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1. 发明申请

US20220204879A1 REDUCING CARBON EMISSIONS ASSOCIATED WITH WASTE GAS 有权
公开(公告)号：US20220204879A1
公开(公告)日：2022-06-30
申请号：US17133831
申请日：2020-12-24
申请人： ExxonMobile Research and Engineering Company
发明人： Kevin B. Daly , Mohsen N. Harandi , Everett J. O'Neal , P. Scott Northrop , Narasimhan Sundaram , David L. Stern
IPC分类号： C10J3/46 , C10L3/10 , C10G49/18 , C10J3/48
摘要： Methods of the present disclosure may comprise: introducing a first effluent and a second effluent in a gasifier of a partial oxidation unit to produce a waste gas, wherein the first effluent comprises one or more hydrocarbon containing feeds and the second effluent comprises air, enriched air with oxygen or oxygen; selectively removing hydrogen sulfide (H2S) from the waste gas; combining the waste gas and steam in a water-gas shift unit to produce a shift gas comprising hydrogen and carbon dioxide; separating the carbon dioxide from the shift gas in a carbon capture unit to produce a carbon dioxide-enriched effluent and an effluent comprising a hydrogen- and nitrogen-enriched mixture; and recovering the carbon dioxide from the carbon dioxide-enriched effluent.

2. 发明申请

US20170342332A1 PRODUCTION OF UPGRADED PETROLEUM BY SUPERCRITICAL WATER 审中-公开
公开(公告)号：US20170342332A1
公开(公告)日：2017-11-30
申请号：US15678631
申请日：2017-08-16
申请人： Saudi Arabian Oil Company
发明人： Ki-Hyouk CHOI , Joo-Hyeong LEE , Mohammad S. GARHOUSH , Ali H. ALSHAREEF
IPC分类号： C10G55/00 , B01D11/04 , C10G47/02 , C10G47/32 , C10G49/18 , B01J3/00
CPC分类号： C10G55/00 , B01D11/0407 , B01J3/008 , C10G47/02 , C10G47/32 , C10G49/18 , C10G2300/202 , C10G2300/206 , C10G2300/308 , C10G2300/4006
摘要： A method for upgrading a petroleum feedstock using a supercritical water petroleum upgrading system includes introducing the petroleum feedstock, water and an auxiliary feedstock. The method includes operating the system to combine the petroleum feedstock and the water to form a mixed petroleum feedstock and introducing separately and simultaneously into a lower portion of an upflowing supercritical water reactor. The auxiliary feedstock is introduced such that a portion of a fluid contained within the upflowing reactor located proximate to the bottom does not lack fluid momentum. An embodiment of the method includes operating the supercritical water petroleum upgrading system such that the upflowing reactor product fluid is introduced into an upper portion of a downflowing supercritical water reactor. The supercritical water petroleum upgrading system includes the upflowing supercritical water reactor and optionally a downflowing supercritical water reactor.

3. 发明授权

US09771527B2 Production of upgraded petroleum by supercritical water 有权
公开(公告)号：US09771527B2
公开(公告)日：2017-09-26
申请号：US14132226
申请日：2013-12-18
申请人： SAUDI ARABIAN OIL COMPANY
发明人： Ki-Hyouk Choi , Joo-Hyeong Lee , Mohammad S. Garhoush , Ali H. Alshareef
IPC分类号： C10G45/08 , C10G45/26 , C10G49/04 , C10G55/00 , B01D11/04 , B01J3/00 , C10G47/02 , C10G47/32 , C10G49/18
CPC分类号： C10G55/00 , B01D11/0407 , B01J3/008 , C10G47/02 , C10G47/32 , C10G49/18 , C10G2300/202 , C10G2300/206 , C10G2300/308 , C10G2300/4006
摘要： A method for upgrading a petroleum feedstock using a supercritical water petroleum upgrading system includes introducing the petroleum feedstock, water and an auxiliary feedstock. The method includes operating the system to combine the petroleum feedstock and the water to form a mixed petroleum feedstock and introducing separately and simultaneously into a lower portion of an upflowing supercritical water reactor. The auxiliary feedstock is introduced such that a portion of a fluid contained within the upflowing reactor located proximate to the bottom does not lack fluid momentum. An embodiment of the method includes operating the supercritical water petroleum upgrading system such that the upflowing reactor product fluid is introduced into an upper portion of a downflowing supercritical water reactor. The supercritical water petroleum upgrading system includes the upflowing supercritical water reactor and optionally a downflowing supercritical water reactor.

4. 发明授权

US5688741A Process and catalyst for upgrading heavy hydrocarbon 失效
公开(公告)号：US5688741A
公开(公告)日：1997-11-18
申请号：US406073
申请日：1995-03-17
申请人： Jose Carrazza , Pedro Pereira , Nelson Martinez
发明人： Jose Carrazza , Pedro Pereira , Nelson Martinez
IPC分类号： B01J23/78 , C10G1/00 , C10G1/06 , C10G1/08 , C10G11/00 , C10G11/02 , C10G11/20 , C10G47/14 , C10G47/24 , C10G47/32 , C10G49/06 , C10G49/10 , C10G49/18 , C10G13/02 , B01I23/78
CPC分类号： C10G47/32 , C10G11/02
摘要： A catalyst for use in a process for steam conversion of a heavy hydrocarbon feedstock includes the steps of: providing a heavy hydrocarbon feedstock; providing a catalytically active phase comprising a first metal and a second metal wherein said first metal is a non-noble Group VIII metal and said second metal is an alkali metal; and contacting said feedstock with steam at a pressure of less than or equal to about 300 psig in the presence of said catalytically active phase so as to provide a hydrocarbon product having a reduced boiling point. The catalyst may be supported on a support material or mixed directly with the feedstock and comprises a first metal selected from the group consisting of non-noble Group VIII metals and mixtures thereof and a second metal comprising an alkali metal wherein said catalyst is active to convert said heavy hydrocarbon at a pressure of less than or equal to about 300 psig.

5. 发明授权

US5484755A Process for preparing a dispersed Group VIB metal sulfide catalyst 失效
标题翻译：制备分散的VIB族金属硫化物催化剂的方法
公开(公告)号：US5484755A
公开(公告)日：1996-01-16
申请号：US294182
申请日：1994-08-22
申请人： Jaime Lopez
发明人： Jaime Lopez
IPC分类号： B01J27/047 , B01J27/049 , B01J37/20 , C10G47/06 , C10G47/26 , C10G49/12 , C10G49/18 , B01J27/051
CPC分类号： C10G49/12 , B01J27/047 , B01J27/049 , B01J37/20 , C10G47/06 , C10G47/26 , C10G49/18
摘要： High activity slurry catalysts for hydroprocessing heavy hydrocarbon oils are produced from Group VIB metal compounds by sulfiding an aqueous mixture of the metal compound with from greater than about 8 to about 14 SCF of hydrogen sulfide per pound of Group VIB metal.
摘要翻译：通过将金属化合物的水性混合物与每磅VIB族金属大于约8至约14SCF的硫化氢硫化，由VIB族金属化合物生产用于加氢处理重质烃油的高活性浆料催化剂。

6. 发明授权

US4970190A Heavy oil hydroprocessing with group VI metal slurry catalyst 失效
标题翻译：重油加氢处理与VI族金属浆料催化剂
公开(公告)号：US4970190A
公开(公告)日：1990-11-13
申请号：US388790
申请日：1989-09-05
申请人： Jaime Lopez , Eugene A. Pasek
发明人： Jaime Lopez , Eugene A. Pasek
IPC分类号： C10G49/18
CPC分类号： C10G49/18
摘要： A process for the preparation of a dispersed Group VIB metal sulfide hydrocarbon oil hydroprocessing catalyst comprising reacting aqueous ammonia and a Group VIB metal compound, such as molybdenum oxide or tungsten oxide, to form water soluble compounds such as aqueous ammonium molybdates or tungstates. The aqueous ammonium molybdates or tungstates are sulfided at a relatively low temperature with hydrogen sulfide without feed oil. The slurry stream is then passed through a separator and ammonia is flashed and separated from the system, leaving a separator residue slurry. The separator residue slurry is then mixed with feed oil, hydrogen and hydrogen sulfide and sulfided at a relatively high temperature to produce a dispersed molybdenum sulfide or tungsten sulfide catalyst of high hydroprocessing activity. The catalyst slurry and feed oil can then be passed to a hydroprocessing reactor.
摘要翻译：一种用于制备分散的VIB族金属硫化物烃油加氢催化剂的方法，其包括使氨水和VIB族金属化合物如氧化钼或氧化钨反应以形成水溶性化合物如钼酸铵或钨酸铵。钼酸铵或钨酸铵在相对低的温度下用不含原料油的硫化氢硫化。然后将浆料流通过分离器，将氨闪蒸并与系统分离，留下分离器残渣浆液。然后将分离器残渣浆料与进料油，氢气和硫化氢混合并在相当高的温度下硫化以产生具有高加氢处理活性的分散的硫化钼或硫化钨催化剂。催化剂浆料和原料油然后可以通入加氢处理反应器。

7. 发明授权

US4857496A Heavy oil hydroprocessing with Group VI metal slurry catalyst 失效
标题翻译：重油加氢处理与VI族金属浆料催化剂
公开(公告)号：US4857496A
公开(公告)日：1989-08-15
申请号：US941456
申请日：1986-12-15
申请人： Jaime Lopez , Eugene A. Pasek
发明人： Jaime Lopez , Eugene A. Pasek
IPC分类号： C10G49/18
CPC分类号： C10G49/18
摘要： A process for the preparation of a dispersed Group VIB metal sulfide hydrocarbon oil hydroprocessing catalyst comprising reacting aqueous ammonia and a Group VIB metal compound, such as molybdenum oxide or tungsten oxide, to form water soluble compounds such as aqueous ammonium molybdates or tungstates. The aqueous ammonium molybdates or tungstates are sulfided at a relatively low temperature with hydrogen sulfide without feed oil. The slurry stream is then passed through a separator and ammonia is flashed and separated from the system, leaving a separator residue slurry. The separator residue slurry is then mixed with feed oil, hydrogen and hydrogen sulfide and sulfided at a relatively high temperature to produce a dispersed molybdenum sulfide or tungsten sulfide catalyst of high hydroprocessing activity. The catalyst slurry and feed oil can then be passed to a hydroprocessing reactor.
摘要翻译：一种用于制备分散的VIB族金属硫化物烃油加氢催化剂的方法，其包括使氨水和VIB族金属化合物如氧化钼或氧化钨反应以形成水溶性化合物如钼酸铵或钨酸铵。钼酸铵或钨酸铵在相对低的温度下用不含原料油的硫化氢硫化。然后将浆料流通过分离器，将氨闪蒸并与系统分离，留下分离器残渣浆液。然后将分离器残渣浆料与进料油，氢气和硫化氢混合并在相当高的温度下硫化以产生具有高加氢处理活性的分散的硫化钼或硫化钨催化剂。催化剂浆料和原料油然后可以通入加氢处理反应器。

8. 发明授权

US11345861B2 Production of linear olefins from heavy oil 有权
公开(公告)号：US11345861B2
公开(公告)日：2022-05-31
申请号：US16908511
申请日：2020-06-22
申请人： Saudi Arabian Oil Company
发明人： Ki-Hyouk Choi , Abdullah Alabdulhadi , Joo-Hyeong Lee , Ali Alsomali
IPC分类号： C10G49/18 , C10G1/02 , B01J3/00 , C10G1/08
摘要： A process for producing olefins comprising the steps of separating the liquid oil in the fractionator to produce a light oil product; separating the light oil product in the extractor to produce a paraffin fraction stream; increasing a pressure of the paraffin fraction stream in a paraffin pump to produce a pressurized paraffin stream; mixing the pressurized paraffin stream with a pressurized water feed in the water mixer to produce a paraffin-containing water stream; heating the paraffin-containing water stream in the water heater to produce a hot paraffin-water stream, wherein a temperature of the hot paraffin-water stream is greater than 450 deg C., wherein the short chain paraffins are operable to crack at the temperature of the hot paraffin-water stream; mixing the hot paraffin-water stream and the hot feedstock in the feed mixer to produce a mixed feed stream; and introducing the mixed feed stream to the supercritical unit.

9. 发明授权

US10920158B2 Supercritical water process to produce bottom free hydrocarbons 有权
公开(公告)号：US10920158B2
公开(公告)日：2021-02-16
申请号：US16442189
申请日：2019-06-14
申请人： SAUDI ARABIAN OIL COMPANY
发明人： Ki-Hyouk Choi , Bader Alotaibi , Mohammad Garhoush
IPC分类号： C10G31/08 , C10G49/18 , C10G61/02 , B01J3/00
摘要： A process to produce a light hydrocarbon fraction from a heavy residue feed, the process comprising the steps of operating the first supercritical reactor such that the heavy residue feed and the supercritical water stream undergo conversion reactions to produce a reactor effluent, introducing the reactor effluent to a top inlet in a top portion of a second supercritical reactor, introducing a supercritical water stream to a bottom inlet in a bottom portion of the second supercritical reactor, operating the second supercritical reactor such that the bottom of the barrel fraction is configured to settle in the bottom portion of the second supercritical reactor, withdrawing an upgraded product stream from a top outlet in the top portion of the second supercritical reactor, and withdrawing a heavy product stream from a bottom outlet in the bottom portion of the second supercritical reactor.

10. 发明申请

US20200224105A1 SUPERCRITICAL REACTOR SYSTEMS AND PROCESSES FOR PETROLEUM UPGRADING 审中-公开
公开(公告)号：US20200224105A1
公开(公告)日：2020-07-16
申请号：US16836273
申请日：2020-03-31
申请人： Saudi Arabian Oil Company
发明人： Ki-Hyouk Choi , Abdullah T. Alabdulhadi , Mohammad A. Al-Abdullah
IPC分类号： C10G31/08 , C10G65/02 , C10G65/10 , C10G65/12 , C10G49/18 , B01J3/00 , C10G75/00 , B01J3/02 , C10G11/10 , C10G51/02 , C10G75/04
摘要： Supercritical upgrading reactors and reactor systems are provided for upgrading a petroleum-based composition using one or more purging fluid inlets to prevent plugging of the catalyst layer in the reactor. Processes for upgrading petroleum-based compositions by utilizing a reactor having at least one purging fluid inlet are also provided.

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