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1. 发明授权

US06833409B2 Impact modifier, process for producing the same, and thermoplastic resin composition containing the same 有权
标题翻译：抗冲改性剂，其制造方法以及含有该抗冲改性剂的热塑性树脂组合物
公开(公告)号：US06833409B2
公开(公告)日：2004-12-21
申请号：US10257405
申请日：2002-10-21
申请人： Keiji Nakamura , Masakazu Ito
发明人： Keiji Nakamura , Masakazu Ito
IPC分类号： C08L5104
CPC分类号： C08L51/003 , C08F257/00 , C08F265/04 , C08F273/00 , C08L51/04 , C08L2666/02
摘要： An impact strength modifier comprises an acrylic rubber graft copolymer (I) obtained by graft-polymerizing a polyalkyl (meth)acrylate composite rubber (A) with a vinyl monomer (B), and a compound (II) which has a sulfonic acid group or a sulfuric acid group and also has two or more benzene ring skeletons, or a salt thereof. The polyalkyl (meth)acrylate composite rubber (A) contains two or more acrylic rubber components each having a different glass transition temperature, and the respective acrylic rubber components have 20% by weight or less of a monomer having two or more unsaturated bonds in a molecule. The compound (II) preferably has two or more benzene ring skeletons, and a particle size distribution of the polyalkyl (meth)acrylate composite rubber (A) is preferably a polydisperse distribution in which two or more peaks exist within a specific range. When using the impact strength modifier of the present invention, the impact resistance, particularly low-temperature impact resistance of the resin can be improved in a small amount and weatherability such as fading resistance or impact resistance of the resulting molded article can be satisfactorily maintained.
摘要翻译：冲击强度改性剂包括通过使（甲基）丙烯酸烷基酯复合橡胶与乙烯基单体（B）接枝聚合得到的丙烯酸橡胶接枝共聚物（I）和具有磺酸基的化合物（II）或硫酸基，也可以具有2个以上的苯环骨架或其盐。聚（甲基）丙烯酸烷基酯复合橡胶（A）含有两种或多种各自具有不同玻璃化转变温度的丙烯酸橡胶组分，各种丙烯酸类橡胶组分在20％（重量）或更少的具有两个或更多个不饱和键的单体中分子。化合物（II）优选具有两个以上的苯环骨架，聚（甲基）丙烯酸聚烷酯复合橡胶（A）的粒径分布优选为在特定范围内存在两个以上峰的多分散分布。当使用本发明的冲击强度调节剂时，可以少量地提高树脂的耐冲击性，特别是低温耐冲击性，并且可以令人满意地保持所得模制品的耐候性，如抗褪色性或耐冲击性。

2. 发明授权

US06663953B2 Fresnel lens base sheet 有权
公开(公告)号：US06663953B2
公开(公告)日：2003-12-16
申请号：US10074223
申请日：2002-02-14
申请人： Shunji Kamiya , Makoto Honda , Keiji Hanamoto
发明人： Shunji Kamiya , Makoto Honda , Keiji Hanamoto
IPC分类号： C08L5104
CPC分类号： G02B3/08 , C08F287/00 , C08L25/14 , C08L51/003 , C08L51/006 , C08L53/02 , G02B1/041 , Y10T428/254 , Y10T428/31935 , C08L33/10 , C08L2666/24 , C08L2666/02 , C08L2666/04
摘要： A Fresnel lens base sheet is provided which is suitable for the formation of a lens layer of an ultraviolet-cured resin and has excellent impact resistance and environmental resistance. The Fresnel lens base sheet comprises a specific rubber-modified styrene resin comprising a rubber-like elastic material as dispersed particles and a copolymer of a styrene monomer with an acrylic (methacrylic) ester monomer as a continuous phase.

3. 发明授权

US06528583B1 Thermoplastic molding composition having improved dimensional stability and low gloss 有权
标题翻译：具有改进的尺寸稳定性和低光泽度的热塑性模塑组合物
公开(公告)号：US06528583B1
公开(公告)日：2003-03-04
申请号：US09538648
申请日：2000-03-30
申请人： Chuan-Ju Chen , Marc E. Gage
发明人： Chuan-Ju Chen , Marc E. Gage
IPC分类号： C08L5104
CPC分类号： C08L51/04 , C08F263/04 , C08F265/04 , C08F279/02 , C08L55/02 , Y10T83/2035 , C08L2666/04 , C08L2666/24
摘要： A thermoplastic molding composition which features improved dimensional stability and low gloss is disclosed. The composition which contains (A) a first grafted rubber having a weight average particle size of 0.05 to 0.30 microns, (B) a second grafted rubber having a weight average particle size of 0.31 to 1.00 microns, (C) vinyl chloride (co) polymer, and, optionally, (D) styrene copolymer, is especially suitable for extruding profiles. In a preferred embodiment, at least one of the grafted rubbers is characterized in that its substrate features a core-shell structure, wherein the core contain at least one crosslinked vinylaromatic polymer, and the shell is elastomeric.
摘要翻译：公开了具有改进的尺寸稳定性和低光泽度的热塑性模塑组合物。该组合物含有（A）重均粒径为0.05〜0.30微米的第一接枝橡胶，（B）重均粒径为0.31〜1.00微米的第二接枝橡胶，（C）氯乙烯（共）聚合物和任选的（D）苯乙烯共聚物，特别适用于挤出型材。在优选的实施方案中，至少一种接枝橡胶的特征在于其基材具有核 - 壳结构，其中芯包含至少一种交联的乙烯基芳族聚合物，并且壳是弹性体。

4. 发明授权

US06476128B1 Low-gloss blends containing poly(meth)acrylate rubber-based graft copolymer and process for making thereof 有权
标题翻译：含有聚（甲基）丙烯酸酯橡胶基接枝共聚物的低光泽共混物及其制备方法
公开(公告)号：US06476128B1
公开(公告)日：2002-11-05
申请号：US09822667
申请日：2001-03-30
申请人： Albin P. Berzinis
发明人： Albin P. Berzinis
IPC分类号： C08L5104
CPC分类号： C08L51/003 , C08F265/04 , C08L27/06 , C08L51/04 , C08L55/02 , C08L2666/24 , C08L2666/04
摘要： A process for controlling the surface gloss of a molded composition of: (a) a polyvinyl chloride resin and (b) a graft copolymer comprising a discontinuous poly(alkyl(meth)acrylate) rubber phase and a rigid thermoplastic phase, wherein at least a portion of rigid thermoplastic phase is chemically grafted to the poly(alkyl(meth)acrylate) rubber phase, by regulating the cross-link density and thus the swell index of the rubber phase in the graft copolymer to at least about 8 to vary the surface gloss after extrusion.
摘要翻译：一种用于控制模塑组合物的表面光泽度的方法：（a）聚氯乙烯树脂和（b）包含不连续的聚（甲基丙烯酸烷基酯）橡胶相和刚性热塑性相的接枝共聚物，其中至少一种将刚性热塑性相的一部分通过将接枝共聚物中的交联密度和橡胶相的溶胀指数调节至至少约8以化学接枝到聚（甲基丙烯酸烷基酯）橡胶相上，以改变表面挤出后的光泽。

5. 发明授权

US06649694B2 Process for producing ethylene-&agr;-olefin interpolymer films 有权
标题翻译：制备乙烯-α-烯烃互聚物膜的方法
公开(公告)号：US06649694B2
公开(公告)日：2003-11-18
申请号：US10027556
申请日：2001-12-21
申请人： Kurt Joseph Jordens , Stephen Wayne Coe , Scott Arnold Hanson , Jeffrey James Vanderbilt , Bradley Scott Westbrook
发明人： Kurt Joseph Jordens , Stephen Wayne Coe , Scott Arnold Hanson , Jeffrey James Vanderbilt , Bradley Scott Westbrook
IPC分类号： C08L5104
CPC分类号： C08J5/18 , C08F255/02 , C08J2323/08 , C08L23/0815 , C08L51/06 , C08L2666/24
摘要： There is disclosed a process for producing films from ethylene-&agr;-olefin interpolymers, which films have, in combination, the properties of improved surface haze, improved stiffness, and improved color. The process involves incorporating from about 0.1 to less than 1% by weight, of a functionalized ethylene homopolymer or functionalized ethylene interpolymer into an ethylene-&agr;-olefin interpolymer-containing composition, and forming a film from the composition.
摘要翻译：公开了一种由乙烯-α-烯烃共聚体制造薄膜的方法，该薄膜具有改进的表面雾度，改善的刚度和改善的颜色的性质。该方法包括将约0.1至小于1重量％的官能化乙烯均聚物或官能化乙烯互聚物掺入含乙烯-α-烯烃共聚体的组合物中，并从该组合物形成膜。

6. 发明授权

US06545090B1 Monovinylidene aromatic polymers with improved properties and a process for their preparation 失效
标题翻译：具有改进性能的单亚乙烯基芳族聚合物及其制备方法
公开(公告)号：US06545090B1
公开(公告)日：2003-04-08
申请号：US09714306
申请日：2000-11-16
申请人： Mehmet Demirors , David Schrader , Jose M. Rego
发明人： Mehmet Demirors , David Schrader , Jose M. Rego
IPC分类号： C08L5104
CPC分类号： C08L51/04 , C08F279/02 , C08L25/06 , C08L2666/24 , C08L2666/02
摘要： The present invention is a rubber modified monovinylidene aromatic polymer comprising: a) a monovinylidene aromatic polymer matrix, b) rubber particles dispersed therein, characterized in that the rubber particles are produced from a diene rubber having I) a high molecular weight component and II) a low molecular weight component; the high molecular weight component having a weight average molecular weight at least two and one half times greater than the weight average molecular weight of the low molecular weight component, wherein both components I and II have a 1,4 cis content of greater than 70 percent and III) the rubber is grafted with monovinylidene aromatic polymer to the extent that there is at least 30 percent monovinylidene aromatic polymer present as grafts on the rubber.
摘要翻译：本发明是橡胶改性单亚乙烯基芳族聚合物，其包含：a）单亚乙烯基芳族聚合物基体，b）分散在其中的橡胶颗粒，其特征在于橡胶颗粒由具有I）高分子量组分和II）低分子量组分; 高分子量组分的重均分子量比低分子量组分的重均分子量至少大2.5倍，其中组分I和II都具有大于70％的1,4-顺式含量和III），橡胶用单亚乙烯基芳族聚合物接枝至至少30％单亚乙烯基芳族聚合物作为橡胶上的接枝物存在的程度。

7. 发明授权

US06486234B1 Impact modifier, process for production, and resin composition containing the same 有权
标题翻译：抗冲改性剂，生产方法和含有它的树脂组合物
公开(公告)号：US06486234B1
公开(公告)日：2002-11-26
申请号：US09720819
申请日：2001-01-12
申请人： Keiji Nakamura , Masakazu Ito , Akira Nakata
发明人： Keiji Nakamura , Masakazu Ito , Akira Nakata
IPC分类号： C08L5104
CPC分类号： C08F265/06 , C08L27/06 , C08L51/00 , C08L51/003 , C08F2/22 , C08L2666/24
摘要： The present invention relates to an impact strength modifier capable of imparting both excellent weathering resistance and impact resistance, and to a resin composition comprising the impact strength modifier and a thermoplastic resin, particularly a rigid vinyl chloride resin. Since this impact strength modifier comprises, as a principal component, an acrylic rubber graft copolymer which is obtained by graft polymerization of a polyalkyl (meth)acrylate (A) rubber containing a plurality of acrylic rubber components composed of a specific monomer as a principal component, and a vinyl monomer (B), it is made possible to improve the impact resistance, particularly impact resistance at low temperatures, of the resin and to satisfactorily maintain the weathering resistance by adding a small amount of the impact strength modifier to the resin. This impact strength modifier is particularly suited for incorporation into a rigid vinyl chloride resin.
摘要翻译：本发明涉及能够赋予耐候性和耐冲击性优异的冲击强度改性剂，以及包含冲击强度改性剂和热塑性树脂，特别是刚性氯乙烯树脂的树脂组合物。由于该冲击强度改性剂包含作为主要成分的丙烯酸橡胶接枝共聚物，该丙烯酸橡胶接枝共聚物是由含有多种以特定单体为主要成分的丙烯酸橡胶组分的聚（甲基）丙烯酸烷基酯（A）和乙烯基单体（B），可以提高树脂的耐冲击性，特别是低温下的耐冲击性，并且通过向树脂中加入少量的冲击强度改性剂令人满意地保持耐候性。该冲击强度调节剂特别适用于掺入刚性氯乙烯树脂中。

8. 发明授权

US06277912B1 Aqueous, chlorinated polyolefin-based resin composition and its manufacture 失效
标题翻译：水性氯化聚烯烃基树脂组合物及其制造
公开(公告)号：US06277912B1
公开(公告)日：2001-08-21
申请号：US09063891
申请日：1998-04-22
申请人： Teruaki Ashihara , Tadanori Funasaka , Shoji Maekawa , Ryozo Orita
发明人： Teruaki Ashihara , Tadanori Funasaka , Shoji Maekawa , Ryozo Orita
IPC分类号： C08L5104
CPC分类号： C08F287/00 , C08F8/20 , C08F255/02 , C08F255/023 , C08L51/06 , C08L2666/14
摘要： An aqueous, chlorinated modified polyolefin-based resin composition and its manufacture, which resin composition provides, as an adhesive, a paint for ink, a coating material, etc., moldings and films consisting mainly of polyolefin-based resins with a coating film excellent at the properties such as adhesiveness, gasohol resistance, moisture resistance, impact resistance, flexibility, etc. and which resin composition is particularly good at environmental conservation, safety, and health and hygiene because the resin composition doesn't contain organic solvents including aromatic solvents such as xylene, toluene, etc.
摘要翻译：一种氯化改性聚烯烃基树脂组合物及其制造方法，该树脂组合物作为粘合剂提供油墨用涂料，涂料等，主要由聚烯烃类树脂组成的成膜和膜，其涂膜具有优异的性能在粘合性，耐汽油性，耐湿性，耐冲击性，柔软性等性质方面，由于树脂组合物不含有芳香族溶剂等有机溶剂，所以树脂组合物在环境保护，安全性，健康卫生上特别优异如二甲苯，甲苯等

9. 发明授权

US06777492B1 Graft copolymer and thermoplastic resin composition containing the same 有权
标题翻译：接枝共聚物和含有它们的热塑性树脂组合物
公开(公告)号：US06777492B1
公开(公告)日：2004-08-17
申请号：US10088904
申请日：2002-07-19
申请人： Yoshihiro Nakai , Hideyuki Fujii , Hisaya Yokohama , Takahiro Ikebe , Nobumitsu Fukuyama , Hideyuki Shigemitsu
发明人： Yoshihiro Nakai , Hideyuki Fujii , Hisaya Yokohama , Takahiro Ikebe , Nobumitsu Fukuyama , Hideyuki Shigemitsu
IPC分类号： C08L5104
CPC分类号： C08L51/04 , C08F265/04 , C08F265/06 , C08F279/02 , C08F2/22 , C08L2666/02
摘要： The graft copolymer (G) of the present invention is a graft copolymer which is prepared by emulsion graft polymerization of a rubber polymer comprising 0-50% by weight of a butadiene unit and 50-100% by weight of a (meth)acrylate unit and at least one monomer selected from aromatic alkenyl compound, methacrylate, acrylate and vinyl cyanide compound, said graft copolymer containing 0.5-2.0% by weight of an emulsifier residue. The thermoplastic resin composition containing the graft copolymer of the present invention causes less gas evolution during the molding, provides a molded article with good gloss of molding, and has excellent weather resistance, impact resistance and fluidity.
摘要翻译：本发明的接枝共聚物（G）是通过橡胶聚合物的乳液接枝聚合制备的接枝共聚物，所述橡胶聚合物包含0-50重量％的丁二烯单元和50-100重量％的（甲基）丙烯酸酯单元和至少一种选自芳族烯基化合物，甲基丙烯酸酯，丙烯酸酯和乙烯基氰化合物的单体，所述接枝共聚物含有0.5-2.0重量％的乳化剂残余物。含有本发明的接枝共聚物的热塑性树脂组合物在成型时导致较少的气体逸出，提供了具有良好的成型光泽度的成型品，并且具有优异的耐候性，耐冲击性和流动性。

10. 发明授权

US06620883B2 Process for the preparation of graft rubber latexes having a reduced residual monomer content 有权
公开(公告)号：US06620883B2
公开(公告)日：2003-09-16
申请号：US09965702
申请日：2001-09-26
申请人： Hans-Erich Gasche , Herbert Eichenauer , Pierre Vanhoorne , Ulrich Jansen , Eckhard Wenz , Stefan Moss
发明人： Hans-Erich Gasche , Herbert Eichenauer , Pierre Vanhoorne , Ulrich Jansen , Eckhard Wenz , Stefan Moss
IPC分类号： C08L5104
CPC分类号： C08L51/04 , C08F279/04 , C08L55/02 , C08L2666/02
摘要： The invention relates to a process for the preparation of graft rubber polymers of the ABS type by emulsion polymerization according to the so-called fed batch process, in which latexes having markedly reduced residual monomer contents are obtained, and to compositions containing the mentioned graft rubber polymers. The polymers so obtained have no negative effects at all on other properties

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