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1. 发明申请

WO2009023452A1 METHODS FOR MAKING IMMOBILIZED ARYL-CONTAINING LIGANDS 审中-公开
标题翻译：用于制造含有ARYL的含ARLL的配体的方法
公开(公告)号：WO2009023452A1
公开(公告)日：2009-02-19
申请号：PCT/US2008/072001
申请日：2008-08-01
申请人： HEADWATERS TECHNOLOGY INNOVATION LLC , ZHOU, Bing , LIU, Changkun
发明人： ZHOU, Bing , LIU, Changkun
IPC分类号： B01J31/12
CPC分类号： B01J31/1633 , B01J31/2409 , B01J31/2452 , B01J2231/643 , B01J2531/821 , B01J2531/822
摘要： Organic ligands that contain at least one aryl group are immobilized on a solid support. The organic ligands are of the type used to form a catalyst complex suitable for carrying out a catalytic reaction, preferably an asymmetric reaction. To immobilize the organic ligands, a tethering group is bonded to the ligand using, for example, a Friedel-Crafts acylation or alkylation reaction. The immobilization of the organic ligand can be carried out using a single reaction with the organic ligand.
摘要翻译：含有至少一个芳基的有机配体固定在固体载体上。有机配体是用于形成适于进行催化反应，优选不对称反应的催化剂络合物的类型。为了固定有机配体，使用例如Friedel-Crafts酰化或烷基化反应将束缚基团键合到配体上。有机配体的固定可以使用与有机配体的单一反应进行。

2. 发明申请

WO2006078352A3 REFORMING NANOCATALYSTS AND METHOD OF MAKING AND USING SUCH CATALYSTS 审中-公开
标题翻译：重新制备纳米催化剂及其制备和使用这种催化剂的方法
公开(公告)号：WO2006078352A3
公开(公告)日：2007-10-25
申请号：PCT/US2005042841
申请日：2005-11-28
申请人： HEADWATERS TECH INNOVATION LLC , ZHOU BING , TREVINO HORACIO , WU ZHIHUA , ZHOU ZHENHUA , LIU CHANGKUN
发明人： ZHOU BING , TREVINO HORACIO , WU ZHIHUA , ZHOU ZHENHUA , LIU CHANGKUN
IPC分类号： C10G35/06
CPC分类号： C10G35/09 , B01J23/40 , B01J23/42 , B01J23/468 , B01J23/56 , B01J23/626 , B01J23/6567 , B01J23/8906 , B01J35/0013 , B01J35/006 , B01J37/0203 , B01J37/08 , B01J37/16 , B01J37/18 , B82Y30/00 , C10G35/085
摘要： Reforming nanocatalysts are formed using a dispersing agent to increase the activity, selectivity and longevity of the catalyst when used in a reforming process. The nanocatalyst particles are formed using a dispersing agent having at least one functional group selected from the group of a hydroxyl, a carboxyl, a carbonyl, an amide, an amine, a thiol, a sulfonic acid, sulfonyl halide, an acyl halide, an organometallic complex, and combinations of these. The dispersing agent is particularly useful for forming multicomponent catalysts comprising an alloy, combination, mixture, decoration, or interspersion of platinum and one or more of tin, rhenium or iridium. The formation of the nanoparticles may include a heat treating process performed in an inert or oxidative environment to maintain the catalyst atoms in a non-zero oxidation state to thereby maintain a stronger bond between the dispersing agent and the catalyst atoms. Multicomponent reforming catalysts having anchored nanocatalyst particles exhibit particularly good activity, selectivity and longevity when used in the reforming of naphtha and/or formation of BTX.
摘要翻译：使用分散剂形成纳米催化剂的重整，以提高催化剂在重整过程中的活性，选择性和使用寿命。纳米催化剂颗粒使用具有至少一个选自羟基，羧基，羰基，酰胺，胺，硫醇，磺酸，磺酰卤，酰基卤，有机金属络合物，以及它们的组合。分散剂特别可用于形成包含铂和锡，铼或铱中的一种或多种的合金，组合，混合物，装饰或间隙的多组分催化剂。纳米颗粒的形成可以包括在惰性或氧化环境中进行的热处理工艺，以保持催化剂原子处于非零氧化态，从而在分散剂和催化剂原子之间保持更强的键。具有锚定的纳米催化剂颗粒的多组分重整催化剂在用于石脑油重整和/或形成BTX时表现出特别好的活性，选择性和寿命。

3. 发明申请

WO2006078352A2 REFORMING NANOCATALYSTS AND METHOD OF MAKING AND USING SUCH CATALYSTS 审中-公开
标题翻译：重新制备纳米催化剂及其制备和使用这种催化剂的方法
公开(公告)号：WO2006078352A2
公开(公告)日：2006-07-27
申请号：PCT/US2005/042841
申请日：2005-11-28
申请人： HEADWATERS NANOKINETIX, INC. , ZHOU, Bing , TREVINO, Horacio , WU, Zhihua , ZHOU, Zhenhua , LIU, Changkun
发明人： ZHOU, Bing , TREVINO, Horacio , WU, Zhihua , ZHOU, Zhenhua , LIU, Changkun
IPC分类号： C10G35/09 , B01J31/00
CPC分类号： C10G35/09 , B01J23/40 , B01J23/42 , B01J23/468 , B01J23/56 , B01J23/626 , B01J23/6567 , B01J23/8906 , B01J35/0013 , B01J35/006 , B01J37/0203 , B01J37/08 , B01J37/16 , B01J37/18 , B82Y30/00 , C10G35/085
摘要： Reforming nanocatalysts are formed using a dispersing agent to increase the activity, selectivity and longevity of the catalyst when used in a reforming process. The nanocatalyst particles are formed using a dispersing agent having at least one functional group selected from the group of a hydroxyl, a carboxyl, a carbonyl, an amide, an amine, a thiol, a sulfonic acid, sulfonyl halide, an acyl halide, an organometallic complex, and combinations of these. The dispersing agent is particularly useful for forming multicomponent catalysts comprising an alloy, combination, mixture, decoration, or interspersion of platinum and one or more of tin, rhenium or iridium. The formation of the nanoparticles may include a heat treating process performed in an inert or oxidative environment to maintain the catalyst atoms in a non-zero oxidation state to thereby maintain a stronger bond between the dispersing agent and the catalyst atoms. Multicomponent reforming catalysts having anchored nanocatalyst particles exhibit particularly good activity, selectivity and longevity when used in the reforming of naphtha and/or formation of BTX.
摘要翻译：使用分散剂形成纳米催化剂的重整，以提高催化剂在重整过程中的活性，选择性和使用寿命。纳米催化剂颗粒使用具有至少一个选自羟基，羧基，羰基，酰胺，胺，硫醇，磺酸，磺酰卤，酰基卤，有机金属络合物，以及它们的组合。分散剂特别可用于形成包含铂和锡，铼或铱中的一种或多种的合金，组合，混合物，装饰或间隙的多组分催化剂。纳米颗粒的形成可以包括在惰性或氧化环境中进行的热处理工艺，以保持催化剂原子处于非零氧化态，从而在分散剂和催化剂原子之间保持更强的键。具有锚定的纳米催化剂颗粒的多组分重整催化剂在用于石脑油重整和/或形成BTX时表现出特别好的活性，选择性和寿命。

4. 发明申请

WO2007044614A3 CARBON NANOSTRUCTURES MANUFACTURED FROM CATALYTIC TEMPLATING NANOPARTICLES 审中-公开
标题翻译：碳纳米结构的催化纳米粒子催化模板制备
公开(公告)号：WO2007044614A3
公开(公告)日：2007-11-08
申请号：PCT/US2006039303
申请日：2006-10-06
申请人： HEADWATERS TECH INNOVATION LLC , ZHANG CHENG , FRANSOON MARTIN , LIU CHANGKUN , ZHOU BING
发明人： ZHANG CHENG , FRANSOON MARTIN , LIU CHANGKUN , ZHOU BING
IPC分类号： C01B31/02
CPC分类号： H01M4/96 , B01J21/18 , B01J21/185 , B01J23/40 , B01J23/74 , B01J37/084 , B82Y30/00 , C01B32/05 , H01M4/9083
摘要： Methods for manufacturing carbon nanostractures include: 1) forming a plurality of catalytic templating particles using a plurality of dispersing agent molecules; 2) forming an intermediate carbon nanostructure by polymerizing a carbon precursor in the presence of the plurality of templating nanoparticles; 3) carbonizing the intermediate carbon nanostructure to form a composite nanostructure; and 4) removing the templating nanoparticles from the composite nanostructure to yield the carbon nanostructures. The carbon nanostructures are well-suited for use as a catalyst support. The carbon nanostructures exhibit high surface area, high porosity, and high graphitization. Carbon nanostructures according to the invention can be used as a substitute for more expensive and likely more fragile carbon nanotubes.
摘要翻译：用于制造碳纳米压裂物的方法包括：1）使用多种分散剂分子形成多个催化模板颗粒; 2）通过在所述多个模板纳米颗粒存在下聚合碳前体来形成中间碳纳米结构; 3）碳化中间碳纳米结构以形成复合纳米结构; 和4）从复合纳米结构去除模板纳米颗粒以产生碳纳米结构。碳纳米结构非常适合用作催化剂载体。碳纳米结构表现出高表面积，高孔隙率和高石墨化。根据本发明的碳纳米结构可以用作更昂贵且可能更脆弱的碳纳米管的替代物。

5. 发明申请

WO2007044614A2 CARBON NANOSTRUCTURES MANUFACTURED FROM CATALYTIC TEMPLATING NANOPARTICLES 审中-公开
标题翻译：由催化态纳米粒子制备的碳纳米管
公开(公告)号：WO2007044614A2
公开(公告)日：2007-04-19
申请号：PCT/US2006/039303
申请日：2006-10-06
申请人： HEADWATERS NANOKINETIX, INC. , ZHANG, Cheng , FRANSOON, Martin , LIU, Changkun , ZHOU, Bing
发明人： ZHANG, Cheng , FRANSOON, Martin , LIU, Changkun , ZHOU, Bing
IPC分类号： C01B31/02
CPC分类号： H01M4/96 , B01J21/18 , B01J21/185 , B01J23/40 , B01J23/74 , B01J37/084 , B82Y30/00 , C01B32/05 , H01M4/9083
摘要： Methods for manufacturing carbon nanostractures include: 1) forming a plurality of catalytic templating particles using a plurality of dispersing agent molecules; 2) forming an intermediate carbon nanostructure by polymerizing a carbon precursor in the presence of the plurality of templating nanoparticles; 3) carbonizing the intermediate carbon nanostructure to form a composite nanostructure; and 4) removing the templating nanoparticles from the composite nanostructure to yield the carbon nanostructures. The carbon nanostructures are well-suited for use as a catalyst support. The carbon nanostructures exhibit high surface area, high porosity, and high graphitization. Carbon nanostructures according to the invention can be used as a substitute for more expensive and likely more fragile carbon nanotubes.
摘要翻译：制造碳纳米结构的方法包括：1）使用多个分散剂分子形成多个催化模板颗粒; 2）通过在多个模板纳米颗粒的存在下聚合碳前体形成中间碳纳米结构; 3）碳化中间碳纳米结构以形成复合纳米结构; 和4）从复合纳米结构中去除模板纳米颗粒以产生碳纳米结构。碳纳米结构非常适合用作催化剂载体。碳纳米结构表现出高的表面积，高孔隙率和高石墨化。根据本发明的碳纳米结构可用作更昂贵且可能更脆弱的碳纳米管的替代物。

6. 发明申请

WO2008042783A2 METHODS FOR PURIFYING POLYMERS USING SOLID SCAVENGERS 审中-公开
标题翻译：使用固体扫描仪净化聚合物的方法
公开(公告)号：WO2008042783A2
公开(公告)日：2008-04-10
申请号：PCT/US2007/079910
申请日：2007-09-28
申请人： HEADWATERS TECHNOLOGY INNOVATION LLC , LIU, Changkun , ZHOU, Bing
发明人： LIU, Changkun , ZHOU, Bing
IPC分类号： C08F8/00
CPC分类号： C08F6/02 , H01L51/0025 , H01L51/0036 , H01L51/0039 , H01L51/0043
摘要： Conductive polymers are purified using a solid scavenger. The solid scavengers include metal-scavenging functional groups linked to the surface of a particle support material. To improve the functionalization of the support material, the support materials are first treated with sulfuric acid or nitric acid before attaching the molecules containing the metal-scavenging functional groups. The solid scavengers used in the purification methods are more efficient at removing impurities in conductive polymers than existing scavengers.
摘要翻译：使用固体清除剂纯化导电聚合物。固体清除剂包括连接到颗粒载体材料表面的金属清除官能团。为了改善载体材料的功能化，首先在将含有金属清除功能基团的分子连接之前，用硫酸或硝酸处理载体材料。净化方法中使用的固体清除剂在除去导电聚合物中的杂质比现有的清除剂更有效。

7. 发明申请

WO2008016956A3 METHODS FOR MANUFACTURING ARY-ARYL COUPLED POLYMERS 审中-公开
标题翻译：制造ARY-ARYL联合聚合物的方法
公开(公告)号：WO2008016956A3
公开(公告)日：2008-12-04
申请号：PCT/US2007074922
申请日：2007-08-01
申请人： HEADWATERS TECH INNOVATION LLC , LIU CHANGKUN , ZHOU BING
发明人： LIU CHANGKUN , ZHOU BING
IPC分类号： C08G79/02 , C07D213/26 , C07D239/30 , C08G79/08
CPC分类号： C08G61/12 , C08G61/02 , C08G61/123 , C08G61/126 , C08G2261/124 , C08G2261/3142 , C08G2261/3162 , C08G2261/3223 , C08G2261/3243 , C08G2261/3246 , H01L51/0039 , H01L51/0043
摘要： Aryl-aryl coupled polymers are manufactured using a water-soluble noble metal catalyst. The hydrophilicity of the catalyst facilitates the separation of the catalyst from the polymer product. The method can be generally carried out by preparing a reaction medium comprising an aqueous phase and an organic phase. A water-soluble noble metal catalyst is dispersed in the aqueous phase. A base is also dispersed in the aqueous phase. An aryl-aryl coupled polymer is formed in the reaction medium by (i) adding at least one polymerizable monomer to the reaction mixture; and (ii) mixing the aqueous phase with the organic phase to cause polymerization of the monomer through an aryl-aryl coupling reaction. The polymer has a greater solubility in the organic phase than the aqueous phase. Allowing the organic phase to separate from the aqueous phase separates the water soluble catalyst from the polymer. The reaction can be used to manufacture high molecular weight polymers (e.g., at least 10,000 g/mole) with low quantities of residual metal (e.g., less than 20 ppm).
摘要翻译：芳基 - 芳基偶联聚合物是使用水溶性贵金属催化剂制备的。催化剂的亲水性促进了催化剂与聚合物产物的分离。该方法通常可以通过制备包含水相和有机相的反应介质进行。将水溶性贵金属催化剂分散在水相中。碱也分散在水相中。通过（i）向反应混合物中加入至少一种可聚合单体，在反应介质中形成芳基 - 芳基偶联聚合物; 和（ii）将水相与有机相混合以使单体通过芳基 - 芳基偶联反应聚合。聚合物在有机相中的溶解度高于水相。使有机相与水相分离使水溶性催化剂与聚合物分离。该反应可用于制备具有少量残余金属（例如小于20ppm）的高分子量聚合物（例如至少10,000g / mol）。

8. 发明申请

WO2008042783A3 METHODS FOR PURIFYING POLYMERS USING SOLID SCAVENGERS 审中-公开
标题翻译：用固体清除剂纯化聚合物的方法
公开(公告)号：WO2008042783A3
公开(公告)日：2008-07-03
申请号：PCT/US2007079910
申请日：2007-09-28
申请人： HEADWATERS TECH INNOVATION LLC , LIU CHANGKUN , ZHOU BING
发明人： LIU CHANGKUN , ZHOU BING
IPC分类号： C08F6/28
CPC分类号： C08F6/02 , H01L51/0025 , H01L51/0036 , H01L51/0039 , H01L51/0043
摘要： Conductive polymers are purified using a solid scavenger. The solid scavengers include metal-scavenging functional groups linked to the surface of a particle support material. To improve the functionalization of the support material, the support materials are first treated with sulfuric acid or nitric acid before attaching the molecules containing the metal-scavenging functional groups. The solid scavengers used in the purification methods are more efficient at removing impurities in conductive polymers than existing scavengers.
摘要翻译：导电聚合物使用固体清除剂进行纯化。固体清除剂包括连接到颗粒载体材料表面的金属清除官能团。为了改善载体材料的官能化，首先用硫酸或硝酸处理载体材料，然后连接含有金属清除官能团的分子。纯化方法中使用的固体清除剂比现有清除剂更有效地去除导电聚合物中的杂质。

9. 发明申请

WO2008016956A2 METHODS FOR MANUFACTURING ARY-ARYL COUPLED POLYMERS 审中-公开
标题翻译：制备芳族 - 芳族偶联聚合物的方法
公开(公告)号：WO2008016956A2
公开(公告)日：2008-02-07
申请号：PCT/US2007/074922
申请日：2007-08-01
申请人： HEADWATERS TECHNOLOGY INNOVATION LLC , LIU, Changkun , ZHOU, Bing
发明人： LIU, Changkun , ZHOU, Bing
IPC分类号： C08G79/02
CPC分类号： C08G61/12 , C08G61/02 , C08G61/123 , C08G61/126 , C08G2261/124 , C08G2261/3142 , C08G2261/3162 , C08G2261/3223 , C08G2261/3243 , C08G2261/3246 , H01L51/0039 , H01L51/0043
摘要： Aryl-aryl coupled polymers are manufactured using a water-soluble noble metal catalyst. The hydrophilicity of the catalyst facilitates the separation of the catalyst from the polymer product. The method can be generally carried out by preparing a reaction medium comprising an aqueous phase and an organic phase. A water-soluble noble metal catalyst is dispersed in the aqueous phase. A base is also dispersed in the aqueous phase. An aryl-aryl coupled polymer is formed in the reaction medium by (i) adding at least one polymerizable monomer to the reaction mixture; and (ii) mixing the aqueous phase with the organic phase to cause polymerization of the monomer through an aryl-aryl coupling reaction. The polymer has a greater solubility in the organic phase than the aqueous phase. Allowing the organic phase to separate from the aqueous phase separates the water soluble catalyst from the polymer. The reaction can be used to manufacture high molecular weight polymers (e.g., at least 10,000 g/mole) with low quantities of residual metal (e.g., less than 20 ppm).
摘要翻译：使用水溶性贵金属催化剂制造芳基 - 芳基偶联聚合物。催化剂的亲水性有利于催化剂与聚合物产物的分离。该方法通常可以通过制备包含水相和有机相的反应介质来进行。水溶性贵金属催化剂分散在水相中。碱也分散在水相中。通过（i）将至少一种可聚合单体加入到反应混合物中，在反应介质中形成芳基 - 芳基偶联聚合物; 和（ii）将水相与有机相混合以引起单体通过芳基 - 芳基偶联反应进行聚合。聚合物在有机相中的溶解度高于水相。让有机相与水相分离，将水溶性催化剂从聚合物中分离出来。该反应可用于制备具有低量残余金属（例如小于20ppm）的高分子量聚合物（例如至少10,000克/摩尔）。

10. 发明申请

WO2007084904A3 METHODS FOR MANUFACTURING FUNCTIONALIZED INORGANIC OXIDES AND POLYMERS INCORPORATING SAME 审中-公开
公开(公告)号：WO2007084904A3
公开(公告)日：2007-07-26
申请号：PCT/US2007/060610
申请日：2007-01-17
申请人： HEADWATERS TECHNOLOGY INNOVATION LLC , ZHOU, Bing , LIU, Changkun , REYES, Clementine
发明人： ZHOU, Bing , LIU, Changkun , REYES, Clementine
IPC分类号： B01D15/00 , C02F1/42
摘要： Inorganic oxide substrates axe functionalized with silicon-free organic functionalizing agents. The organic functionalizing agent has a bonding functional group for bonding to the substrate and a functionalizmg moiety that is not bonded to the substrate for imparting a desired functionality to the substrate. The functionalized inorganic oxide substrates are manufactured by selecting a functionalizing agent and reaction conditions that allows the bonding functional group to bond to the inorganic material while leaving the functionalizing moiety available for providing the desired functionality. The functionalized inorganic oxides can be used as filler materials in polymers or to manufacture a supported nanoparticle catalyst.

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