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    • 3. 发明申请
    • Thermosetting resin composition and adhesive films
    • 热固性树脂组合物和粘合膜
    • US20050228079A1
    • 2005-10-13
    • US10509023
    • 2003-03-26
    • Toru FujikiToshiki MoriHironobu IyamaShigeki Naitoh
    • Toru FujikiToshiki MoriHironobu IyamaShigeki Naitoh
    • C08L63/00C08L15/00C08L61/06C08L61/08C08L65/00C09J7/00C09J7/02C09J123/02C09J161/06C09J163/00
    • C08L61/06C08L63/00C09J7/10C09J2461/00C09J2463/00C08L2666/22
    • The present invention provides a thermosetting resin composition containing the following (A) component and (B) component, an adhesive containing the thermosetting resin composition and an organic solvent and/or water, and an adhesive film containing the thermosetting resin composition. (A) component: at least one kind of phenol resin selected from the group consisting of alkylphenol novolak, a phenol adduct of an aliphatic polymer containing a double bond, and a phenol adduct of an alicyclic polymer containing a double bond (B) component: epoxy group—containing ethylene-based copolymer obtained by polymerizing the following (b1) and (b2): (b1) ethylene and/or propylene (b2) monomer represented by the following formula (1): (wherein R represents a hydrocarbon group of a carbon number of 2 to 18 having a double bond, wherein at least one of hydrogen atoms of the hydrocarbon group may be substituted with a halogen atom, a hydroxyl group or a carboxyl group, and X represents a single bond or a carbonyl group).
    • 本发明提供一种含有下述(A)成分和(B)成分的热固性树脂组合物,含有热固性树脂组合物和有机溶剂和/或水的粘合剂和含有热固性树脂组合物的粘合剂膜。 (A)成分:选自烷基酚酚醛清漆,含有双键的脂肪族聚合物的苯酚加合物和含有双键的脂环式聚合物(B)成分的苯酚加合物中的至少一种酚醛树脂: 通过聚合以下(b 1/2)和(b 2/2):乙烯和(b 1/2)乙烯获得的含环氧基的乙烯基共聚物和 /或由下式(1)表示的丙烯(b 2/2)单体:(其中R表示具有双键的碳数为2至18的烃基,其中至少一个氢 烃基的原子可以被卤素原子,羟基或羧基取代,X表示单键或羰基)。
    • 4. 发明授权
    • Polymerizable compositions containing olefin metathesis catalysts and
cocatalysts, and methods of use therefor
    • 含有烯烃复分解催化剂和助催化剂的可聚合组合物及其使用方法
    • US5296566A
    • 1994-03-22
    • US992381
    • 1992-12-16
    • Katherine A. Brown-WensleyMichael C. PalazzottoWilliam M. LamannaLarry D. BoardmanJohn E. GozumFred B. McCormic
    • Katherine A. Brown-WensleyMichael C. PalazzottoWilliam M. LamannaLarry D. BoardmanJohn E. GozumFred B. McCormic
    • C08F4/06C08F4/42C08F4/80C08G61/06C08G61/08C08L61/08
    • C08G61/08Y10S526/943
    • Polymerization of ring-strained cyclic olefins takes place in the presence of a one-part or two-part catalyst which is air and moisture stable and which comprises a transition metal-containing compound.The one-part transition metal-containing catalyst is selected from the group consisting of(a) compounds of the formula(L.sup.1)(L.sup.2)Q whereinQ represents Mo or W;L.sup.1 represents one to six CO (carbonyl) ligands;L.sup.2 represents none to 5 ligands, each of which is a non-ionic compound or unit of a polymer which can be the same or different, each contributes two, four, or six electrons to the metal and is different from L.sup.1 ; wherein the sum of the valence electrons of Q and the electrons contributed by the ligands L.sup.1 and L.sup.2 is 18,(b) at least one of cationic ruthenium and osmium-containing organometallic salts having at least one polyene ligand, and(c) [Ir(RO.sub.2 CHC.dbd.CHCO.sub.2 R).sub.2 Cl].sub.2 wherein each R independently is hydrogen or lower alkyl (C.sub.1 to C.sub.4), provided that the oxidation state of the metal is in the range of +3 to 0, and that cocatalysts containing C-halogen bonds are not present.The two-part catalyst comprises(a) a transition metal-containing catalyst, provided that the oxidation state of the transition metal is in the range of +3 to 0, and(b) a cocatalyst selected from the group consisting of(i) terminal or silyl alkynes,(ii) organosilanes containing at least one of ##STR1## groups, (iii) oxidative salts or oxidative compounds containing an oxygen atom to non-oxygen atom double bond, and(iv) heteroatom-containing alkenes.The polymerized composition is useful to provide molded articles, elastomers, dielectric supports, ionophoric or biologically active materials, composite materials, and the like.
    • 环应变环状烯烃的聚合在其为空气和湿气稳定的,并且其包括一个含过渡金属的化合物的一部分或两部分催化剂的存在下进行。 单部分含过渡金属的催化剂选自(a)式(L1)(L2)Q,其中Q代表Mo或W的化合物的组中选择; L1代表一至六个CO(羰基)配体; L2代表无5个配体,它们各自是可以相同或不同的非离子化合物或聚合物单元,每个赋予金属二,四或六个电子,并且不同于L1; 其中Q和由配体L1和L2贡献的电子的价数之和为18,(b)至少一种具有至少一个多烯配体的阳离子钌和含锇的有机金属盐,和(c)(Ir (RO2CHC = CHCO2R)2Cl)2,其中每个R独立地为氢或低级烷基(C1-C4),条件是金属的氧化态在+3至0的范围内,并且含有C-卤键的助催化剂为 不存在。 两部分催化剂包括(a)含过渡金属的催化剂,条件是过渡金属的氧化态在+3至0的范围内,和(b)选自(i)的助催化剂, 末端或甲硅烷基炔,(ii)含有(*化学结构*)基团中的至少一个的有机硅烷,(iii)含氧原子与非氧原子双键的氧化性盐或氧化性化合物,和(iv)含杂原子的烯烃 。 所述聚合的组合物是提供模塑制品,弹性体,电介质支撑件,离子载体或生物活性材料,复合材料,等是有用的。