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    • 5. 发明申请
    • METHODS FOR MANUFACTURING ARY-ARYL COUPLED POLYMERS
    • 制造ARY-ARYL联合聚合物的方法
    • WO2008016956A3
    • 2008-12-04
    • PCT/US2007074922
    • 2007-08-01
    • HEADWATERS TECH INNOVATION LLCLIU CHANGKUNZHOU BING
    • LIU CHANGKUNZHOU BING
    • C08G79/02C07D213/26C07D239/30C08G79/08
    • C08G61/12C08G61/02C08G61/123C08G61/126C08G2261/124C08G2261/3142C08G2261/3162C08G2261/3223C08G2261/3243C08G2261/3246H01L51/0039H01L51/0043
    • Aryl-aryl coupled polymers are manufactured using a water-soluble noble metal catalyst. The hydrophilicity of the catalyst facilitates the separation of the catalyst from the polymer product. The method can be generally carried out by preparing a reaction medium comprising an aqueous phase and an organic phase. A water-soluble noble metal catalyst is dispersed in the aqueous phase. A base is also dispersed in the aqueous phase. An aryl-aryl coupled polymer is formed in the reaction medium by (i) adding at least one polymerizable monomer to the reaction mixture; and (ii) mixing the aqueous phase with the organic phase to cause polymerization of the monomer through an aryl-aryl coupling reaction. The polymer has a greater solubility in the organic phase than the aqueous phase. Allowing the organic phase to separate from the aqueous phase separates the water soluble catalyst from the polymer. The reaction can be used to manufacture high molecular weight polymers (e.g., at least 10,000 g/mole) with low quantities of residual metal (e.g., less than 20 ppm).
    • 芳基 - 芳基偶联聚合物是使用水溶性贵金属催化剂制备的。 催化剂的亲水性促进了催化剂与聚合物产物的分离。 该方法通常可以通过制备包含水相和有机相的反应介质进行。 将水溶性贵金属催化剂分散在水相中。 碱也分散在水相中。 通过(i)向反应混合物中加入至少一种可聚合单体,在反应介质中形成芳基 - 芳基偶联聚合物; 和(ii)将水相与有机相混合以使单体通过芳基 - 芳基偶联反应聚合。 聚合物在有机相中的溶解度高于水相。 使有机相与水相分离使水溶性催化剂与聚合物分离。 该反应可用于制备具有少量残余金属(例如小于20ppm)的高分子量聚合物(例如至少10,000g / mol)。
    • 7. 发明申请
    • METHODS FOR MANUFACTURING ARY-ARYL COUPLED POLYMERS
    • 制备芳族 - 芳族偶联聚合物的方法
    • WO2008016956A2
    • 2008-02-07
    • PCT/US2007/074922
    • 2007-08-01
    • HEADWATERS TECHNOLOGY INNOVATION LLCLIU, ChangkunZHOU, Bing
    • LIU, ChangkunZHOU, Bing
    • C08G79/02
    • C08G61/12C08G61/02C08G61/123C08G61/126C08G2261/124C08G2261/3142C08G2261/3162C08G2261/3223C08G2261/3243C08G2261/3246H01L51/0039H01L51/0043
    • Aryl-aryl coupled polymers are manufactured using a water-soluble noble metal catalyst. The hydrophilicity of the catalyst facilitates the separation of the catalyst from the polymer product. The method can be generally carried out by preparing a reaction medium comprising an aqueous phase and an organic phase. A water-soluble noble metal catalyst is dispersed in the aqueous phase. A base is also dispersed in the aqueous phase. An aryl-aryl coupled polymer is formed in the reaction medium by (i) adding at least one polymerizable monomer to the reaction mixture; and (ii) mixing the aqueous phase with the organic phase to cause polymerization of the monomer through an aryl-aryl coupling reaction. The polymer has a greater solubility in the organic phase than the aqueous phase. Allowing the organic phase to separate from the aqueous phase separates the water soluble catalyst from the polymer. The reaction can be used to manufacture high molecular weight polymers (e.g., at least 10,000 g/mole) with low quantities of residual metal (e.g., less than 20 ppm).
    • 使用水溶性贵金属催化剂制造芳基 - 芳基偶联聚合物。 催化剂的亲水性有利于催化剂与聚合物产物的分离。 该方法通常可以通过制备包含水相和有机相的反应介质来进行。 水溶性贵金属催化剂分散在水相中。 碱也分散在水相中。 通过(i)将至少一种可聚合单体加入到反应混合物中,在反应介质中形成芳基 - 芳基偶联聚合物; 和(ii)将水相与有机相混合以引起单体通过芳基 - 芳基偶联反应进行聚合。 聚合物在有机相中的溶解度高于水相。 让有机相与水相分离,将水溶性催化剂从聚合物中分离出来。 该反应可用于制备具有低量残余金属(例如小于20ppm)的高分子量聚合物(例如至少10,000克/摩尔)。
    • 10. 发明申请
    • PHOSPHAZENE COMPOUND, PHOTOSENSITIVE RESIN COMPOSITION AND USE THEREOF
    • 磷酸酯化合物,感光树脂组合物及其用途
    • WO2005019231A8
    • 2005-10-20
    • PCT/JP2004007719
    • 2004-06-03
    • KANEKA CORPOKADA KOJIYAMANAKA TOSHIO
    • OKADA KOJIYAMANAKA TOSHIO
    • C07F9/06C07F9/6581C08G79/02G03F7/027G03F7/032G03F7/037G03F7/038C07F9/24C08K5/5399C08L79/08G03F7/004
    • C08G79/025C07F9/067C07F9/65812G03F7/027G03F7/032G03F7/037G03F7/0388
    • A phosphazene compound and photosensitive resin composition suitable for production of wiring boards, having such characteristics that no halogenated flame retardants are used; a water base development can be made; desirable pattern morphology can be realized; a balance can be struck between properties such as thermal stability, resistance to hydrolysis, processability and adherence on the one hand and photosensitivity, flame resistance and mechanical strength on the other hand; and they can meet the demand for miniaturization and weight reduction of electronic parts. There is provided a phosphazene compound that has in its molecule an unsaturated double bond resulting from reaction of phenoxyphosphazene compound having a phenolic hydroxyl and/or crosslinked phenoxyphosphazene compound obtained by crosslinking of the phenoxyphosphazene compound with epoxy compound having an unsaturated double bond and/or isocyanate compound. Furthermore, there is provided a photosensitive resin composition comprising the phenoxyphosphazene compound and at least carboxylated and/or hydroxylated soluble polyimide resin, and further comprising (meth)acrylic compound.
    • 适用于生产线路板的磷腈化合物和感光性树脂组合物,具有不使用卤化阻燃剂的特性; 可以进行水基开发; 可以实现理想的图案形态; 另一方面,热稳定性,耐水解性,加工性和粘附性等特性与光敏性,阻燃性和机械强度之间存在平衡。 它们可以满足电子零件的小型化和减重的需求。 提供了一种磷腈化合物,其在其分子中具有由具有酚氧基和/或交联的苯氧基磷腈化合物的苯氧基磷腈化合物与苯氧基磷腈化合物与具有不饱和双键的环氧化合物和/或异氰酸酯交联而得到的不饱和双键 复合。 此外,提供了包含苯氧基磷腈化合物和至少羧化和/或羟基化的可溶性聚酰亚胺树脂的光敏树脂组合物,并且还包含(甲基)丙烯酸化合物。