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21. 发明申请

WO2006120143A1 AZAPERYLENES AS ORGANIC SEMICONDUCTORS 审中-公开
标题翻译： AZAPERYLENES作为有机半导体
公开(公告)号：WO2006120143A1
公开(公告)日：2006-11-16
申请号：PCT/EP2006/062007
申请日：2006-05-03
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , BIENEWALD, Frank , SCHMIDHALTER, Beat , BERENS, Ulrich , KIRNER, Hans, Jürg
发明人： BIENEWALD, Frank , SCHMIDHALTER, Beat , BERENS, Ulrich , KIRNER, Hans, Jürg
IPC分类号： H01L51/00
CPC分类号： C09B5/028 , C07D471/06 , H01L51/0067 , H01L51/0069 , H01L51/0071 , H01L51/0072 , H01L51/0512 , H01L51/0541 , H01L51/5012 , Y10S428/93
摘要： A novel semiconductor device comprises an azaperylene organic semiconductor of the formula I (I) wherein each of R1 , R2, R3 and R4 independently is selected from H, unsubstituted or substituted alkyl, unsubstituted or substituted alkenyl, unsubstituted or substituted alkynyl, unsubstituted or substituted aryl, halogen, Si(RH ) 3, XR6; or one or more of R1 and R2, R2 and R3, R3 and R4, together with the carbon atoms they are bonding to, form a saturated or unsaturated, unsubstituted or substituted carbocyclic or heterocyclic ring; R5 is OR7, SR7, NR7R8, unsubstituted or substituted alkyl, unsubstituted or substituted alkenyl, unsubstituted or substituted alkynyl, or unsubstituted or substituted aryl; R6 is Si(R11 ) 3, unsubstituted or substituted alkyl, unsubstituted or substituted alkenyl, unsubstituted or substituted alkynyl, unsubstituted or substituted aryl; R7 is H, unsubstituted or substituted alkyl, unsubstituted or substituted alkenyl, unsubstituted or substituted alkynyl, unsubstituted or substituted aryl; X is O, S, NR8; Rδ is H, unsubstituted or substituted alkyl, unsubstituted or substituted alkenyl, unsubstituted or substituted alkynyl, unsubstituted or substituted aryl, R11 being C 1 -C 20 -alkyl or -alkoxy.
摘要翻译：一种新颖的半导体器件包括式I（I）的氮杂伯有机半导体，其中R1，R2，R3和R4各自独立地选自H，未取代或取代的烷基，未取代或取代的烯基，未取代或取代的炔基，未取代或取代的芳基，卤素，Si（RH）3，XR6; 或R 1和R 2，R 2和R 3，R 3和R 4中的一个或多个与它们键合的碳原子一起形成饱和或不饱和的未取代或取代的碳环或杂环; R5是OR7，SR7，NR7R8，未取代或取代的烷基，未取代或取代的烯基，未取代或取代的炔基，或未取代或取代的芳基; R6是Si（R11）3，未取代或取代的烷基，未取代或取代的烯基，未取代或取代的炔基，未取代或取代的芳基; R 7为H，未取代或取代的烷基，未取代或取代的烯基，未取代或取代的炔基，未取代或取代的芳基; X是O，S，NR8; Rd为H，未取代或取代的烷基，未取代或取代的烯基，未取代或取代的炔基，未取代或取代的芳基，R11为C 1 -C 20 - 烷基或 - 烷氧基。

22. 发明申请

WO2006067074A1 ELECTROLUMINESCENT METAL COMPLEXES WITH NUCLEOPHILIC CARBENE LIGANDS 审中-公开
标题翻译：电致发光金属配合物与核酸碳配体
公开(公告)号：WO2006067074A1
公开(公告)日：2006-06-29
申请号：PCT/EP2005/056767
申请日：2005-12-14
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , PRÉTÔT, Roger , VAN DER SCHAAF, Paul Adriaan , SCHMIDT, Jemima , SCHMIDHALTER, Beat , SCHÄFER, Thomas , LAMATSCH, Bernd
发明人： PRÉTÔT, Roger , VAN DER SCHAAF, Paul Adriaan , SCHMIDT, Jemima , SCHMIDHALTER, Beat , SCHÄFER, Thomas , LAMATSCH, Bernd
IPC分类号： C09K11/06 , H05B33/14 , H01L51/50 , H01L51/30 , C07F15/00
CPC分类号： H01L51/0067 , C07F15/0033 , C07F15/0086 , C09K11/06 , C09K2211/1029 , C09K2211/1037 , C09K2211/1059 , C09K2211/1092 , C09K2211/185 , H01L51/0071 , H01L51/0072 , H01L51/0074 , H01L51/0085 , H01L51/0087 , H01L51/5016 , H01L51/5048 , H05B33/14
摘要： This invention relates to electroluminescent metal complexes of the formula (I), wherein the ring A, formula (II), represents an optionally substituted aryl group which can optionally contain heteroatoms, the ring B, formula (III), represents an optionally substituted nitrogen containing aryl group, which can optionally contain further heteroatoms, or the ring A may be taken with the ring B binding to the ring A to form a ring; the group C, formula (IV), represents an acyclic carbene, or a cyclic carbene (ring C), which can optionally contain heteroatoms, the ring D, formula (V), represents an optionally substituted aryl group which can optionally contain heteroatoms, n1 is an integer of 1 to 3, m1 is an integer of 0, 1, or 2, m2 is an integer 0, or 1, M 1 is a metal with an atomic weight of greater than 40, L 3 is a monodentate ligand, or a bidentate ligand, Y is -C(=O)-, or -C(X 1 ) 2- , wherein X 1 is hydrogen, or C 1-4 alkyl, especially hydrogen, and y is 0, or 1, especially 0; a process for their preparation, electronic devices comprising the metal complexes and their use in electronic devices, especially organic light emitting diodes (OLEDs), as oxygen sensitive indicators, as phosphorescent indicators in bioassays, and as catalysts.
摘要翻译：本发明涉及式（I）的电致发光金属络合物，其中环A，式（II）代表任选地含有杂原子的任选取代的芳基，环B，式（III）代表任选取代的氮含有芳基，其可以任选地含有其它杂原子，或者环A可以与环B结合成环A而形成环; 式C（式Ⅳ）代表可任选地含有杂原子的无环卡宾或环卡宾（环C），环D，式（Ⅴ）代表任意取代的可任意含有杂原子的芳基， n1是1〜3的整数，m1是0,1或2的整数，m2是整数0或1，M 1是原子量大于40的金属，L 3是单齿配体或二齿配体，Y是-C（= O） - 或-C（X 1）2 - 其中X 1是氢或C 1-4烷基，特别是氢，y是0或1，特别是0; 其制备方法，包括金属络合物的电子器件及其在电子器件中的用途，特别是有机发光二极管（OLED），作为氧敏感指示剂，作为生物测定中的磷光指示剂，以及作为催化剂。

23. 发明申请

WO2008031743A1 HETEROCYCLIC BRIDGED BIPHENYLS AND THEIR USE IN OLEDS 审中-公开
标题翻译：异质桥接双极性及其在OLEDs中的应用
公开(公告)号：WO2008031743A1
公开(公告)日：2008-03-20
申请号：PCT/EP2007/059218
申请日：2007-09-04
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , WENDEBORN, Frédérique , SCHMIDHALTER, Beat , SCHÄFER, Thomas , MURER, Peter , BARDON, Kristina
发明人： WENDEBORN, Frédérique , SCHMIDHALTER, Beat , SCHÄFER, Thomas , MURER, Peter , BARDON, Kristina
IPC分类号： C07D235/18 , C07D241/42 , C07D263/56 , C07D209/58 , C07D403/14 , C07D413/14 , C07F7/10 , C07F9/53 , H01L51/30
CPC分类号： C07D235/18 , C07D209/58 , C07D241/42 , C07D263/57 , C07D403/14 , C07D413/14 , C07F9/65068 , C07F9/65324
摘要： The present invention relates electroluminescent devices, comprising a compound of the formula (I), especially as host for phosphorescent compounds. The hosts may function with phosphorescent materials to provide improved efficiency, stability, manufacturability, or spectral characteristics of electroluminescent devices.
摘要翻译：本发明涉及电致发光器件，其包含式（I）化合物，特别是作为磷光化合物的宿主。主机可以与磷光材料一起工作，以提供电致发光器件的改进的效率，稳定性，可制造性或光谱特性。

24. 发明申请

WO2005049695A1 NOVEL DIKETOPYRROLOPYRROLE POLYMERS 审中-公开
标题翻译：新型二氯丙烯聚合物
公开(公告)号：WO2005049695A1
公开(公告)日：2005-06-02
申请号：PCT/EP2004/052565
申请日：2004-10-18
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , HEIM, Ingo , TIEKE, Bernd , LENZ, Roman , SCHMIDHALTER, Beat , RABINDRANATH, Aravinda Raman , DÜGGELI, Mathias
发明人： HEIM, Ingo , TIEKE, Bernd , LENZ, Roman , SCHMIDHALTER, Beat , RABINDRANATH, Aravinda Raman , DÜGGELI, Mathias
IPC分类号： C08G73/00
CPC分类号： C08G61/126 , C08G61/123 , C08G61/124 , C08G61/125 , C08G73/0611 , C08G73/0688 , C08G73/0694 , C09B57/004 , C09B69/109 , C09K11/06 , C09K2211/1029 , H01L51/0035 , H01L51/0036 , H05B33/14 , Y02E10/549
摘要： The present invention relates to polymers comprising a repeating unit of the formula (I) and their use in electronic devices. The polymers according to the invention have excellent solubility in organic solvents and excellent film-forming properties. In addition, high charge carrier mobilities and high temperature stability of the emission color are observed, if the polymers according to the invention are used in polymer light emitting diodes (PLEDs).
摘要翻译：本发明涉及包含式（I）的重复单元及其在电子器件中的用途的聚合物。根据本发明的聚合物在有机溶剂中具有优异的溶解性和优异的成膜性能。此外，如果根据本发明的聚合物用于聚合物发光二极管（PLED）中，则观察到高电荷载流子迁移率和发光颜色的高温稳定性。

25. 发明申请

WO2006097419A1 NOVEL POLYMERS 审中-公开
标题翻译：新型聚合物
公开(公告)号：WO2006097419A1
公开(公告)日：2006-09-21
申请号：PCT/EP2006/060538
申请日：2006-03-08
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , SCHÄFER, Thomas , SCHMIDHALTER, Beat , MURER, Peter , BARDON, Kristina , HINTERMANN, Tobias
发明人： SCHÄFER, Thomas , SCHMIDHALTER, Beat , MURER, Peter , BARDON, Kristina , HINTERMANN, Tobias
IPC分类号： C08L65/00 , C07C211/00
CPC分类号： H01L51/0035 , C08G61/12 , C08G61/122 , C08G61/124 , C08G61/125 , C08G61/126 , H01L51/5012 , Y02E10/549
摘要： The present invention relates to polymers comprising a repeating unit of the formula (I), and their use in electronic devices. The polymers according to the invention have excellent 5 solubility in organic solvents and excellent film-forming properties. In addition, high charge carrier mobilities and high temperature stability of the emission color are observed, if the polymers according to the invention are used in polymer light emitting diodes (PLEDs).
摘要翻译：本发明涉及包含式（I）的重复单元的聚合物及其在电子器件中的用途。根据本发明的聚合物在有机溶剂中的溶解度优异且成膜性优异。此外，如果根据本发明的聚合物用于聚合物发光二极管（PLED）中，则观察到高电荷载流子迁移率和发光颜色的高温稳定性。

26. 发明申请

WO2006000544A3 ELECTROLUMINESCENT METAL COMPLEXES WITH TRIAZOLES AND BENZOTRIAZOLES 审中-公开
公开(公告)号：WO2006000544A3
公开(公告)日：2006-01-05
申请号：PCT/EP2005/052845
申请日：2005-06-20
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , SCHÄFER, Thomas , BARDON, Kristina , SCHMIDHALTER, Beat , PRÉTÔT, Roger
发明人： SCHÄFER, Thomas , BARDON, Kristina , SCHMIDHALTER, Beat , PRÉTÔT, Roger
IPC分类号： C09K11/06 , H01L51/30 , C07D249/06 , C07D249/18 , C07F15/00
摘要： This invention relates to electroluminescent metal complexes with triazoles and benzotriazoles, respectively of the formula (I) a process for their preparation, electronic devices comprising the metal complexes and their use in electronic devices, especially organic light emitting diodes (OLEDs), as oxygen sensitive indicators, as phosphorescent indicators in bioassays, and as catalysts.

27. 发明申请

WO2009047104A2 PYRROLOPYRROLE DERIVATIVES, THEIR MANUFACTURE AND USE 审中-公开
标题翻译：吡咯烷酮衍生物及其制备和使用
公开(公告)号：WO2009047104A2
公开(公告)日：2009-04-16
申请号：PCT/EP2008/062586
申请日：2008-09-22
申请人： CIBA HOLDING INC. , HAO, Zhimin , SCHMIDHALTER, Beat , BUDRY, Jean-Luc , FONTANA, Margherita , TURBIEZ, Mathieu G. R. , BIENEWALD, Frank , DÜGGELI, Mathias , AEBISCHER, Olivier Frédéric , HAYOZ, Pascal , FONRODONA TURON, Marta
发明人： HAO, Zhimin , SCHMIDHALTER, Beat , BUDRY, Jean-Luc , FONTANA, Margherita , TURBIEZ, Mathieu G. R. , BIENEWALD, Frank , DÜGGELI, Mathias , AEBISCHER, Olivier Frédéric , HAYOZ, Pascal , FONRODONA TURON, Marta
IPC分类号： C07D487/04 , H01L51/00
CPC分类号： H01L51/0071 , C07D487/04 , C09B57/004 , H01L51/0053 , H01L51/0058 , H01L51/0068 , H01L51/0095 , Y02E10/549
摘要： The present invention relates to compounds of the formula (I) wherein the substituents are as defined in claim 1, and their use as organic semiconductor in organic devices, like diodes, organic field effect transistors and/or a solar cells. The compounds of the formula I have excellent solubility in organic solvents. High efficiency of energy conversion, excellent field-effect mobility, good on/off current ratios and/or excellent stability can be observed, when said compounds are used in semiconductor devices or organic photovoltaic (PV) devices (solar cells).
摘要翻译：本发明涉及式（I）化合物，其中取代基如权利要求1中所定义，及其作为有机半导体在有机器件中的用途，如二极管，有机场效应晶体管和/或太阳能电池。式I的化合物在有机溶剂中具有优异的溶解性。当所述化合物用于半导体器件或有机光伏（PV）器件（太阳能电池））时，可以观察到高效率的能量转换，优异的场效应迁移率，良好的导通/截止电流比和/或优异的稳定性。

28. 发明申请

WO2010063609A2 HOLE INJECTION MATERIAL 审中-公开
标题翻译：孔注射材料
公开(公告)号：WO2010063609A2
公开(公告)日：2010-06-10
申请号：PCT/EP2009/065687
申请日：2009-11-24
申请人： BASF SE , SCHMIDHALTER, Beat , NESVADBA, Peter , SCHÄFER, Thomas
发明人： SCHMIDHALTER, Beat , NESVADBA, Peter , SCHÄFER, Thomas
IPC分类号： C09K11/06
CPC分类号： C09K11/06 , C09K2211/1007
摘要： The present invention relates to an electronic device, which comprises a compound of the formula (I), wherein R 1 and R 2 independently of one another are C 1 -C 12 alkyl, C 1 -C 12 alkyl, which is interrupted by one, or more oxygen atoms, C 3 -C 8 cycloalkyl which is unsubstituted or substituted by C 1 -C 4 alkyl, unsubstituted C 6 -C 12 aryl, or C 3 -C 7 heteroaryl, or benzyl, or C 6 -C 12 aryl, or C 3 -C 7 heteroaryl, or benzyl which is substituted by F, Cl, Br, C 1 -C 6 alkyl, C 1 -C 6 alkoxy or di(C 1 -C 6 alkylamino). The compound of the formula (I) is a n-type organic material, which is an intrinsically good semiconducting material, resulting in a high device stability and reliability.
摘要翻译：本发明涉及电子器件，其包含式（I）化合物，其中R 1和R 2彼此独立地为被一个或多个氧原子间隔的C 1 -C 12烷基，C 1 -C 12烷基，C 3 -C 12烷基，未取代或被C 1 -C 4烷基，未被取代的C 6 -C 12芳基或C 3 -C 7杂芳基或苄基或C 6 -C 12芳基或C 3 -C 7杂芳基取代的C 8环烷基或被F，Cl，Br，C 1 -C 6烷基， C 1 -C 6烷氧基或二（C 1 -C 6烷基氨基）。式（I）的化合物是n型有机材料，其是本质上良好的半导体材料，导致高的器件稳定性和可靠性。

29. 发明申请

WO2010046259A1 POLYCYCLIC COMPOUNDS FOR ELECTRONIC APPLICATIONS 审中-公开
标题翻译：用于电子应用的多环化合物
公开(公告)号：WO2010046259A1
公开(公告)日：2010-04-29
申请号：PCT/EP2009/063267
申请日：2009-10-12
申请人： BASF SE , NESVADBA, Peter , WENDEBORN, Frédérique , SCHÄFER, Thomas , SCHMIDHALTER, Beat , RICCI, Andrea , MURER, Peter , CHEBOTAREVA, Natalia
发明人： NESVADBA, Peter , WENDEBORN, Frédérique , SCHÄFER, Thomas , SCHMIDHALTER, Beat , RICCI, Andrea , MURER, Peter , CHEBOTAREVA, Natalia
IPC分类号： C07D487/04 , C07D493/04 , C07D495/04 , C07F9/655 , H01L27/32
CPC分类号： C07D493/04 , C07D487/04 , C07D495/04 , C07F9/6561 , C09B57/00 , H01L51/0054 , H01L51/0058 , H01L51/0061 , H01L51/0072 , H01L51/0073 , Y02E10/549
摘要： The present invention relates to electronic devices, especially electroluminescent devices, comprising compounds of formula (I), and/or (II), especially as host for phosphorescent emitters, electron transporting materials, or emitter materials. The hosts may function with phosphorescent materials to provide improved efficiency, stability, manufacturability, or spectral characteristics of electroluminescent devices.
摘要翻译：本发明涉及包含式（I）和/或（II）化合物的电子器件，特别是电致发光器件，特别是磷光发射体，电子传输材料或发射体材料的主体。主机可以与磷光材料一起工作，以提供电致发光器件的改进的效率，稳定性，可制造性或光谱特性。

30. 发明申请

WO2011161078A1 AN ORGANIC FIELD EFFECT TRANSISTOR WITH IMPROVED CURRENT ON/OFF RATIO AND CONTROLLABLE THRESHOLD SHIFT 审中-公开
标题翻译：具有改进的电流开/关比和可控阈值转换的有机场效应晶体管
公开(公告)号：WO2011161078A1
公开(公告)日：2011-12-29
申请号：PCT/EP2011/060283
申请日：2011-06-21
申请人： BASF SE , SCHMIDHALTER, Beat , CHEBOTAREVA, Natalia , HAYOZ, Pascal
发明人： SCHMIDHALTER, Beat , CHEBOTAREVA, Natalia , HAYOZ, Pascal
IPC分类号： H01L51/00 , H01L51/05
CPC分类号： H01L51/002 , C09B69/105 , C09B69/109 , H01L51/0036 , H01L51/0043 , H01L51/0053 , H01L51/0566
摘要： The present invention provides a semiconductor device, especially an organic field effect transistor, comprising a layer comprising a polymer comprising repeating units having a diketopyrrolopyrrole skeleton (DPP polymer) and an acceptor compound having an electron affinity in vacuum of 4.6 eV, or more. The doping of the DPP polymer with the acceptor compound leads to an organic field effect transistor with improved hole mobility, current on/off ratio and controllable threshold shift.
摘要翻译：本发明提供一种半导体器件，特别是有机场效应晶体管，其包含含有包含具有二酮吡咯并吡咯骨架（DPP聚合物）的重复单元和在真空中具有电子亲和力的受体化合物为4.6eV以上的聚合物的层。 DPP聚合物与受体化合物的掺杂导致具有改善的空穴迁移率，电流开/关比和可控的阈值偏移的有机场效应晶体管。

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