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    • 12. 发明申请
    • LITHOGRAPHIC PRINTING PLATE PRECURSORS WITH OLIGOMERIC OR POLYMERIC SENSITIZERS
    • 具有低分子或聚合物敏感剂的平版印刷机前驱体(LITHOGRAPHIC PRINTING PLATE PRECURSORS WITH OLIGOMERIC或POLYMERIC SENSITIZERS)
    • WO2006053689A1
    • 2006-05-26
    • PCT/EP2005/012136
    • 2005-11-11
    • KODAK POLYCHROME GRAPHICS GMBHSTREHMEL, BerndBAUMANN, HaraldDWARS, UdoPIETSCH, DetlefDRABER, AxelMURSAL, Michael
    • STREHMEL, BerndBAUMANN, HaraldDWARS, UdoPIETSCH, DetlefDRABER, AxelMURSAL, Michael
    • G03F7/031G03F7/029
    • G03F7/029G03F7/031Y10S430/116Y10S430/117Y10S430/121Y10S430/123Y10S430/127Y10S522/904Y10S522/913
    • Lithographic printing plate precursor comprising (a) a lithographic substrate with a hydrophilic surface and (b) a radiation-sensitive coating on the hydrophilic surface comprising (i) one or more types of monomers and/or oligomers and/or polymers, each comprising at least one ethylenically unsaturated group accessible to a freeradical polymerization, (ii) at least one sensitizer, and at least one coinitiator capable of forming free radicals together with the sensitizer (ii); characterized in that the at least one sensitizer is an oligomeric or polymeric compound comprising the following structural unit (Formula (I)), wherein π 1 is an aromatic or heteroaromatic unit or a combination of the two so that a conjugated n-system is present between the two groups Z in structure (I), each Z independently represents a heteroatom, each R 1 and R 2 is independently selected from a halogen atom, an alkyl, aryl, alkylaryl or aralkyl group, a group -NR 3 R 4 and a group -OR 5 , each R 3 , R 4 and R 5 is independently selected from an alkyl, aryl, alkylaryl and aralkyl group, a and b independently represent 0 or an integer from 1 to 4, n has a value of >1 and AS is an aliphatic spacer.
    • 该平版印刷版前体包括(a)具有亲水表面的平版印刷基材和(b)亲水表面上的辐射敏感涂层,其包含(i)一种或多种类型的单体和/或低聚物和/或聚合物, 至少一种可自由聚合的烯属不饱和基团,(ii)至少一种敏化剂,和至少一种能够与敏化剂(ii)一起形成自由基的共引发剂; 其特征在于,所述至少一种敏化剂是包含以下结构单元(式(I))的低聚或聚合化合物,其中p 1是芳族或杂芳族单元或两者的组合,使得 在结构(I)中的两个基团Z之间存在共轭n系,每个Z独立地表示杂原子,每个R 1和R 2独立地选自 卤素原子,烷基,芳基,烷基芳基或芳烷基,基团-NR 3 R 4和基团-OR 5,各R R 4,R 4和R 5独立地选自烷基,芳基,烷基芳基和芳烷基,a和b独立地表示0或 1〜4的整数,n的值为1,AS为脂肪族间隔物。
    • 14. 发明申请
    • PROCESS FOR THE PRODUCTION OF LITHOGRAPHIC PRINTING PLATES
    • 生产平版印刷板的方法
    • WO2006087102A2
    • 2006-08-24
    • PCT/EP2006/000878
    • 2006-02-01
    • KODAK POLYCHROME GRAPHICS GMBHBAUMANN, HaraldFIEBAG, UlrichDWARS, UdoSTREHMEL, BerndFLUGEL, MichaelTIMPE, Hans-Joachim
    • BAUMANN, HaraldFIEBAG, UlrichDWARS, UdoSTREHMEL, BerndFLUGEL, MichaelTIMPE, Hans-Joachim
    • G03F7/322
    • Process for the production of lithographic printing plates comprising (a) providing a lithographic substrate with a hydrophilic surface; (b) applying a negative working radiation-sensitive composition onto the hydrophilic surface, wherein the composition comprises: (i) one or more types of monomers and/or oligomers and/or polymers, each comprising at least one ethylenically unsaturated group accessible to a free-radical polymerization, (ii) at least one sensitizer which in the presence of at least one coinitiator and upon exposure to radiation of a wavelength of 300 to 750 to 1,100 nm initiates the free-radical polymerization of component (i); and (iii) at least one binder with acidic functional groups and is substantially not sensitive to the wavelength range of 480 to 750 nm; (c) image-wise exposure of the resulting negative working lithographic printing plate precursor to radiation selected from the wavelength range of 300 to 750 to 1,100 nm depending on the sensitizer or initiator system used; and (d) removing the non-irradiated areas by means of a treatment with an alkaline developer with a pH value in the range of 9 to 14 comprising (i) water, (ii) one or more alkali hydroxides in an amount sufficient for adjusting a pH value in the range of 9 to 14; and (iii) 1 to 30 wt. -% of at least one compound of formula (I) wherein R 1 , R 2 , R 3 and R 4 are each independently selected from C 1 -C 12 alkyl groups and aryl groups, X is selected from -CH=CH-, -C≡C-,formula (II), formula (III), and formula (IV), n + m results in a value of 2 to 30 and p + q results in a value of 0 to 30, wherein in the case of p + q ≠ 0 the ethylene oxide and propylene oxide units are present as blocks or randomly distributed.
    • 制备平版印刷版的方法包括(a)向平版印刷基材提供亲水表面; (b)将负性辐射敏感组合物施加到所述亲水性表面上,其中所述组合物包含:(i)一种或多种类型的单体和/或低聚物和/或聚合物,其各自包含至少一个烯键式不饱和基团 自由基聚合,(ii)至少一种敏化剂,其在至少一种共引发剂的存在下,并且在暴露于300至<480nni或> 750至1,100nm的波长的辐射下引发组分的自由基聚合 一世); 和(iii)至少一种具有酸性官能团的粘合剂,并且对480至750nm的波长范围基本上不敏感; (c)根据所使用的敏化剂或引发剂体系,将得到的负性工作平版印刷版原版成像曝光于从300至<480nm或> 750至1,100nm的波长范围内的辐射; 和(d)通过用pH值在9至14范围内的碱性显影剂处理除去未照射的区域,其包含(i)水,(ii)一种或多种足以调节的碱金属氢氧化物 pH值在9至14的范围内; 和(iii)1〜30wt。 - 至少一种其中R 1,R 2,R 3和R 4的式(I)化合物的% SUP>各自独立地选自C 1 -C 12烷基和芳基,X选自-CH = CH-,-C = C-,式( II),式(III)和式(IV)中,n + m的值为2〜30,p + q的值为0〜30,其中,在p +q≥2的情况下, 0环氧乙烷和环氧丙烷单元以块或随机分布存在。