申请人： MERCK PATENT GESELLSCHAFT MIT BESCHRÄNKTER ... , SAGE, Ian, Charles , LEWIS, Stephen, John , CHAPLIN, Dominic
发明人： MERCK PATENT GESELLSCHAFT MIT BESCHRÄNKTER ...
IPC分类号： C09K19/52
CPC分类号： C09K19/42 , C09K19/54
摘要： Liquid crystalline mixtures with at least two liquid-crystalline compounds free of perfluoro alkylene groups and at least one partially fluorinated additive of formula (I): R -(CH2)m-(CF2)n-R , wherein m is 0 to 12, n is 1 to 16 and R and R each signify a group of formula (II), in which R is F or alkyl with 1-15 C atoms, being possible for one or two non-adjacent CH2 groups to be replaced by -O-, -CO-, -O-CO-, -CO-O-, -O-CO-O-, -C=C- and/or -CH=CH-, A and A in each case an unsubstituted, mono- or polysubstituted 1,4-cyclohexylene group, also possible for one or two non-adjacent CH2 groups to be replaced by -O- and/or -S-; or a 1,4-bicyclo-[2,2,2]octylene group, or a 1,4-phenylene group unsubstituted or substituted by one or two F and/or Cl atoms and/or CH3 groups and/or CN groups, being possible for one or two CH groups to be replaced by N, Z -CO-O-, -O-CO-, -CH2CH2-, -CHCN-CH2-, -CH2-CHCN-, -CH=CH-, -C=C-, -OCH2-, -CH2O, -CH=N-, -N=CH-, -N=N-, -NO=N-, -N=NO- or Z -CO-O-, -O-CO-, -CH2CH2-, -CHCN-CH2, -CH2-CHCN-, -CH=CH-, -C=C-, -OCH2-, -CH2O-, -CH=N-, -N=CH-, -N=N-, -NO=N-, -N=NO-, -(CH2)k-CO-O- or k 1 to 6, p: 0, 1, 2; q: 0, 1. R or R may also be H, with the proviso that m+p+q = 1 to 15. Means of reducing the refractive indices of a L.C. mixture by adding one or more additives of formula (I).
摘要翻译：具有至少两种不含全氟亚烷基的液晶化合物和式（I）的至少一种部分氟化的添加剂的液晶混合物：R 1 - （CH 2）m - （CF 2）n R 2，其中m是 0至12，n为1至16，R 1和R 2各自表示式（II）的基团，其中R为F或具有1-15个C原子的烷基，可能为一个或两个非相邻的CH 2基团被-O - ， - CO-，-O-CO-，-CO-O-，-O-CO-O-，-C≡C-和/或-CH = CH-取代，在每种情况下，A 1和A 2均为未取代的单取代或多取代的1,4-亚环己基，对于一个或两个不相邻的CH 2基团可以被-O-和/或-S- ; 或未取代或被一个或两个F和/或Cl原子和/或CH 3基团和/或CN基团取代的1,4-二环[2,2,2]亚辛基或1,4-亚苯基，一个或两个CH基团可被N，Z 1 -CO-O-，-O-CO - ， - CH 2 CH 2 - ， - CHCN-CH 2 - ， - CH 2 -CHCN-， - CH = CH - ， - C = C-，-OCH 2 - ， - CH 2 O，-CH = N - ， - N = CH-，-N = N-，-NO = N - ， - N = NO-或Z 2 - CO-O - ， - O - CO - ， - CH 2 CH 2 - ， - CHCN-CH 2，-CH 2 -CHCN-， - CH = CH-，-C≡C-，-OCH 2 - ， - CH 2 O-，-CH = N - ，-N = CH-，-N = N-，-NO = N - ， - N = NO-， - （CH 2）k-CO-O-或k 1至6，p：0,1,2; q：0,1，R 1或R 2也可以是H，前提条件是m + p + q = 1至15.降低L.C.的折射率的方法。混合物中加入一种或多种式（I）的添加剂。

30. 发明申请

WO1988004305A1 MATERIALS WITH NITROGENOUS SIX-MEMBERED RINGS 审中-公开
标题翻译：材料与硝基六成员环
公开(公告)号：WO1988004305A1
公开(公告)日：1988-06-16
申请号：PCT/EP1987000731
申请日：1987-11-26
申请人： MERCK PATENT GESELLSCHAFT MIT BESCHRÄNKTER ... , DORSCH, Dieter , EIDENSCHINK, Rudolf , RIEGER, Bernhard , MAROWSKY, Gerd
发明人： MERCK PATENT GESELLSCHAFT MIT BESCHRÄNKTER ...
IPC分类号： C08F08/30
CPC分类号： G02F1/3617 , C08F8/30 , C09K19/3833 , C09K19/3852 , G02F1/3612 , G02F1/3613
摘要： Nitrogenous compounds with six-membered rings having the formula (I) and polymer materials containing the organic residue of a compound having the formula (I) covalently linked therewith are suitable as non-linear optical media. In the formula (I), D, W, X, Y and Z have the meaning given in the first claim.

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