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    • 3. 发明授权
    • Process for producing a purified synthesis gas stream
    • 用于生产纯化的合成气流的方法
    • US08772361B2
    • 2014-07-08
    • US13262109
    • 2010-03-30
    • Gerald Sprachmann
    • Gerald Sprachmann
    • C07C27/00B01J8/00C01C3/00
    • C01B3/16B01D53/75B01D2257/304B01D2257/308B01D2257/406B01D2257/408B01D2257/504C01B3/501C01B3/506C01B3/52C01B3/56C01B3/58C01B17/05C01B17/164C01B2203/0415C01B2203/0435C01B2203/0465C01B2203/0475C01B2203/0485Y02P20/152
    • A process for producing a purified synthesis gas stream from a feed synthesis gas stream comprising besides the main constituents carbon monoxide and hydrogen also hydrogen sulphide, HCN and/or COS, the process comprising the steps of: (a) contacting one part of the feed synthesis gas stream with a water gas shift catalyst in a shift reactor in the presence of water and/or steam to react at least part of the carbon monoxide to hydrogen and carbon dioxide, to obtain a shifted synthesis gas stream enriched in hydrogen and in carbon dioxide; (b) contacting another part of the feed gas stream with a hydrolysis catalyst in the presence of water to remove HCN and/or COS to obtain a hydrolysed synthesis gas stream depleted in HCN and/or COS; (c) removing H2S from the shifted synthesis gas stream and from the hydrolysed synthesis gas stream by contacting these gas streams in a H2S-removal zone with an aqueous alkaline washing liquid to obtain a H2S-depleted synthesis gas stream and a sulphide-comprising aqueous stream; (d) contacting the sulphide-comprising aqueous stream with sulphide-oxidizing bacteria in the presence of oxygen in a bioreactor to obtain a sulphur slurry and aregenerated aqueous alkaline washing liquid; (e) removing carbon dioxide from the H2S-depleted synthesis gas stream, to obtain the purified synthesis gas stream.
    • 一种从原料合成气流生产纯化的合成气流的方法,除了主要成分一氧化碳和氢气外,还包括硫化氢,HCN和/或COS,该方法包括以下步骤:(a)使一部分进料 合成气流与水煤气变换催化剂在变换反应器中在水和/或蒸汽存在下反应至少一部分一氧化碳与氢气和二氧化碳,以获得富含氢气和碳的转移合成气流 二氧化碳 (b)在水存在下使进料气流的另一部分与水解催化剂接触以除去HCN和/或COS,以获得耗尽HCN和/或COS的水解合成气流; (c)通过将H2S去除区中的这些气流与碱性洗涤液水溶液接触,从移动的合成气流和水解的合成气流中除去H 2 S,以获得贫硫酸的合成气流和含硫化物的水 流; (d)在生物反应器中,在氧的存在下使含硫化物的含水物流与硫化物 - 氧化细菌接触以获得硫浆液并且生成水性碱性洗涤液; (e)从除去H2S的合成气流中除去二氧化碳,以获得纯化的合成气流。
    • 4. 发明授权
    • Ammonium recovery from waste water using CO2 acidified absorption water
    • 使用CO2酸化吸收水从废水中回收铵
    • US08486359B2
    • 2013-07-16
    • US13190355
    • 2011-07-25
    • Robert Hickey
    • Robert Hickey
    • C01C3/00
    • C01C1/26C10G2300/1011C10K1/08Y02P30/20
    • The processes are utilized to recover ammonium from waste water using CO2 acidified absorption water. The process is particularly suited for utilization of cellular matter and a CO2 rich tail gas from a syngas fermentation process and derives significant benefit from the recovery of ammonium bicarbonate and ammonium carbonate. Ammonia and ammonium are recovered from the treatment of the syngas as an ammonium rich solution, at least a portion of which is recycled to the fermentation zone to aid in the production of liquid products. A carbon dioxide rich gas produced by fermentation is used to capture the ammonia and ammonium, forming the ammonium rich solution.
    • 该方法用于使用CO2酸化吸收水从废水中回收铵。 该方法特别适用于从合成气发酵过程中利用细胞物质和富含CO 2的尾气,并从碳酸氢铵和碳酸铵的回收中获得显着的益处。 从作为富铵溶液的合成气的处理中回收氨和铵,其中至少一部分被再循环到发酵区以帮助生产液体产物。 通过发酵产生的富含二氧化碳的气体用于捕获氨和铵,形成富铵溶液。