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    • 4. 发明授权
    • Method for recovering the metal values from materials containing tin
and/or zinc
    • 从含锡和/或锌的材料中回收金属值的方法
    • US4571260A
    • 1986-02-18
    • US696095
    • 1985-01-29
    • Leif JohanssonStig A. PeterssonBengt O. Rudling
    • Leif JohanssonStig A. PeterssonBengt O. Rudling
    • C22B13/02C22B19/00C22B19/04C22B25/02C22B13/00C22B25/00
    • C22B25/02C22B13/02C22B19/00C22B19/04
    • The invention relates to a method for recovering the metal values from materials containing at least one of zinc and tin, by smelting the starting materials under oxidizing conditions and reducing the resultant molten bath. The starting materials are first smelted in a furnace while adding flux, to form a slag which is sluggish at selected reduction temperatures and has a low lead contents. The reduction process is carried out while charging solid carbonaceous reduction agent and optionally also sulphur- and/or chlorine-donor material to the slag. The reduction agent and optionally supplied donor material is brought into suspension with the slag, and this suspension is sustained at least during the latter phase of the reduction period, at which the lead content of the slag has fallen to beneath about 1-2%, during which phase the reduction of zinc and tin takes place. Zinc is recovered from the furnace in the form of zinc vapor, while tin optionally is removed as volatile tin sulphide, chloride or oxide, and lead and any other metal values present in the starting materials are recovered as a molten lead phase.
    • 本发明涉及一种从含有锌和锡中至少一种的材料中回收金属值的方法,通过在氧化条件下熔炼原料并还原所得的熔融液。 原料首先在炉中熔炼,同时加入助熔剂,形成在选定的还原温度下缓慢并且铅含量低的炉渣。 还原过程在将固体碳质还原剂和任选的硫和/或氯给体材料装入炉渣的同时进行。 还原剂和任选供应的供体材料与炉渣悬浮,并且该悬浮液至少在还原期的后期维持,渣的铅含量降至约1-2%以下, 在此期间锌和锡的还原发生。 锌以锌蒸气的形式从炉中回收,而锡任选地作为挥发性硫化锡,氯化物或氧化物除去,并且铅和原料中存在的任何其它金属值作为熔融铅相回收。
    • 6. 发明授权
    • Process for the fuming treatment of metallurgical slag
    • 冶金炉渣发烟处理工艺
    • US4252563A
    • 1981-02-24
    • US714506
    • 1976-08-16
    • Eric O. A. Sundstrom
    • Eric O. A. Sundstrom
    • C22B7/04C22B13/00C22B17/00C22B19/10C22B25/00
    • C22B7/04Y02P10/212
    • A continuous process for the fuming treatment of metallurgical slag, e.g. lead and copper smelting furnace slag. Passing the slag continuously through consecutive slag treatment zones of a fuming furnace, subjecting it in a first one of said zones to heating to fume off comparatively volatile, preferably sulphide-bound constituents thereof, subjecting it in a second one of said zones to reduction to reduce preferably oxide-bound constituents and fuming off said last mentioned constituents in an elementary form and adjusting the temperature of the slag in said first zone such that the reduction treatment in said second zone is accomplishable substantially without further heating the slag.
    • 用于冶金炉渣的发烟处理的连续方法,例如, 铅和铜冶炼炉渣。 使炉渣连续通过发烟炉的连续炉渣处理区,使其在第一个所述区域中进行加热以将其相对挥发的,优选硫化物结合的成分进行加热,使其在第二个所述区域中进行还原 优选地减少氧化物结合的组分并以基本形式发出所述最后提到的组分,并调节所述第一区中的炉渣的温度,使得所述第二区域中的还原处理基本上可实现,而不进一步加热炉渣。
    • 7. 发明授权
    • Metal crystals and process
    • 金属晶体和工艺
    • US4192695A
    • 1980-03-11
    • US898799
    • 1978-04-24
    • Shalom Mahalla
    • Shalom Mahalla
    • C30B7/00C30B7/12C30B7/14C22B9/08C22B13/00C22B25/00C22B30/00
    • C30B7/14C30B29/02C30B7/00C30B7/12
    • A new article of manufacture consisting of a metal crystal which is macrocrystalline, unicrystalline and columnar. The crystal consists of a single prime particle bounded by at least two sets of distinguishable (hkl) planes specific to the metal which are determined by the internal crystal structure. The crystal orientation is such that another (hkl) plane specific to the metal is perpendicular to the long axis of the crystal. The sets of planes define a plurality of parallel, non-coplanar macroscopic facets, which microscopically are crystallographic step-growth surfaces.A process for producing a product metal from a solution of metal values is disclosed. Crystals of the product metal in a pregnant solution of the metal values are supplied with electrons to preferentially reduce product metal ions in the locus of the crystals to product metal. Positive ions are supplied in a region of the crystallization zone remote from the locus of reduction of the metal ions to maintain ionic charge neutrality in the pregnant solution. A concentration step-function of the metal values is established in the locus of the crystals, the gradient thereof being at least sufficient to cause the product metal to attach to the crystal lattice of the crystals by atomic bonding.
    • 一种由金属晶体组成的新型制品,其为微晶,单晶和柱状。 该晶体由由至少两组由金属特异的可区分(hkl)平面界定的单质量粒子组成,这些平面由内部晶体结构确定。 晶体取向使得特定于金属的另一(hkl)平面垂直于晶体的长轴。 这些平面组限定了多个平行的,非共面的宏观面,其在显微镜上是晶体的阶梯生长表面。 公开了一种由金属溶液制造产品金属的方法。 在金属值的怀孕溶液中的产物金属的晶体被提供有电子以优先地将晶体中的产物金属离子还原成产物金属。 在远离金属离子还原轨迹的结晶区域中提供正离子,以保持怀孕溶液中的离子电荷中性。 在晶体的轨迹上建立金属值的浓度梯度函数,其梯度至少足以使产物金属通过原子键合附着到晶体的晶格上。