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1. 发明申请

WO2011011492A2 DECARBOXYLATION CELL FOR PRODUCTION OF COUPLED RADICAL PRODUCTS 审中-公开
标题翻译：用于生产偶联产物的脱羧单元
公开(公告)号：WO2011011492A2
公开(公告)日：2011-01-27
申请号：PCT/US2010042715
申请日：2010-07-21
申请人： CERAMATEC INC , BHAVARAJU SAI , KARANJIKAR MUKUND , JOSHI ASHOK , HUNT JOEL , CHITTA PALLAVI
发明人： BHAVARAJU SAI , KARANJIKAR MUKUND , JOSHI ASHOK , HUNT JOEL , CHITTA PALLAVI
IPC分类号： C25B9/08 , C07C1/207 , C25B3/10
CPC分类号： C25B3/10 , C25B9/08
摘要： An electrolytic cell produces coupled radical products. The method involves obtaining a carboxylic acid material from biomass and converting it into an alkali metal salt. The alkali metal salt is then used in an anolyte as part of an electrolytic cell. The electrolytic cell may include an alkali ion conducting membrane (such as a NaSICON membrane). When the cell is operated, the alkali metal salt of the carboxylic acid decarboxylates and forms radicals. Such radicals are then bonded to other radicals, thereby producing a coupled radical product such as a hydrocarbon. The produced hydrocarbon may be, for example, saturated, unsaturated, branched, or unbranched, depending upon the starting material.
摘要翻译：电解池产生偶联的自由基产物。该方法包括从生物质获得羧酸物质并将其转化为碱金属盐。然后将碱金属盐用作阳极电解液作为电解池的一部分。电解池可以包括碱离子传导膜（例如NaSICON膜）。当电池操作时，羧酸的碱金属盐脱羧并形成自由基。然后将这些基团与其它基团键合，由此产生偶联的基团产物如烃。取决于起始原料，生成的烃可以是例如饱和的，不饱和的，支链的或非支链的。

2. 发明申请

WO2011011521A3 METHOD OF PRODUCING COUPLED RADICAL PRODUCTS 审中-公开
标题翻译：生产偶联产品的方法
公开(公告)号：WO2011011521A3
公开(公告)日：2011-05-05
申请号：PCT/US2010042756
申请日：2010-07-21
申请人： CERAMATEC INC , BHAVARAJU SAI , KARANJIKAR MUKUND , JOSHI ASHOK , HUNT DAVID , CHITTA PALLAVI
发明人： BHAVARAJU SAI , KARANJIKAR MUKUND , JOSHI ASHOK , HUNT DAVID , CHITTA PALLAVI
IPC分类号： C10K3/00 , C25B3/06
CPC分类号： C25B9/08 , C10G3/00 , C10G2300/1011 , C10G2300/44 , C25B3/10 , Y02P30/20
摘要： A method that produces coupled radical products. An alkali metal salt is used in an anolyte as part of an electrolytic cell. The electrolytic cell may include an alkali ion conducting membrane (such as a NaSICON membrane). When the cell is operated, the alkali metal salt of the carboxylic acid decarboxylates and forms radicals. Such radicals are then bonded to other radicals, thereby producing a coupled radical product such as a hydrocarbon.
摘要翻译：一种产生偶联产物的方法。在阳极电解液中使用碱金属盐作为电解池的一部分。电解池可以包括碱离子传导膜（例如NaSICON膜）。当电池操作时，羧酸的碱金属盐脱羧并形成自由基。然后将这些基团与其它基团键合，由此产生偶联的基团产物如烃。

3. 发明申请

WO2011011537A2 METHOD OF PRODUCING COUPLED RADICAL PRODUCTS FROM BIOMASS 审中-公开
标题翻译：从生物质生产耦合自由基产物的方法
公开(公告)号：WO2011011537A2
公开(公告)日：2011-01-27
申请号：PCT/US2010042780
申请日：2010-07-21
申请人： CERAMATEC INC , KARANJIKAR MUKUND , BHAVARAJU SAI , JOSHI ASHOK , CHITTA PALLAVI , HUNT DAVID
发明人： KARANJIKAR MUKUND , BHAVARAJU SAI , JOSHI ASHOK , CHITTA PALLAVI , HUNT DAVID
IPC分类号： C25B3/10 , C07C1/207 , C25B9/08
CPC分类号： C10G3/40 , C10G3/45 , C10G3/47 , C10G3/50 , C10G2300/1014 , C10G2300/1018 , C10G2300/44 , C10G2400/04 , C12P7/54 , C25B3/00 , C25B3/10 , C25B9/08 , Y02E50/343 , Y02P30/20
摘要： A method that produces coupled radical products from biomass. The method involves obtaining a lipid or carboxylic acid material from the biomass. This lipid material or carboxylic acid material is converted into an alkali metal salt. The alkali metal salt is then used in an anolyte as part of an electrolytic cell. The electrolytic cell may include an alkali ion conducting membrane (such as a NaSICON membrane). When the cell is operated, the alkali metal salt of the carboxylic acid decarboxylates and forms radicals. Such radicals are then bonded to other radicals, thereby producing a coupled radical product such as a hydrocarbon.
摘要翻译：一种从生物质产生偶联自由基产物的方法。该方法涉及从生物质获得脂质或羧酸材料。该脂质材料或羧酸材料被转化为碱金属盐。然后将碱金属盐用于阳极电解液中作为电解池的一部分。电解池可以包括碱离子传导膜（例如NaSICON膜）。当电池运行时，羧酸的碱金属盐脱羧并形成自由基。然后将这些基团键合到其他基团上，由此产生偶联的自由基产物如烃。

4. 发明申请

WO2011011521A2 METHOD OF PRODUCING COUPLED RADICAL PRODUCTS 审中-公开
标题翻译：生产偶联产品的方法
公开(公告)号：WO2011011521A2
公开(公告)日：2011-01-27
申请号：PCT/US2010042756
申请日：2010-07-21
申请人： CERAMATEC INC , BHAVARAJU SAI , KARANJIKAR MUKUND , JOSHI ASHOK , HUNT DAVID , CHITTA PALLAVI
发明人： BHAVARAJU SAI , KARANJIKAR MUKUND , JOSHI ASHOK , HUNT DAVID , CHITTA PALLAVI
IPC分类号： C10K3/00 , C25B3/06
CPC分类号： C25B9/08 , C10G3/00 , C10G2300/1011 , C10G2300/44 , C25B3/10 , Y02P30/20
摘要： A method that produces coupled radical products. An alkali metal salt is used in an anolyte as part of an electrolytic cell. The electrolytic cell may include an alkali ion conducting membrane (such as a NaSICON membrane). When the cell is operated, the alkali metal salt of the carboxylic acid decarboxylates and forms radicals. Such radicals are then bonded to other radicals, thereby producing a coupled radical product such as a hydrocarbon.
摘要翻译：一种产生耦合自由基产物的方法。碱金属盐在阳极电解液中用作电解槽的一部分。电解池可以包括碱离子传导膜（例如NaSICON膜）。当电池运行时，羧酸的碱金属盐脱羧并形成自由基。然后将这些基团键合到其他基团上，由此产生偶联的自由基产物如烃。

5. 发明申请

WO2012166530A2 BIO-OIL UPGRADING PROCESS 审中-公开
标题翻译：生物油升级过程
公开(公告)号：WO2012166530A2
公开(公告)日：2012-12-06
申请号：PCT/US2012039388
申请日：2012-05-24
申请人： CERAMATEC INC , CHITTA PALLAVI , KARANJIKAR MUKUND
发明人： CHITTA PALLAVI , KARANJIKAR MUKUND
IPC分类号： B01J23/72 , B01J21/08 , B01J23/46
CPC分类号： B01J23/83 , B01J21/08 , B01J23/70 , B01J23/72 , B01J35/023 , B01J35/1014 , B01J37/0036 , B01J37/0201 , B01J37/04 , C10G3/44 , C10G3/49 , C10G3/52 , C10L1/18 , Y02P30/20
摘要： A method for upgrading pyrolysis oil into a hydrocarbon fuel involves obtaining a quantity of pyrolysis oil, separating (130) the pyrolysis oil into an organic phase and an aqueous phase, and then upgrading (160) the organic phase into a hydrocarbon fuel by reacting the organic phase with hydrogen gas using a catalyst. The catalyst used in the reaction includes a support material, an active metal and a zirconia promoter material. The support material may be alumina, silica gel, carbon, silicalite or a zeolite material. The active metal may be copper, iron, nickel or cobalt. The zirconia promoter material may be zirconia itself, zirconia doped with Y, zirconia doped with Sc and zirconia doped with Yb.
摘要翻译：将热解油升级成烃燃料的方法包括获得一定数量的热解油，将热解油分离（130）成有机相和水相，然后通过使有机相（160）升级成烃类燃料有机相与氢气使用催化剂。用于反应的催化剂包括载体材料，活性金属和氧化锆促进剂材料。载体材料可以是氧化铝，硅胶，碳，硅沸石或沸石材料。活性金属可以是铜，铁，镍或钴。氧化锆促进剂材料可以是氧化锆本身，掺杂有Y的氧化锆，掺杂有Sc的氧化锆和用Yb掺杂的氧化锆。

6. 发明申请

WO2012103135A3 PRODUCTION OF FUEL FROM CHEMICALS DERIVED FROM BIOMASS 审中-公开
标题翻译：由生物质衍生的化学品生产燃料
公开(公告)号：WO2012103135A3
公开(公告)日：2012-11-22
申请号：PCT/US2012022425
申请日：2012-01-24
申请人： CERAMATEC INC , BHAVARAJU SAI , KARANJIKAR MUKUND
发明人： BHAVARAJU SAI , KARANJIKAR MUKUND
IPC分类号： C10G3/00 , B09B3/00 , C08B37/00 , C10L1/16
CPC分类号： C25B9/08 , C07C51/00 , C07C51/09 , C07C51/41 , C07C51/412 , C10L1/02 , C25B3/00 , C25B3/02 , Y02E50/13 , Y02P30/20 , C07C59/185 , C07C53/126 , C07C59/125
摘要： Hydrocarbons may be formed from six carbon sugars. This process involves obtaining a quantity of a hexose sugar. The hexose sugar may be derived from biomass. The hexose sugar is reacted to form an alkali metal levulinate, an alkali metal valerate, an alkali metal 5-hydroxy pentanoate, or an alkali metal 5-alkoxy pentanoate. An anolyte is then prepared for use in a electrolytic cell. The anolyte contains the alkali metal levulinate, the alkali metal valerate, the alkali metal 5-hydroxy pentanoate, or the alkali metal 5-alkoxy pentanoate. The anolyte is then decarboxylated. This decarboxylating operates to decarboxylate the alkali metal levulinate, the alkali metal valerate, the alkali metal 5-hydroxy pentanoate, or the alkali metal 5-alkoxy pentanoate to form radicals, wherein the radicals react to form a hydrocarbon fuel compound.
摘要翻译：碳氢化合物可以由六种碳糖形成。这个过程涉及获得一定数量的己糖。己糖可以来源于生物质。己糖反应形成碱金属乙酰丙酸盐，碱金属戊酸盐，碱金属5-羟基戊酸盐或碱金属5-烷氧基戊酸盐。然后制备用于电解池的阳极电解液。阳极电解液含有碱金属乙酰丙酸盐，碱金属戊酸盐，碱金属5-羟基戊酸盐或碱金属5-烷氧基戊酸盐。然后将阳极电解液脱羧。该脱羧作用是使碱金属乙酰丙酸盐，碱金属戊酸盐，碱金属5-羟基戊酸盐或碱金属5-烷氧基戊酸盐脱羧生成自由基，其中自由基反应形成烃燃料化合物。

7. 发明申请

WO2011133906A3 ELECTROCHEMICAL SYNTHESIS OF ARYL-ALKYL SURFACTANT PRECURSOR 审中-公开
标题翻译： ARYL-ALKYL表面活性剂前体的电化学合成
公开(公告)号：WO2011133906A3
公开(公告)日：2012-04-05
申请号：PCT/US2011033636
申请日：2011-04-22
申请人： CERAMATEC INC , BHAVARAJU SAI , KARANJIKAR MUKUND
发明人： BHAVARAJU SAI , KARANJIKAR MUKUND
IPC分类号： C25B3/04 , C25B3/00
CPC分类号： C25B3/10 , C25B9/08 , Y02E60/366
摘要： An aryl-alkyl (R-Ar) hydrocarbon is prepared by an electrosynthesis process in an electrolytic cell (100) having an alkali ion conductive membrane (110) positioned between an anolyte compartment (112) configured with an anode (116) and a catholyte compartment (114) configured with a cathode (118). An anolyte solution (124) containing an alkali metal salt of an alkyl carboxylic acid (128) and an aryl compound (130) is introduced into the anolyte compartment (112). The aryl compound (130) may include an alkali metal salt of an aryl carboxylic acid, an arene (aromatic) hydrocarbon, or an aryl alkali metal adduct (Ar- M+). The anolyte solution (124) undergoes electrolytic decarboxylation to form an alkyl radical. The alkyl radical reacts with the aryl compound to produce the aryl-alkyl hydrocarbon.
摘要翻译：在具有位于阳极（116）的阳极电解液室（112）和阴极电解液（116）之间的碱金属离子传导膜（110）的电解槽（100）中，通过电合成工艺制备芳基 - 烷基（R-Ar）隔室（114）配置有阴极（118）。将含有烷基羧酸（128）和芳基化合物（130）的碱金属盐的阳极电解液（124）引入阳极电解液室（112）中。芳基化合物（130）可以包括芳基羧酸的碱金属盐，芳烃（芳族）烃或芳基碱金属加合物（Ar-M +）。阳极电解液（124）进行电解脱羧以形成烷基。烷基与芳基化合物反应生成芳基 - 烷基烃。

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