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11. 发明申请

WO2012057935A2 METHOD FOR REDUCING MERCAPTANS IN HYDROCARBONS 审中-公开
标题翻译：降低烃类中MERCAPTANS的方法
公开(公告)号：WO2012057935A2
公开(公告)日：2012-05-03
申请号：PCT/US2011/052155
申请日：2011-09-19
申请人： CHEVRON U.S.A. INC. , HE, Zunqing , ZHOU, Zhen , LI, Lin
发明人： HE, Zunqing , ZHOU, Zhen , LI, Lin
IPC分类号： C10G27/02 , C10G27/06 , C10G31/08 , C10G33/00 , C10L1/04
CPC分类号： C10G27/02 , C10G27/06 , C10G33/00 , C10G2300/1033 , C10G2300/202 , C10G2400/08
摘要： A method for reducing mercaptan concentration in a liquid hydrocarbon, comprising: contacting a mercaptan-rich liquid hydrocarbon having a first concentration of mercaptan sulfur with a composition comprising an oxidizing agent and water wherein the molar ratio of the oxidizing agent to mercaptan sulfur in the mercaptan-rich liquid hydrocarbon is from 3:1 to 10:1; and separating the water from the liquid hydrocarbon to yield a mercaptan-depleted liquid hydrocarbon having a second concentration of mercaptan sulfur, the second concentration being less than the first concentration; wherein a major amount of mercaptan compounds in the mercaptan-rich liquid hydrocarbon are converted to at least one sulfur oxoacid or salt thereof, having the formula: [RSOx]nY wherein R is a hydrocarbyl group; x is an integer from 1 to 3; n is 1 or 2; and Y is hydrogen, an alkaline metal, or alkaline earth metal.
摘要翻译： 1.一种用于降低液态烃中硫醇浓度的方法，所述方法包括：使具有第一硫醇硫浓度的富硫醇液态烃与包含氧化剂和水的组合物接触，其中所述富硫醇液态烃中硫醇硫的摩尔比为3:1至10:1; 以及从液态烃中分离水以产生具有第二硫醇硫浓度的硫醇贫化液态烃，第二浓度小于第一浓度; 其中将富含硫醇的液态烃中的主要量的硫醇化合物转化为至少一种具有下式的硫代含氧酸或其盐：[RSO x] n Y其中R为烃基; x是1至3的整数; n是1或2; Y是氢，碱金属或碱土金属。

12. 发明申请

WO2011028329A2 MULTI-GRADE ENGINE OIL FORMULATIONS COMPRISING A BIO-DERIVED ESTER COMPONENT 审中-公开
标题翻译：包含生物衍生酯组分的多级发动机油制剂
公开(公告)号：WO2011028329A2
公开(公告)日：2011-03-10
申请号：PCT/US2010/042641
申请日：2010-07-20
申请人： CHEVRON U.S.A. INC. , MILLER, Stephen Joseph , ELOMARI, Saleh A. , ZHOU, Zhen
发明人： MILLER, Stephen Joseph , ELOMARI, Saleh A. , ZHOU, Zhen
IPC分类号： C10M169/04 , C10M129/72 , C07C69/52 , C10M107/02
CPC分类号： C10M105/38 , C10M129/74 , C10M2205/0285 , C10M2207/283 , C10M2207/2835 , C10M2209/084 , C10N2220/021 , C10N2220/022 , C10N2220/023 , C10N2220/033 , C10N2230/02 , C10N2230/10 , C10N2240/10
摘要： The present invention is generally directed to the present invention provides for multi-grade engine oil formulations comprising a diester component, wherein the diester component comprises vicinal diester species, and wherein at least a portion of said diester component is bio-derived. Many such formulations of the present invention are expected to favorably compete with similar, existing formulations comprising synthetic esters, but such formulations are generally expected to meet or exceed such existing formulations in a number of areas including, but not limited to, economics, biodegradability, and/or toxicity.
摘要翻译：本发明总体涉及本发明提供包含二酯组分的多级发动机油制剂，其中二酯组分包含邻位二酯物质，并且其中至少一部分所述二酯组分是生物衍生的。预期本发明的许多这样的制剂有利地与包含合成酯的类似的现有制剂竞争，但是通常预期这些制剂在许多领域达到或超过这些现有制剂，包括但不限于经济性，生物降解性，和/或毒性。

13. 发明申请

WO2011005604A2 SYNTHESIS OF BIOLUBRICANT ESTERS FROM UNSATURATED FATTY ACID DERIVATIVES 审中-公开
标题翻译：由不饱和脂肪酸衍生物合成生物润滑剂酯
公开(公告)号：WO2011005604A2
公开(公告)日：2011-01-13
申请号：PCT/US2010/039809
申请日：2010-06-24
申请人： CHEVRON U.S.A. INC. , ELOMARI, Saleh, A. , MILLER, Stephen, Joseph , ZHOU, Zhen
发明人： ELOMARI, Saleh, A. , MILLER, Stephen, Joseph , ZHOU, Zhen
IPC分类号： C10M105/38 , C07C69/02 , C07C67/08
CPC分类号： C10M105/38 , C07C29/132 , C07C29/147 , C07C67/08 , C10M2207/2835 , C10N2270/00 , C11C3/00 , C11C3/12 , C07C31/20 , C07C69/28
摘要： The present invention is generally directed to diester-based lubricant compositions comprising one or more isomeric mixtures of diester species. The present invention is also directed to methods of making these and other similar lubricant compositions. In some embodiments, the methods for making such diester-based lubricants utilize a biomass precursor material from which mono-unsaturated free lipid species can be provided or otherwise generated, wherein such mono-unsaturated free lipid species are converted to isomeric diol species en route to the synthesis of diester species for use as/in the diester-based lubricant compositions.
摘要翻译：本发明总体上涉及包含一种或多种二酯类异构体混合物的二酯基润滑剂组合物。本发明还涉及制造这些和其他类似润滑剂组合物的方法。在一些实施方案中，用于制造这种基于二酯的润滑剂的方法利用生物质前体材料，其中可以提供或以其他方式生成单不饱和游离脂质物种，其中这种单 - 不饱和游离脂质物质在途中转化为异构二醇物质在二酯基润滑剂组合物中/用于二酯基润滑剂组合物中的二酯物质的合成。

14. 发明申请

WO2014179723A1 DIESTER-BASED BASE OIL BLENDS WITH IMPROVED COLD FLOW PROPERTIES AND LOW NOACK 审中-公开
标题翻译：基于柴油机的基础油混合物，具有改进的冷流特性和低含量
公开(公告)号：WO2014179723A1
公开(公告)日：2014-11-06
申请号：PCT/US2014/036628
申请日：2014-05-02
申请人： CHEVRON U.S.A. INC.
发明人： MILLER, Stephen Joseph , ELOMARI, Saleh Ali , HAO, Yalin , ROSENBAUM, John Michael , ZHOU, Zhen
IPC分类号： C10M105/38 , C10M111/02 , C10N30/02 , C10N30/10 , C10N40/25
CPC分类号： C10M105/38 , C10M111/02 , C10M2203/1006 , C10M2203/1025 , C10M2207/2835 , C10N2230/02 , C10N2230/04 , C10N2230/08 , C10N2230/10 , C10N2230/64 , C10N2230/74 , C10N2240/10 , C10N2220/022
摘要： The present invention is generally directed to diester-based base oils and base oil blends with improved cold flow properties and improved Noack. The diesters employed have a number a performance benefits in lubricant applications - among them: biodegradability, extreme temperature performance, oxidative stability, solubility for additives and deposit and sludge precursors, flash and fire points. However, ester usage in lubricants has been quite limited due to their high cost. We utilize new proprietary diesters, structurally different from traditional diesters, which are made from fatty acids and alpha olefins in simple processing steps, yet feature performance similar to more traditional lubricant esters.
摘要翻译：本发明一般涉及具有改善的冷流特性和改进的Noack的基于二酯的基础油和基础油混合物。使用的二酯在润滑剂应用中具有许多性能优势，其中包括：生物降解性，极端温度性能，氧化稳定性，添加剂和沉积物和污泥前体的溶解度，闪点和火点。然而，由于其高成本，润滑剂中的酯用量已经非常有限。我们利用与传统二酯结构不同的新专有二酯，它们由简单加工步骤中的脂肪酸和α-烯烃制成，但具有与传统润滑剂酯类似的性能。

15. 发明申请

WO2012030443A2 BIOFUEL PRODUCTION THROUGH CATALYTIC DEOXYGENATION 审中-公开
标题翻译：通过催化脱氧生物生产生物燃料
公开(公告)号：WO2012030443A2
公开(公告)日：2012-03-08
申请号：PCT/US2011/044722
申请日：2011-07-20
申请人： CHEVRON U.S.A. INC. , ZHOU, Zhen , HUSAIN, Shabbir , LI, Lin
发明人： ZHOU, Zhen , HUSAIN, Shabbir , LI, Lin
IPC分类号： C10G31/00 , C10G3/00 , C10L1/02 , C07C7/00 , B01J21/06
CPC分类号： C10G3/48 , B01J21/063 , B01J23/002 , B01J23/06 , C10B53/02 , C10G3/45 , C10G3/49 , C10G2300/1014 , C10G2300/1018 , C10G2300/202 , C10G2300/4018 , Y02P30/20
摘要： A process useful for treating biologically derived oils in the production of biofuels is described. A biologically derived oil feed is deoxygenated by contacting the feed with a metal titanate catalyst. The process does not require the addition of hydrogen.
摘要翻译：描述了在生物燃料生产中用于处理生物衍生的油的方法。通过使进料与金属钛酸盐催化剂接触，生物衍生的油进料被脱氧。该方法不需要加氢。

16. 发明申请

WO2010068644A2 REMOVING UNSTABLE SULFUR COMPOUNDS FROM CRUDE OIL 审中-公开
标题翻译：从原油中取出不稳定的硫化合物
公开(公告)号：WO2010068644A2
公开(公告)日：2010-06-17
申请号：PCT/US2009/067251
申请日：2009-12-09
申请人： CHEVRON U.S.A. INC. , LUO, Huping , ZHOU, Zhen , LI, Lin , HE, Alice , CHINN, Daniel , FORDER, Graham , YOUNG, Lyman , HUSAIN, Shabbir , SCHINSKI, William
发明人： LUO, Huping , ZHOU, Zhen , LI, Lin , HE, Alice , CHINN, Daniel , FORDER, Graham , YOUNG, Lyman , HUSAIN, Shabbir , SCHINSKI, William
IPC分类号： C10G31/06 , C10G29/04 , C10G29/16 , B01J23/74 , B01J23/06 , B01J20/18 , B01J20/08
CPC分类号： C10G29/00 , B01J8/00 , B01J19/24 , B01J27/16 , B01J29/084 , B01J29/146 , B01J2208/00796 , B01J2219/24 , C10G17/00 , C10G17/06 , C10G21/06 , C10G21/12 , C10G21/16 , C10G21/20 , C10G29/04 , C10G29/20 , C10G45/02 , C10G2300/1033 , C10G2300/202 , C10G2300/4006 , C10G2300/4093
摘要： A crude oil which contains at least 0.1 wt% unstable sulfur compounds is treated in a reaction zone at low temperature to convert at least 50 wt% of the unstable sulfur compounds contained therein. The reaction and removal of sulfur from the crude may be facilitated by contacting the crude oil with a catalytic material in the presence of a stripping fluid.
摘要翻译：含有至少0.1wt％不稳定的硫化合物的原油在低温下在反应区中处理，以转化至少50wt％的不稳定的硫化合物。可以通过在汽提流体存在下使原油与催化材料接触来促进来自粗制物的硫的反应和除去。

17. 发明申请

WO2010056832A3 SYNTHESIS OF DIESTER-BASED LUBRICANTS FROM ENZYMATICALLY-DIRECTED EPOXIDES 审中-公开
公开(公告)号：WO2010056832A3
公开(公告)日：2010-05-20
申请号：PCT/US2009/064170
申请日：2009-11-12
申请人： CHEVRON U.S.A. INC. , NOVOZYMES A/S , MILLER, Stephen Joseph , ELOMARI, Saleh A. , ZHOU, Zhen , BRASK, Jesper , BORCH, Kim
发明人： MILLER, Stephen Joseph , ELOMARI, Saleh A. , ZHOU, Zhen , BRASK, Jesper , BORCH, Kim
IPC分类号： C10M105/36 , C10M105/32 , C12P7/40
摘要： The present invention is generally directed to methods of making diester-based lubricant compositions, wherein formation of diester species proceeds via esterification of epoxide intermediates, and wherein the epoxide intermediates are generated via an enzymatically-driven mechanism. In some embodiments, the methods for making such diester-based lubricants utilize a biomass precursor and/or low value (e.g., Fischer-Tropsch (FT) olefins and/or alcohols) so as to produce high value diester-based lubricants. In some embodiments, such diester-based lubricants are derived from FT olefins and fatty acids. The fatty acids can be from a bio-based source (i.e., biomass, renewable source) or can be derived from FT alcohols via oxidation.

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