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    • 1. 发明申请
    • Solid electrolyte and electrochemical system using the solid electrolyte
    • 固体电解质和电化学系统使用固体电解质
    • US20040188248A1
    • 2004-09-30
    • US10765862
    • 2004-01-29
    • Haruo Sawa
    • C25C007/04
    • H01M6/181B01D53/32C02F1/4618C02F2201/46195C25B13/08H01M8/04197H01M8/04291H01M8/1023H01M8/1081H01M2300/0082H01M2300/0091Y02P70/56
    • It is an object to provide a solid electrolyte and an electrochemical system using the solid electrolyte which has a little expansion (swelling) and whose strength does not decrease in case of positioning the solid electrolyte including a complex compound composed of an inorganic compound, polyvinyl alcohol, and water, in a wet condition. It is possible to use the solid electrolyte in a device such as a fuel cell or an electrolytic device used with the wet condition. The solid electrolyte has a little size variation even if humidity varies and has a low methanol permeability. The solid electrolyte is produced by replacing a part or all of hydroxyl groups of polyvinyl alcohol domain to groups each of which has a water absorption less than that of said hydroxyl group, in the solid electrolyte including a complex compound which is composed of polyvinyl alcohol, water, and at least one inorganic compound selected from silicic acid compound, tungstic acid compound, molybdic acid compound, stannic acid compound, and zirconic acid compound.
    • 本发明的目的是提供一种使用固体电解质的固体电解质和电化学体系,所述固体电解质具有很小的膨胀(膨胀),并且在将含有由无机化合物构成的络合物的固体电解质,聚乙烯醇 ,和水,在潮湿的条件。 可以在诸如燃料电池或与潮湿条件一起使用的电解装置的装置中使用固体电解质。 固体电解质即使湿度变化且甲醇渗透性低,也具有小的变化。 固体电解质是通过将聚乙烯醇结构域的一部分或全部的羟基替换为比所述羟基的吸水率小的基团而制造的固体电解质,其包含由聚乙烯醇, 水和至少一种选自硅酸化合物,钨酸化合物,钼酸化合物,锡酸化合物和锆酸化合物的无机化合物。
    • 6. 发明申请
    • Electrochemical cell comprising lamination of electrode and paper separator members
    • 电化学电池,其包括电极和纸分离器构件的层叠
    • US20030062257A1
    • 2003-04-03
    • US09970437
    • 2001-10-03
    • Antoni S. Gozdz
    • C25C007/00C25B009/00C25C007/04C25D017/00C25B013/00
    • H01G9/155H01G9/02H01G11/52H01M2/145H01M2/1626H01M2/1673H01M4/622H01M10/04Y02E60/13
    • In double-layer capacitor and rechargeable battery electrochemical cell systems comprising opposed electrode members of polymeric matrix composition having an interposed electrically insulative, ion-conductive separator member incorporating electrolyte solution, thermal lamination of the electrode members to an interposed paper separator member to form a unitary cell structure is enabled by initially providing in the region of the separator/electrode interface, either incorporated into the electrode composition or situated in the separator member, a sufficient amount of a supplemental plasticizer compatible with the electrode matrix polymer to render at least the surface portion of the electrode composition capable of adhesive flow under the selected conditions of laminating heat and pressure. After lamination, a sufficient amount of the supplemental plasticizer is removed, by evaporation or selective extraction, to ensure against delamination of the cell structure in the event of exposure to vagrant heating.
    • 在双层电容器和可再充电电池电化学电池系统中,包括具有插入的电绝缘的离子导电隔离器构件的聚合物基质组合物的相对电极构件,其包含电解质溶液,电极构件与插入的纸分离器构件的热层压形成一体 通过在分离器/电极界面的区域中首先提供或者并入电极组合物中或位于分离器构件中的单元结构能够实现足够量的与电极基质聚合物相容的补充增塑剂,以使至少表面部分 的电极组合物在选择的层压热和压力条件下能够粘合流动。 层压后,通过蒸发或选择性萃取,除去充足量的补充增塑剂,以确保在暴露于流动性加热的情况下不会分解细胞结构。