会员体验
专利管家(专利管理)
工作空间(专利管理)
风险监控(情报监控)
数据分析(专利分析)
侵权分析(诉讼无效)
联系我们
交流群
官方交流:
QQ群: 891211   
微信请扫码    >>>
现在联系顾问~
热词
    • 6. 发明授权
    • Process for the preparation of brominated, alkoxy-substituted metal
phthalocyanines
    • 制备溴化烷氧基取代的金属酞菁的方法
    • US5594128A
    • 1997-01-14
    • US530973
    • 1995-09-20
    • Heinz Wolleb
    • Heinz Wolleb
    • C07D487/22C09B47/10C09B47/18C09B47/04
    • C07D487/22C09B47/10
    • A process for the preparation of a mixture of positionally isomeric brominated tetraalkoxymetal phthalocyanines of the formula I, ##STR1## where Me is Cu(II), Pd(II), Zn(II), Sn(II), Ni(II), Co(II), Pb(II), Mn(O) or V(O), x is a number from 1 to 5, and R.sub.1 to R.sub.4, independently of one another, are linear or branched C.sub.1 -C.sub.16 alkyl, C.sub.3 -C.sub.16 alkenyl or C.sub.3 -C.sub.16 alkynyl radicals which are unsubstituted or substituted by C.sub.1 -C.sub.12 alkoxy, CN, NO.sub.2, halogen, OH, phenyl, cyanophenyl, nitrophenyl, halophenyl, hydroxyphenyl or (C.sub.1 -C.sub.12 alkoxy)phenyl,by reacting a tetraalkoxy metal phthalocyanine of the formula II with bromine, ##STR2## which comprises carrying out the reaction in a halogenated, aromatic solvent, essentially water-immiscible in the presence of a second, aqueous phase.Substituted phthalocyanines are an important class of dyes for optical information recording, since they have high NIR absorption in the range from 700 nm to 900 nm in the case of appropriate peripheral substitution, depending on the central metal atom.
    • 制备式I的其中Me是Cu(II),Pd(II),Zn(II),Sn(II),Ni(I)的位置异构的溴化四烷氧基金属酞菁的混合物的方法, II),Co(II),Pb(II),Mn(O)或V(O),x为1至5的数,R1至R4彼此独立地为直链或支链的C 1 -C 16烷基, CN,NO 2,卤素,OH,苯基,氰基苯基,硝基苯基,卤代苯基,羟基苯基或(C 1 -C 12烷氧基)苯基未被取代或被C 1 -C 12烷氧基,CN,NO 2,卤素,OH,苯基,羟基苯基或(C 1 -C 12烷氧基)苯基取代的C 3 -C 16烯基或C 3 -C 16炔基, 式II与溴,其包括在卤化的芳族溶剂中进行反应,其在第二水相存在下基本上与水不混溶。 取代酞菁是用于光学信息记录的重要类型的染料,因为根据中心金属原子,在适当的外部取代的情况下,它们在700nm至900nm的范围内具有高的近红外吸收。