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    • 1. 发明申请
    • Method for producing pulp and lignin
    • 生产纸浆和木质素的方法
    • US20040244925A1
    • 2004-12-09
    • US10728976
    • 2003-12-08
    • David Tarasenko
    • D21C003/02D21C011/00D21C003/16
    • D21C1/04D21C3/02D21C11/04
    • The invention provides for methods for producing pulp (comprising cellulose) and lignin from lignocellulosic material, such as wood chips. The methods involve acid catalyzed hydrolysis. Lignocellulosic material having a relatively high moisture concentration can be used as the starting material. The lignocellulosic material is impregnated with an acid (preferably nitric acid) and heated. During the heating lignin is depolymerized at relatively low temperatures, and the acid catalyst is distilled off. The acid catalyst can be collected and recycled after impregnation and heating. The lignocellulosic material is then digested in an alkaline solution under heat, dissolving the lignin and allowing the pulp to be removed. Acid is added to the black liquor to precipitate the lignin which is then removed. The resultant amber liquor can be further processed into other ancillary products such as alcohols and/or unicellular proteins.
    • 本发明提供了用于从木质纤维素材料如木屑生产纸浆(包括纤维素)和木质素的方法。 该方法涉及酸催化水解。 可以使用具有较高水分浓度的木质纤维素材料作为原料。 木质纤维素材料用酸(优选硝酸)浸渍并加热。 在加热期间,木质素在较低温度下解聚,并将酸催化剂蒸馏掉。 浸渍和加热后可以收集和回收酸催化剂。 然后将木质纤维素材料在碱性溶液中加热消化,溶解木质素并允许除去纸浆。 将酸加入到黑液中以沉淀木质素,然后将其除去。 所得琥珀色液体可以进一步加工成其它辅助产物如醇和/或单细胞蛋白。
    • 3. 发明申请
    • Lignins derived from black liquor
    • 来自黑液的木质素
    • US20030221804A1
    • 2003-12-04
    • US10161508
    • 2002-06-03
    • Gene E. Lightner
    • D21C011/00D21C011/04D21C003/20
    • C08H6/00C10G1/04C10J3/00C10J2300/092C10J2300/0973D21C11/0007Y02P40/44
    • Depolymerized lignins contained within black liquor are transferred to an organic solvent, soluble in organic matter and insoluble of aqueous sodium compounds contained within the black liquor. Upon separation of the aqueous sodium compounds from the organic solvent, saturated with contained depolymerized lignins, depolymerized lignins are removed from the organic solvent to result in depolymerized lignins and a separated organic solvent suitable for recycling. Resulting aqueous sodium compounds are concentrated by a multiple effect evaporator to provide liquor to digest wood chips. Whereby depolymerized lignins, substantially free from sodium compounds, are separated from a black liquor. Accordingly this invention modifies black liquor without employing a lime kiln and a recovery boiler, producing a molten smelt.
    • 包含在黑液中的解聚木质素转移到有机溶剂中,可溶于有机物质,并且不溶于包含在黑液中的含水钠化合物。 在将含水的钠化合物与有机溶剂分离后,用含有解聚的木质素饱和,从有机溶剂中除去解聚的木质素,得到解聚的木质素和适于回收的分离的有机溶剂。 所得的含水钠化合物通过多效蒸发器浓缩以提供消化木屑的液体。 由此,基本上不含钠化合物的解聚木质素与黑液分离。 因此,本发明在不使用石灰窑和回收锅炉的情况下改性黑液,产生熔融熔融。
    • 4. 发明申请
    • Cellulose production from lignocellulosic biomass
    • 来自木质纤维素生物质的纤维素生产
    • US20020148575A1
    • 2002-10-17
    • US10081930
    • 2002-02-20
    • Richard C. Wingerson
    • D21C011/00D21C009/02
    • D21C3/02D21C1/02D21C3/026D21C3/028D21C3/18D21C3/26Y02P70/24
    • A multi-function process is described for the separation of cellulose fibers from the other constituents of lignocellulosic biomass such as found in trees, grasses, agricultural waste, and waste paper with application in the preparation of feedstocks for use in the manufacture of paper, plastics, ethanol, and other chemicals. This process minimizes waste disposal problems since it uses only steam, water, and oxygen at elevated temperature in the range of 180null C. to 240null C. for 1 to 10 minutes plus a small amount of chemical reagents to maintain pH in the range 8 to 13. An energy recuperation function is important to the economic viability of the process.
    • 描述了一种多功能过程,用于将纤维素纤维与木质纤维素生物质的其他成分分离,例如在树木,草,农业废弃物和废纸中发现,用于制备用于制造纸,塑料的原料 ,乙醇等化学药品。 该方法使废物处理问题最小化,因为它仅在180℃至240℃的高温下仅使用蒸汽,水和氧,持续1至10分钟加上少量化学试剂以将pH保持在范围内 能量回收功能对于该过程的经济可行性很重要。
    • 6. 发明申请
    • Process for producing cellulose, and by-product
    • 生产纤维素和副产物的方法
    • US20020069983A1
    • 2002-06-13
    • US09969616
    • 2001-10-03
    • Chempolis Oy
    • Pasi P. RousuPaivi P. RousuEsa J. Rousu
    • D21C011/00D21C011/12D21C003/02
    • D21C11/0028C05D1/00D21C9/1063D21C11/0007
    • The invention relates to a process for producing cellulose and a fertilizer by-product by using a closed cycle of cooking chemicals and process waters. In the process of the invention, the pulp is bleached by at least partly using potassium hydroxide as a bleaching chemical. Thus, a bleach concentrate rich in potassium is obtained from the bleach filtrate, which bleach concentrate is combined with ashes obtained from the burning of lignin and other organic matter recovered from pulp production as a by-product, in order to be used as a potash fertilizer. The bleach concentrate can also be used as a potash fertilizer as such. The invention also relates to a potash fertilizer obtained this way.
    • 本发明涉及通过使用烹饪化学品和处理水的封闭循环来生产纤维素和副产物的方法。 在本发明的方法中,纸浆通过至少部分地使用氢氧化钾作为漂白化学品漂白。 因此,从漂白滤液中获得富含钾的漂白浓缩物,漂白浓缩物与作为副产物从纸浆生产回收的木质素和其它有机物质的燃烧中获得的灰分相结合,以便用作钾盐 肥料。 漂白浓缩物也可以作为钾肥使用。 本发明还涉及以这种方式获得的钾肥。
    • 7. 发明申请
    • Pulping process without a recovery furnace
    • 没有回收炉的制浆工艺
    • US20020059994A1
    • 2002-05-23
    • US09974483
    • 2001-10-10
    • Kenneth R. Kurple
    • D21C011/00D21C001/04
    • D21C11/0042D21C3/02D21C11/0007D21C11/0085
    • A novel process has been discovered whereby acid is added to the lignocellulosic material (black liquor containing lignin). The acid renders the lignin insoluble thus enabling it to be separated from the lignocellulosic material. This allows the chemical value of various components to be reclaimed. This process enables important environmental and economic benefits to be achieved. The invention obviates the need for a recovery boiler which burns the sugars and the lignin. Additionally, sodium salts are precipitated out of the process. Sodium carbonate from outside sources is used in the novel process. The supply of energy to the separation process is from a source other than the recovery furnace.
    • 已经发现了一种新的方法,其中将酸加入到木质纤维素材料(含有木质素的黑液)中。 酸使木质素不溶,从而使其能够与木质纤维素材料分离。 这允许回收各种组分的化学价值。 这个过程可以实现重要的环境和经济效益。 本发明消除了对烧焦糖和木质素的回收锅炉的需要。 此外,钠盐沉淀出该过程。 来自外部来源的碳酸钠用于新工艺。 向分离过程供应的能量来自回收炉以外的来源。
    • 9. 发明申请
    • Method for reducing and /or avoiding the build-up of wood components
    • 减少和/或避免木材部件积聚的方法
    • US20040011482A1
    • 2004-01-22
    • US10148210
    • 2002-10-04
    • Ingo Von MedveyThomas RajcsanyiAndreas OpalkaJoachim Werres
    • D21B001/16D21C007/14D21C011/00D21C011/06
    • D21B1/12D21C3/226
    • The invention relates to a method for avoiding and/or reducing the deposition of volatile and non-volatile wood components in gas-bearing systems, whereby at least one of the volatile wood components, at least partly, condenses in the gas-bearing system and the gas contains at least one compound with a similar condensation profile to the volatile wood component and which at least reduces the deposition of volatile wood components or the reaction products thereof. The invention further relates to a method for reducing and/or avoiding the deposition of wood components on machines and/or equipment components for the production of wood fiber materials from wood chippings, in which the shredding of the wood is achieved in the presence of a compound which forms a film on the surfaces of the above machines and/or equipment components and at least reduces the deposition of volatile wood components and/or the reaction products thereof.
    • 本发明涉及一种用于避免和/或减少气体承载系统中的挥发性和非挥发性木质组分的沉积的方法,其中至少一种挥发性木质组分至少部分地在气体承载系统中冷凝, 该气体含有至少一种具有与挥发性木材组分相似的冷凝轮廓的化合物,并且至少减少挥发性木材组分或其反应产物的沉积。 本发明还涉及一种用于减少和/或避免木材部件沉积在机器和/或设备部件上的方法,用于从木屑生产木纤维材料,其中在存在木材的情况下实现木材的切碎 在上述机器和/或设备部件的表面上形成膜的化合物,并且至少减少挥发性木材组分和/或其反应产物的沉积。