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111. 发明申请

WO02038701A1 METHOD FOR HYDROTREATMENT OF A MIXTURE OF HYDROCARBON COMPOUNDS, RICH IN OLEFINS AND AROMATIC COMPOUNDS 审中-公开
标题翻译：氢化烯烃与芳烃化合物混合物的方法
公开(公告)号：WO02038701A1
公开(公告)日：2002-05-16
申请号：PCT/EP2001/012989
申请日：2001-11-06
IPC分类号： C10G45/08 , C10G45/00 , C10G45/32 , C10G69/04 , C10G69/06
CPC分类号： C10G45/32 , C10G2300/104 , C10G2300/1044 , C10G2300/4018 , C10G2300/4081 , C10G2400/02
摘要： The invention concerns a method for hydrotreatment of C4-C8 hydrocarbon compounds rich in olefins and mono-aromatic compounds, by hydrogenation in the presence of a solid catalyst. The invention is characterised in that it consists in introducing an ammonia precursor in the hydrocarbon feedstock and the catalyst comprises at least a transition metal supported on at least a refractory oxide.
摘要翻译：本发明涉及通过在固体催化剂存在下氢化来加氢处理富含烯烃和单芳族化合物的C4-C8烃化合物的方法。本发明的特征在于其包括在烃原料中引入氨前体，催化剂至少包含负载在至少难熔氧化物上的过渡金属。

112. 发明申请

WO00029513A1 SMALL CATALYST PARTICLE ADDITION TO SLURRY REACTOR 审中-公开
标题翻译：小型催化剂颗粒添加到浆料反应器中
公开(公告)号：WO00029513A1
公开(公告)日：2000-05-25
申请号：PCT/US1999/025387
申请日：1999-10-29
IPC分类号： B01J23/36 , B01J8/00 , B01J8/22 , B01J23/889 , B01J35/02 , C07B61/00 , C07C29/156 , C07C31/04 , C10G2/00 , C10G45/02 , C10G45/16 , C10G45/32 , C10G45/42 , C10G45/44 , C10G45/56 , C10G45/66 , C10G47/26 , C10G49/02 , C10G49/12
CPC分类号： C10G2/331 , B01J8/0015 , B01J8/006 , B01J8/22 , B01J23/8896 , B01J35/023 , B01J2208/00672 , B01J2208/00681 , B01J2219/00006 , C10G2/342 , C10G45/02 , C10G45/16 , C10G45/32 , C10G45/42 , C10G45/44 , C10G45/56 , C10G45/66 , C10G47/26 , C10G49/02 , C10G49/12
摘要： Small particle size catalysts having an average particle size of less than 20 or 10 microns, which agglomerate when contacted with a hydrocarbon liquid, are easily dispersed in the hydrocarbon liquid by first forming a mixture comprising the catalyst particles and one or more non-acidic, liquid polar oxygenates, such as an alcohol, ketone, ester, ether or mixture thereof. The mixture is contacted with the hydrocarbon liquid in which the particles then readily disperse. This process is useful for adding fresh or regenerated small particle size catalyst to catalytic hydroprocessing process slurries, including a reactive Fischer-Tropsch hydrocarbon synthesis slurry. One to four carbon atom alcohols are preferred oxygenates for use with a Fischer-Tropsch slurry.
摘要翻译：平均粒径小于20或10微米的小颗粒尺寸的催化剂，当与烃液体接触时，其结块容易地分散在烃液体中，首先形成包含催化剂颗粒和一种或多种非酸性，液体极性含氧化合物，例如醇，酮，酯，醚或其混合物。混合物与其中颗粒容易分散的烃液体接触。该方法可用于将新鲜或再生的小粒度催化剂加入到催化加氢处理浆料中，包括反应性费 - 托烃合成浆料。一至四个碳原子醇是与费 - 托浆料一起使用的优选的含氧化合物。

113. 发明申请

WO1996006900A1 PROCESS FOR SELECTIVE HYDROGENATION OF CRACKED HYDROCARBONS 审中-公开
标题翻译：裂解烃选择性加氢方法
公开(公告)号：WO1996006900A1
公开(公告)日：1996-03-07
申请号：PCT/US1995011000
申请日：1995-08-25
申请人： EXXON CHEMICAL PATENTS INC.
发明人： EXXON CHEMICAL PATENTS INC. , VEBELIUNAS, Rimas, Virgilijus , BAMFORD, David, Alan , DRUMMOND, Neil, James , SNIDER, Sheri, Renee , STRACK, Robert, David , HALLE, Roy, Thomas
IPC分类号： C10G70/02
CPC分类号： C10G70/02 , C10G45/32 , Y10S585/95
摘要： The invention relates to a process to selectively hydrogenate di-olefinically, poly-olefinically, and acetylenically unsaturated hydrocarbon components a C2 to C5 or a C3 to C5 fraction of a cracked hydrocarbon stream. The process comprises removing from a deethanizer or depropanizer a heavy stream enriched in a C3 to C5 or a C4 to C5 fraction; reacting the heavy stream with hydrogen for selective hydrogenation; and returning at least a portion of the hydrogenated stream to the deethanizer or depropanizer. Embodiments are disclosed where the heavy stream is removed by a side draw or by means of the reboiler circuit. The invention is applicable to front-end demethanizer, deethanizer, or depropanizer fractional distillation process sequences such as may be used with steam cracking or catalytic cracking.
摘要翻译：本发明涉及一种选择性氢化裂化烃物流的C2- C5 +或C3-C5 +馏分的二烯属，聚烯烃和炔属不饱和烃成分的方法。该方法包括从脱乙烷塔或脱丙烷塔中除去富含C3至C5 +或C4至C5 +级分的重流; 使重质流与氢气反应进行选择性氢化; 并将至少一部分氢化流返回到脱乙烷塔或脱丙烷塔。公开了其中重流通过侧抽或通过再沸器回路除去的实施例。本发明适用于前端脱甲烷塔，脱乙烷塔或脱丙烷分馏工序，可用于蒸汽裂化或催化裂化。

114. 发明申请

WO1995015934A1 SELECTIVE HYDROGENATION OF HIGHLY UNSATURATED COMPOUNDS IN HYDROCARBON STREAMS 审中-公开
标题翻译：烃类化合物中高度不饱和化合物的选择性加氢
公开(公告)号：WO1995015934A1
公开(公告)日：1995-06-15
申请号：PCT/US1994007758
申请日：1994-07-21
申请人： CHEMICAL RESEARCH & LICENSING COMPANY
发明人： CHEMICAL RESEARCH & LICENSING COMPANY , HEARN, Dennis , ARGANBRIGHT, Robert, P. , JONES, Edward, M., Jr. , SMITH, Lawrence, A., Jr. , GILDERT, Gary, R.
IPC分类号： C07C05/05
CPC分类号： C10G70/02 , C10G45/32
摘要： A process for the selective hydrogenation of the diolefins and acetylenic compounds in an olefin-rich aliphatic hydrocarbon stream (1) comprises contacting the feed stream (1) at 40-300 DEG F under low hydrogen partial pressure of 0.1-70 psia at a total pressure of 0-350 psig in a distillation column reactor (10) containing a hydrogenation catalyst bed (12) which serves as a component of a distillation structure (10), such as supported PdO encased in a tubular wire mesh. Essentially no hydrogenation of the olefins occur. The feed stream (1) enters below or at the lower end of the catalyst bed (12), and is contacted with hydrogen fed through line (2) in the catalyst bed (12). The overhead (3) is obtained at the overhead, condensed in a condenser (20) and separated in a settler (30), and partially recycled back to catalyst bed (12) as a reflux stream (6). The bottom stream (11) is obtained at the lower end of the distillation reactor, and is partially recycled back as stream (4) after being heated in a heat exchanger (40) as recycle stream (13). Net hydrogenation effluent is obtained as stream (9), and light gases as stream (7).
摘要翻译：在富烯烃脂肪族烃流（1）中选择性氢化二烯烃和炔属化合物的方法包括在40-300°F的低氢分压0.1-70psia下将进料流（1）在总共在含有用作蒸馏结构（10）的成分的氢化催化剂床（12）的蒸馏塔反应器（10）中的压力为0-350psig，例如包裹在管状丝网中的负载PdO。基本上没有发生烯烃的氢化。进料流（1）在催化剂床（12）的下端或下端进入，并与在催化剂床（12）中通过管线（2）进料的氢气接触。塔顶馏出物（3）在顶部获得，在冷凝器（20）中冷凝并在沉降器（30）中分离，并作为回流（6）部分地再循环回催化剂床（12）。底部物流（11）在蒸馏反应器的下端获得，并且在作为再循环物流（13）的热交换器（40）中加热后，以物流（4）的形式部分地再循环回来。净氢化流出物作为流（9）获得，轻质气体如流（7）获得。

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