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1. 发明申请

WO1998012158A1 PROCESS FOR THE TREATMENT OF LIGHT NAPHTHA HYDROCARBON STREAMS 审中-公开
标题翻译：用于处理轻质石墨烃流程的方法
公开(公告)号：WO1998012158A1
公开(公告)日：1998-03-26
申请号：PCT/US1997015133
申请日：1997-08-28
申请人： CHEMICAL RESEARCH & LICENSING COMPANY
发明人： CHEMICAL RESEARCH & LICENSING COMPANY , HEARN, Dennis , GILDERT, Gary, R.
IPC分类号： C07C05/00
CPC分类号： C10G65/06 , C10G2300/4087 , Y10S203/06
摘要： A process for treating a light cracked naphtha (1) to be used as an etherification or alkylation feedstock in which the mercaptans and diolefins react in a single pass fixed bed reactor (20) and are removed in a distillation column reactor (10) which hydrogenate the unreacted diolefins. The mercaptans are reacted with the diolefins to form sulfides which are higher boiling than that portion of the naphtha which is used as feed to the etherification or alkylation unit. The higher boiling sulfides are removed as bottoms along with any C6 and heavier materials. Any diolefins not converted to sulfides are selectively hydrogenated to mono-olefins for use in the etherification process. Certain C5 olefins, for example pentene-1 and 3-methyl butene-1 are isomerized during the process to more beneficial isomers.
摘要翻译：一种用于处理轻度裂化石脑油（1）的方法，其用作醚化或烷基化原料，其中硫醇和二烯烃在单程固定床反应器（20）中反应，并在蒸馏塔反应器（10）中除去，氢气化未反应的二烯烃。硫醇与二烯烃反应形成沸点高于用作醚化或烷基化单元的进料的石脑油部分的硫化物。较高沸点的硫化物作为底部以及任何C6和较重的材料被除去。任何未转化成硫化物的二烯烃都被选择性氢化成单烯烃，用于醚化过程。某些C5烯烃，例如戊烯-1和3-甲基丁烯-1在该过程中被异构化为更有益的异构体。

2. 发明申请

WO1998009930A1 SELECTIVE HYDROGENATION OF AROMATICS IN HYDROCARBON STREAMS 审中-公开
标题翻译：油气藏中芳烃选择性氢化
公开(公告)号：WO1998009930A1
公开(公告)日：1998-03-12
申请号：PCT/US1997014530
申请日：1997-08-18
申请人： CHEMICAL RESEARCH & LICENSING COMPANY
发明人： CHEMICAL RESEARCH & LICENSING COMPANY , GILDERT, Gary, R. , PUTMAN, Hugh, M. , HEARN, Dennis
IPC分类号： C07C05/10
CPC分类号： C10G45/44 , Y02P20/127 , Y10S203/06
摘要： A process for the hydrogenation of a selected aromatic, such as benzene contained in a naphtha stream to cyclohexane wherein the distillation column reactor (10) is operated such that the portion of the naphtha containing the benzene is maintained in the catalyst bed such that essentially only benzene is hydrogenated. The reactor is operated at a pressure wherein the reaction mixture is boiling under low hydrogen partial pressure in the range of about 0.1 psi to less than 70 psia at 0 to 350 psig. The catalyst is provided as a catalytic distillation structure (12) such that the reaction is concurrently occurring with a distillation. A portion of the overheads is returned as reflux to provide cooling within the catalyst bed and concurrent condensation of some of the gaseous material within the bed.
摘要翻译：将选择的芳族化合物，例如石脑油中所含的苯加氢至环己烷的方法，其中蒸馏塔反应器（10）的操作使得含有苯的部分石脑油保持在催化剂床中，使得基本上仅苯被氢化。反应器在压力下操作，其中反应混合物在0至350psig下在约0.1psi至小于70psia的低氢分压下沸腾。提供催化剂作为催化蒸馏结构（12），使得反应同时进行蒸馏。塔顶馏出物的一部分作为回流返回，以在催化剂床内提供冷却，同时使一些气态物质在床内冷凝。

3. 发明申请

WO1997003149A1 HYDRODESULFURIZATION PROCESS 审中-公开
标题翻译：水解过程
公开(公告)号：WO1997003149A1
公开(公告)日：1997-01-30
申请号：PCT/US1996010971
申请日：1996-06-27
申请人： CHEMICAL RESEARCH & LICENSING COMPANY
发明人： CHEMICAL RESEARCH & LICENSING COMPANY , HEARN, Dennis , PUTMAN, Hugh, M.
IPC分类号： C10G45/02
CPC分类号： C10G45/02
摘要： A process for the hydrodesulfurization of petroleum streams is disclosed wherein the sulfur containing petroleum stream is contacted along with hydrogen at a partial pressure of less than 70 psig in a distillation column reactor containing a hydrodesulfurization catalyst in the form of a catalytic distillation structure.
摘要翻译：公开了一种用于石油流加氢脱硫的方法，其中在含有催化蒸馏结构形式的加氢脱硫催化剂的蒸馏塔反应器中，含硫石油物流与低于70psig分压的氢气一起接触。

4. 发明申请

WO1995019946A1 METHOD FOR REMOVING CONTAMINANTS FROM HYDROCARBON STREAMS 审中-公开
标题翻译：从碳氢化合物流中除去污染物的方法
公开(公告)号：WO1995019946A1
公开(公告)日：1995-07-27
申请号：PCT/US1995000869
申请日：1995-01-24
申请人： CHEMICAL RESEARCH & LICENSING COMPANY
发明人： CHEMICAL RESEARCH & LICENSING COMPANY , ARGANBRIGHT, Robert, P. , JONES, Edward, M., Jr. , HEARN, Dennis
IPC分类号： C07C07/00
CPC分类号： C07C7/10 , C10G21/06 , C10G21/16 , C10G21/28
摘要： The present invention is a method for removing nitrile contaminants from C5 streams. In particular, a C5 stream (10) is washed in a countercurrent fashion with a mixture comprising 50 % methanol and 50 % water (18) to extract the nitriles from the C5 hydrocarbons into the water-methanol mixture (16). Propionitrile removal is enhanced by the presence of the methanol in the solvent. Further embodiments include (1) a method for recovering methanol from the extract stream by hydrogenating the nitriles to form amines, converting the amines to ammonium salts by acid treatment, and distilling out the methanol; and (2) a method for distilling out methanol/nitriles from the extract stream, admixing the methanol/nitriles with an alkane/alkene ether stream, then distilling the methanol out in an azeotrope with the alkane/alkenes whilst leaving the nitriles in the ether.
摘要翻译：本发明是从C5流中除去腈污染物的方法。特别地，将C5流（10）以与50％甲醇和50％水（18）的混合物逆流的方式洗涤，以将来自C5烃的腈提取到水 - 甲醇混合物（16）中。通过甲醇在溶剂中的存在来提高丙腈去除效果。进一步的实施方案包括（1）通过氢化腈形成胺从萃取物流中回收甲醇的方法，通过酸处理将胺转化成铵盐，并蒸出甲醇; 和（2）从萃取物流中蒸出甲醇/腈的方法，将甲醇/腈与烷烃/烯烃醚流混合，然后将甲醇与烷烃/烯烃共沸，同时将腈在醚中。

5. 发明申请

WO1998012160A1 PROCESS FOR CONCURRENT SELECTIVE HYDROGENATION OF ACETYLENES AND 1,2 BUTADIENE IN HYDROCARBON STREAMS 审中-公开
标题翻译：烯烃选择性氢化方法和1,2-二苯乙烯在氢气流中的选择性加氢
公开(公告)号：WO1998012160A1
公开(公告)日：1998-03-26
申请号：PCT/US1997015137
申请日：1997-08-28
申请人： CHEMICAL RESEARCH & LICENSING COMPANY
发明人： CHEMICAL RESEARCH & LICENSING COMPANY , GILDERT, Gary, R. , PUTMAN, Hugh, M. , HEARN, Dennis
IPC分类号： C07C07/10
CPC分类号： B01D3/009 , C07C7/163 , C07C7/167 , C07C2523/42 , C07C2523/44 , C07C2523/46 , C10G45/32 , C10G45/40 , C10G70/02 , Y02P20/127 , Y10S203/06
摘要： A process for the removal of vinylacetylene, ethylacetylene and 1,2-butadiene from C4 aliphatic hydrocarbon streams comprising, concurrently: (1) feeding hydrogen and a hydrocarbon stream comprising C4 hydrocarbons including butanes, butenes, butadienes and vinylacetylene to a distillation column reactor containing a bed comprising a hydrogenation catalyst of the type characterized by platinum, palladium or rhodium which is prepared as a distillation structure to selectively hydrogenate a portion of the vinylacetylene and the 1,2-butadiene and (2) fractionally distilling the reaction mixture to remove a heavier fraction and removing a fraction overhead comprising substantially all of the C4.
摘要翻译：一种从C4脂族烃流中除去乙烯基乙炔，乙乙炔和1,2-丁二烯的方法，包括同时：（1）将含有C4烃（包括丁烷，丁烯，丁二烯和乙烯基乙炔）的碳氢化合物进料到含有包含以铂，钯或铑为特征的类型的加氢催化剂的床，其被制备为蒸馏结构以选择性氢化一部分乙烯基乙炔和1,2-丁二烯，和（2）分级蒸馏反应混合物以除去较重的馏分并除去基本上全部C4的塔顶馏分。

6. 发明申请

WO1997028874A1 ETHERIFICATION-HYDROGENATION PROCESS 审中-公开
标题翻译：加氢加氢过程
公开(公告)号：WO1997028874A1
公开(公告)日：1997-08-14
申请号：PCT/US1996020896
申请日：1996-12-31
申请人： CHEMICAL RESEARCH & LICENSING COMPANY
发明人： CHEMICAL RESEARCH & LICENSING COMPANY , HEARN, Dennis , GILDERT, Gary, R. , GROTEN, Willibrord, A.
IPC分类号： B01D03/34
CPC分类号： B01D3/009 , C07C41/06 , C07C41/42 , Y02P20/127 , Y10S203/06 , C07C43/046
摘要： A process for removing dienes from etherification uses a hydrogenation zone (24) in the reactor distillation column (20) above the etherification zone (22). MTBE is produced and the unreacted C4 stream is also subjected to selected hydrogenation of the butadiene contained in the C4 feed stream. The C4 stream is introduced via line (101) and methanol is introduced via line (102) which is combined in flow line (104) and subsequently enters the distillation column (20) via line (103) wherein the C4 stream is contacted with methanol in the etherification zone (22) where the MTBE is distilled downward. The unreacted C4's then are subjected to selective hydrogenation in the hydrogenation zone (24) wherein butadiene in the overhead raffinate (108) is reduced by over 90 %. The hydrotreated C4's are thus suitable for cold acid alkylation or other use wherein butadiene is harmful.
摘要翻译：用于从醚化中除去二烯的方法在醚化区（22）上方的反应器蒸馏塔（20）中使用氢化区（24）。生产MTBE，并且还对未反应的C4物流进行C4进料流中包含的丁二烯的选择氢化。经由管线（101）引入C4流，并且经由管线（102）引入甲醇，该管线（102）在流动管线（104）中组合，随后通过管线（103）进入蒸馏塔（20），其中C4流体与甲醇接触在醚化区（22）中，MTBE向下蒸馏。然后在氢化区（24）中对未反应的C4进行选择性氢化，其中塔顶残液（108）中的丁二烯减少超过90％。因此，加氢处理的C4适合于冷酸烷基化或丁二烯有害的其它用途。

7. 发明申请

WO1996027580A1 HYDROGENATION OF UNSATURATED CYCLIC COMPOUNDS 审中-公开
标题翻译：不饱和环化合物的氢化
公开(公告)号：WO1996027580A1
公开(公告)日：1996-09-12
申请号：PCT/US1996001950
申请日：1996-02-09
申请人： CHEMICAL RESEARCH & LICENSING COMPANY
发明人： CHEMICAL RESEARCH & LICENSING COMPANY , GILDERT, Gary, R. , HEARN, Dennis , PUTMAN, Hugh, M. , NEMPHOS, Speros, Peter
IPC分类号： C07C209/72
CPC分类号： C07C209/72 , B01D3/009 , C07C5/10 , C07C2601/14 , Y02P20/127 , C07C13/18
摘要： A process for the hydrogenation of unsaturated cyclic and polycyclic compounds to saturates is provided wherein the reactor is operated at a pressure wherein the reaction mixture is boiling under low hydrogen partial pressure in the range of about 0.1 psi to less than 70 psia at 0 to 350 psig. The catalyst is provided as a catalytic distillation structure such that the reaction is concurrently occurring with a distillation. A portion of the overheads is returned as reflux to provide cooling within the catalyst bed and concurrent condensation of some of the gaseous material within the bed. Although no separation is obtained all of the advantages of concurrent reaction with distillation are achieved.
摘要翻译：提供了将不饱和环和多环化合物氢化成饱和物的方法，其中反应器在压力下操作，其中反应混合物在0至350℃的约0.1psi至小于70psia的低氢分压下沸腾磅。提供催化剂作为催化蒸馏结构，使得反应同时进行蒸馏。塔顶馏出物的一部分作为回流返回，以在催化剂床内提供冷却，同时使一些气态物质在床内冷凝。虽然没有分离，但是实现了与蒸馏同时反应的所有优点。

8. 发明申请

WO1998012281A1 HYDROCONVERSION PROCESS 审中-公开
标题翻译： HYDROCONVERSION过程
公开(公告)号：WO1998012281A1
公开(公告)日：1998-03-26
申请号：PCT/US1997015128
申请日：1997-08-28
申请人： CHEMICAL RESEARCH & LICENSING COMPANY
发明人： CHEMICAL RESEARCH & LICENSING COMPANY , HICKEY, Thomas, P. , HEARN, Dennis , PUTMAN, Hugh, M.
IPC分类号： C10G47/02
CPC分类号： B01D3/009 , C10G47/00
摘要： The hydroconversion of heavy petroliferous stocks boiling mainly above 400 DEG F is carried out in a distillation column reactor where concurrently a petroleum stream is fed into a feed zone; hydrogen is fed at a point below said feed zone; the petroleum stream is distilled and contacted in the presence of a cracking catalyst prepared in the form of a catalytic distillation structure at total pressure of less than about 300 psig and a hydrogen partial pressure in the range of 1.0 to less than 70 psia and a temperature in the range of 400 to 1000 DEG F whereby a portion of the petroleum stream is cracked to lighter products boiling below the boiling point of the feed and products are distilled to remove a vaporous overhead stream comprising products mainly boiling below the boiling point of the feed and a liquid bottoms stream.
摘要翻译：主要在400°F以上沸腾的重质含油气体的加氢转化在蒸馏塔反应器中进行，同时将石油流进料到进料区; 氢在所述进料区下方的一点进料; 在催化蒸馏结构形式的裂化催化剂存在下蒸馏并接触石油物流，其总压力小于约300psig，氢分压为1.0至小于70psia，温度为在400至1000°F的范围内，其中一部分石油流被裂解成低于进料沸点沸点的较轻的产物，并蒸馏产物以除去主要沸点低于进料沸点的产物的汽蒸塔顶物流和液体底部流。

9. 发明申请

WO1995015934A1 SELECTIVE HYDROGENATION OF HIGHLY UNSATURATED COMPOUNDS IN HYDROCARBON STREAMS 审中-公开
标题翻译：烃类化合物中高度不饱和化合物的选择性加氢
公开(公告)号：WO1995015934A1
公开(公告)日：1995-06-15
申请号：PCT/US1994007758
申请日：1994-07-21
申请人： CHEMICAL RESEARCH & LICENSING COMPANY
发明人： CHEMICAL RESEARCH & LICENSING COMPANY , HEARN, Dennis , ARGANBRIGHT, Robert, P. , JONES, Edward, M., Jr. , SMITH, Lawrence, A., Jr. , GILDERT, Gary, R.
IPC分类号： C07C05/05
CPC分类号： C10G70/02 , C10G45/32
摘要： A process for the selective hydrogenation of the diolefins and acetylenic compounds in an olefin-rich aliphatic hydrocarbon stream (1) comprises contacting the feed stream (1) at 40-300 DEG F under low hydrogen partial pressure of 0.1-70 psia at a total pressure of 0-350 psig in a distillation column reactor (10) containing a hydrogenation catalyst bed (12) which serves as a component of a distillation structure (10), such as supported PdO encased in a tubular wire mesh. Essentially no hydrogenation of the olefins occur. The feed stream (1) enters below or at the lower end of the catalyst bed (12), and is contacted with hydrogen fed through line (2) in the catalyst bed (12). The overhead (3) is obtained at the overhead, condensed in a condenser (20) and separated in a settler (30), and partially recycled back to catalyst bed (12) as a reflux stream (6). The bottom stream (11) is obtained at the lower end of the distillation reactor, and is partially recycled back as stream (4) after being heated in a heat exchanger (40) as recycle stream (13). Net hydrogenation effluent is obtained as stream (9), and light gases as stream (7).
摘要翻译：在富烯烃脂肪族烃流（1）中选择性氢化二烯烃和炔属化合物的方法包括在40-300°F的低氢分压0.1-70psia下将进料流（1）在总共在含有用作蒸馏结构（10）的成分的氢化催化剂床（12）的蒸馏塔反应器（10）中的压力为0-350psig，例如包裹在管状丝网中的负载PdO。基本上没有发生烯烃的氢化。进料流（1）在催化剂床（12）的下端或下端进入，并与在催化剂床（12）中通过管线（2）进料的氢气接触。塔顶馏出物（3）在顶部获得，在冷凝器（20）中冷凝并在沉降器（30）中分离，并作为回流（6）部分地再循环回催化剂床（12）。底部物流（11）在蒸馏反应器的下端获得，并且在作为再循环物流（13）的热交换器（40）中加热后，以物流（4）的形式部分地再循环回来。净氢化流出物作为流（9）获得，轻质气体如流（7）获得。

10. 发明申请

WO1994000235A1 CATALYTIC DISTILLATION STRUCTURE 审中-公开
标题翻译：催化蒸馏结构
公开(公告)号：WO1994000235A1
公开(公告)日：1994-01-06
申请号：PCT/US1993004589
申请日：1993-05-14
申请人： CHEMICAL RESEARCH & LICENSING COMPANY
发明人： CHEMICAL RESEARCH & LICENSING COMPANY , HEARN, Dennis
IPC分类号： B01J35/04
CPC分类号： B01J35/04 , B01J8/02 , B01J19/30 , B01J35/02 , B01J35/06 , B01J2208/00814 , B01J2219/30238 , B01J2219/30257 , B01J2219/30408 , B01J2219/30475 , Y10S203/06
摘要： A catalytic distillation structure comprising a tube of open mesh wire (6) containing particulate catalyst and sealed on each end (2), (5) along seams at 15 to 90 relative to each other.
摘要翻译：一种催化蒸馏结构，其包含含有颗粒催化剂的开口网丝（6）的管并且密封在每个端部（2）上，（5）沿着相对于彼此以15至90°的接缝。

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