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1. 发明授权

US06288182B1 Supported metallocene catalyst system for olefin polymerization 有权
标题翻译：用于烯烃聚合的负载金属茂催化剂体系
公开(公告)号：US06288182B1
公开(公告)日：2001-09-11
申请号：US09416282
申请日：1999-10-12
申请人： Orass Hamed , Akhlaq Moman , Atieh Abu-Raqabah
发明人： Orass Hamed , Akhlaq Moman , Atieh Abu-Raqabah
IPC分类号： C08F450
CPC分类号： C08F10/00 , C08F4/65912 , C08F4/65925 , C08F110/02 , C08F210/16 , Y10S526/904 , Y10S526/943 , C08F4/65916 , C08F2500/03 , C08F210/14
摘要： A catalyst composition has a catalyst component which includes a metallocene transition metal compound, a magnesium compound, a hydroxyl containing compound, and a polymeric material. The catalyst component may also include asilicon compound and an aluminum compound. The catalyst component is combined with a cocatalyst and used in olefin polymerization.
摘要翻译：催化剂组合物具有包含茂金属过渡金属化合物，镁化合物，含羟基化合物和聚合物材料的催化剂组分。催化剂组分还可以包括硅化合物和铝化合物。催化剂组分与助催化剂组合并用于烯烃聚合。

2. 发明授权

US06608154B2 Process for synthesizing trans polydiene rubber 失效
公开(公告)号：US06608154B2
公开(公告)日：2003-08-19
申请号：US10178493
申请日：2002-06-24
申请人： Adel Farhan Halasa , Wen-Liang Hsu , Laurie Elizabeth Austin , Chad Aaron Jasiunas
发明人： Adel Farhan Halasa , Wen-Liang Hsu , Laurie Elizabeth Austin , Chad Aaron Jasiunas
IPC分类号： C08F450
CPC分类号： C08F136/06 , C08F4/50 , C08F4/48
摘要： The process and catalyst system of this invention can be utilized to synthesize polybutadiene rubber having a high trans content and a low melting point by solution polymerization. The trans-polybutadiene rubber made by the process of this invention can be utilized in tire tread rubbers that exhibit outstanding wear characteristics. More importantly, the trans-polybutadiene rubber of this invention can be easily processed because of its low level of crystallinity. In fact, the trans-polybutadiene made by the process of this invention does not need to be heated in a “hot-house” before being used in making rubber compounds. The process and catalyst system of this invention can also be used in the synthesis of trans-styrene-butadiene rubber (SBR). This invention more specifically reveals a process for synthesizing trans-polybutadiene rubber which comprises polymerizing 1,3-butadiene in an organic solvent in the presence of a catalyst system which comprises (a) an organolithium compound, (b) a barium compound selected from the group consisting of (i) barium salts of cyclic alcohols, such as barium mentholate, and (ii) barium thymol, and (c) an organoaluminum compound.

3. 发明授权

US06288180B1 Process for the polymerization of &agr;-olefins, a catalyst used in the polymerization and its preparation 有权
公开(公告)号：US06288180B1
公开(公告)日：2001-09-11
申请号：US09147889
申请日：1999-03-19
申请人： Thomas Garoff , Timo Leinonen , Sirpa Ala-Huikku
发明人： Thomas Garoff , Timo Leinonen , Sirpa Ala-Huikku
IPC分类号： C08F450
CPC分类号： C08F10/00 , C08F4/6543 , C08F4/651
摘要： In the polymerization of C3-C12-&agr;-olefins, the activity of the catalyst and the isotacticity and molecular weight of the polymer product can be adjusted and improved in a controlled manner by a new process wherein A) a catalyst system is prepared by bringing a support which comprises magnesium chloride, a derivative thereof or a reagent forming it into contact with at least titanium tetrachloride or a reagent forming it, in order to produce a titanated support; by bringing the titanated support into contact with at least a group 1, 2 or 13 metal compound which contains a C1-C10-alkyl and activates titanium tetrachloride to a catalytically active titanium group, in order to produce an activated support; and by bringing a substance selected from among the said support, titanated support and activated support into contact with at least one donor or a reagent forming it, in order to produce a catalyst system B) polymerization is carried out using the catalyst system by bringing it into contact with at least a C3-C12-&agr;-olefin, whereupon poly-C3-C12-&agr;-olefin chains are formed in the catalytically active titanium groups, and preferably by bringing the said catalyst system, the said C3-C12-&agr;-olefin and the said poly-C3-C12-&agr;-olefin chains into contact with hydrogen or some other similar chain transfer agent, whereupon a poly-C3-C12-&agr;-olefin terminated with hydrogen or suchlike is formed. In the process the improvement is achieved so that, in step A), i) a first controlled amount of a less soluble internal donor and a second controlled amount of a more soluble internal donor are provided on the surface of the said support, titanated support or activated support, in order to produce an internal donoration product, and ii) the internal donoration product is brought into contact with at least one eluant eluting the more soluble internal donor and with at least one external donor or a reagent forming it, in order to produce an external donoration product, the catalyst system thereby formed having at least catalytically active titanium groups, the said first controlled amount of the less soluble internal donor and the said second controlled amount comprising external donor.

4. 发明授权

US06420499B1 Catalyst component comprising magnesium, titanium, a halogen and an election donor, its preparation and use 有权
标题翻译：包含镁，钛，卤素和选择供体的催化剂组分，其制备和用途
公开(公告)号：US06420499B1
公开(公告)日：2002-07-16
申请号：US09216882
申请日：1998-12-21
申请人： Thomas Garoff , Timo Leinonen , Sirpa Ala-Huikku
发明人： Thomas Garoff , Timo Leinonen , Sirpa Ala-Huikku
IPC分类号： C08F450
CPC分类号： C08F10/00 , C07F3/003 , C08F4/6543 , C08F4/6546
摘要： The invention relates to a novel process for the preparation of an olefin polymerization catalyst component comprising magnesium, titanium, a halogen and an electron donor. The process comprises the steps of: (i) reacting a titaniumless magnesium compound (a) containing an alkoxy moiety, which titaniumless magnesium compound is selected from the group consisting of a compound or complex containing halogen and alkoxy linked to magnesium, a complex containing a magnesium dihalide and an alcohol, and a non-complex magnesium dialkoxide, with a halogen compound (b) being capable of forming the electron donor by replacement of its halogen by said alkoxy moiety, to give an intermediate (ab), and (ii) reacting said intermediate (ab) with a titanium halide (c), or (i)′ reacting a titaniumless magnesium compound (a) containing an alkoxy moiety, which titaniumless magnesium compound is selected from the group consisting of a compound or complex containing halogen and alkoxy linked to magnesium, and a complex containing a magnesium dihalide and an alcohol, with a titanium halide (c), to give an intermediate (ac), and (ii)′ reacting said intermediate (ac) with a halogen compound (b) being capable of forming the electron donor by replacement of its halogen by said alkoxy moiety.
摘要翻译：本发明涉及制备包含镁，钛，卤素和电子给体的烯烃聚合催化剂组分的新方法。该方法包括以下步骤：（i）使含有烷氧基部分的无钛镁化合物（a），该无钛镁化合物选自由与卤素连接的化合物或络合物与与镁连接的烷氧基，卤素化合物（b）能够通过用所述烷氧基部分取代其卤素形成电子给体，得到中间体（ab），和（ii）可以通过将卤素化合物（b）使所述中间体（ab）与卤化钛（c）反应，或（i）使含有烷氧基部分的无钛镁化合物（a）反应，该无钛镁化合物选自含卤素的化合物或络合物，烷氧基，和与二卤化镁和醇的络合物与卤化钛（c）反应，得到中间体（ac），和（ii）使所述中间体（ac）与卤素c反应（b）能够通过用所述烷氧基部分置换其卤素来形成电子给体。

5. 发明授权

US06407202B1 Poly(arylene ether) and process for making the same 有权
标题翻译：聚（亚芳基醚）及其制备方法
公开(公告)号：US06407202B1
公开(公告)日：2002-06-18
申请号：US09616737
申请日：2000-07-14
申请人： Adrianus J. F. M. Braat , Hugo G. E. Ingelbrecht , Peter Alexander Knops , Ruud Trion
发明人： Adrianus J. F. M. Braat , Hugo G. E. Ingelbrecht , Peter Alexander Knops , Ruud Trion
IPC分类号： C08F450
CPC分类号： C08G65/46 , C08G65/44
摘要： The present invention relates to substantially pure poly(arylene ether), e.g. purities exceeding about 99%, and to a method for making the same. The method which eliminates multiple rinses with a complexing reagent includes removing the catalyst from the polymerization mixture by mixing the polymerization mixture with a complexing reagent and liquid/liquid centrifuging the multiphase mixture. Water is then added to the polymer phase prior to a subsequent liquid/liquid centrifuge process. Once the catalyst has been sufficiently removed, the polymer can be concentrated in a flash vessel (which is not heated) by introducing a heated polymer phase to the vessel at a high pressure and quickly reducing the pressure. The concentrated polymer can then be introduced to an extruder to produce the high purity polymer. Due to the introduction of low molecular weight poly(arylene ether) at the intake zone of the extruder, essentially pure poly(arylene ether) can be isolated by this process. By combining the extruder process with an underwater pelletizer, thus providing extremely rapid cooling of the polymer melt when it exits the extruder and contacts air, much better color and lower amount of black specs in the final product is obtained.
摘要翻译：本发明涉及基本上纯的聚（亚芳基醚），例如纯度超过99％，以及其制造方法。用络合剂除去多次冲洗的方法包括通过将聚合混合物与络合试剂和离心多相混合物的液/液混合来从聚合混合物中除去催化剂。然后在随后的液/液离心分离工艺之前，将水加入到聚合物相中。一旦催化剂已被充分除去，聚合物可以通过在高压下将加热的聚合物相引入容器而快速降低压力而将其浓缩在闪蒸容器（其不加热）中。然后将浓缩的聚合物引入挤出机以制备高纯度聚合物。由于在挤出机的入口区域引入低分子量聚（亚芳基醚），所以可以通过该方法分离出基本上纯的聚（亚芳基醚）。通过将挤出机工艺与水下造粒机结合，从而在聚合物熔体离开挤出机并接触空气时提供非常快速的冷却，从而获得最终产品中更好的颜色和更少量的黑色规格。

6. 发明授权

US06399727B1 Heteroleptic alkaline-earth metal compounds and methods for carrying out stereoselective anionic polymerization 失效
标题翻译：异位碱土金属化合物和进行立体选择性阴离子聚合的方法
公开(公告)号：US06399727B1
公开(公告)日：2002-06-04
申请号：US09913993
申请日：2001-08-21
申请人： Konrad Knoll , Hans-Herbert Brintzinger , Sjoerd Harder , Armin Weeber , Florian Feil
发明人： Konrad Knoll , Hans-Herbert Brintzinger , Sjoerd Harder , Armin Weeber , Florian Feil
IPC分类号： C08F450
CPC分类号： C08F297/04 , C08F12/04 , C08F36/04 , C08F4/50
摘要： Polymerization initiator comprising an alkaline earth metal compound chosen from the group a) of heteroleptic alkaline earth metal compounds of the formula I L—M—R (I) or b) of cationic alkaline earth metal complexes of the formula II [D→M—R]+X− (II), where M: is Ca, Sr or Ba, L: is a polymerization-inactive ligand, R: is a polymerization-active ligand, D: is a donor ligand, and X: is a non-coordinating anion, and processes for the preparation of the polymerization initiators and processes for anionic polymerization in the presence of the polymerization initiators.
摘要翻译：聚合引发剂，其包含碱土金属化合物，其选自式I的异位碱土金属化合物，式I））其中M为Ca，Sr或Ba的阳离子碱土金属配合物，L：是聚合 - 无活性配体，R：是聚合活性配体，D：是供体配体，X是非配位阴离子，在聚合引发剂存在下制备聚合引发剂和阴离子聚合方法。

7. 发明授权

US06284702B1 Iron-based catalyst composition and process for producing syndiotactic 1,2-polybutadiene 有权
标题翻译：铁基催化剂组合物和间同立构1,2-聚丁二烯的制备方法
公开(公告)号：US06284702B1
公开(公告)日：2001-09-04
申请号：US09172346
申请日：1998-10-14
申请人： Steven Luo
发明人： Steven Luo
IPC分类号： C08F450
CPC分类号： C08F136/06 , C08F4/70
摘要： A catalyst composition comprising (a) an iron-containing compound, (b) an organomagnesium compound and (c) a dihydrocarbyl hydrogen phosphite is disclosed for polymerizing 1,3-butadiene into syndiotactic 1,2-polybutadiene. The use of the catalyst composition of this disclosure avoids the use of environmentally detrimental components such as carbon disulfide and halogenated solvents. The melting temperature of the syndiotactic 1,2-polybutadiene can be varied from about 100 to about 190° C. by variations in the catalyst components and the component ratios. The ability to vary the melting temperature with a single catalyst composition is very desirable. The syndiotactic 1,2-polybutadiene can be used as a plastic or as an additive for rubber compositions wherein it can crosslink with conventional rubbers using conventional crosslinking agents.
摘要翻译：公开了一种催化剂组合物，其包含（a）含铁化合物，（b）有机镁化合物和（c）二烃基亚磷酸氢盐，用于将1,3-丁二烯聚合成间规1,2-聚丁二烯。使用本公开的催化剂组合物避免使用环境有害组分如二硫化碳和卤化溶剂。间同立构1,2-聚丁二烯的熔融温度可以通过催化剂组分和组分比例的变化从约100至约190℃变化。用单一催化剂组合物改变熔融温度的能力是非常理想的。间规1,2-聚丁二烯可以用作塑料或作为橡胶组合物的添加剂，其中它可以使用常规的交联剂与常规橡胶交联。

8. 发明授权

US06758251B2 Pneumatic tire having a component containing high trans styrene-butadiene rubber 失效
公开(公告)号：US06758251B2
公开(公告)日：2004-07-06
申请号：US10224984
申请日：2002-08-21
申请人： Kenneth Allen Bates , Brian David Holden , John Joseph Andre Verthe
发明人： Kenneth Allen Bates , Brian David Holden , John Joseph Andre Verthe
IPC分类号： C08F450
CPC分类号： C08L9/06 , B60C1/00 , C08L21/00 , Y10T152/10036 , Y10T152/10495 , C08L2666/08
摘要： The invention is directed to a pneumatic tire having at least one component comprising a vulcanizable rubber composition, wherein the vulcanizable rubber composition comprises, based on 100 parts by weight of elastomer (phr), from about 30 to 100 phr of high trans random SBR, and from about zero to about 70 phr of at least one additional elastomer, wherein the high trans random SBR comprises from about 3 to about 30 percent by weight of styrene.

9. 发明授权

US06703455B1 Catalyst component comprising magnesium, titanium, a halogen and an electron donor, its preparation and use 有权
标题翻译：包含镁，钛，卤素和电子给体的催化剂组分，其制备和用途
公开(公告)号：US06703455B1
公开(公告)日：2004-03-09
申请号：US09762482
申请日：2001-02-07
申请人： Thomas Garoff , Timo Leinonen , Sirpa Ala-Huikku
发明人： Thomas Garoff , Timo Leinonen , Sirpa Ala-Huikku
IPC分类号： C08F450
CPC分类号： C08F110/06 , C08F4/651 , C08F4/6543 , C08F4/6548 , C08F2500/18 , C08F2500/12
摘要： A process for the preparation of an olefin polymerization catalyst component containing a magnesium dihalide, a titanium tetrahalide, and a dicarboxylic acid di- oligo- or polyester as internal electron donors is disclosed. A catalyst component and its use for the polymerization of &agr;-olefins such as propene are also disclosed.
摘要翻译：公开了一种制备含有二卤化镁，四卤化钛和二羧酸二低聚物或聚酯作为内电子给体的烯烃聚合催化剂组分的方法。还公开了催化剂组分及其用于α-烯烃如丙烯的聚合的用途。

10. 发明授权

US06627715B2 Group IIa metal containing catalyst system 失效
标题翻译： IIa族金属含催化剂体系
公开(公告)号：US06627715B2
公开(公告)日：2003-09-30
申请号：US10124006
申请日：2002-04-17
申请人： Adel Farhan Halasa , Wen-Liang Hsu , Chad Aaron Jasiunas , John Robert Zuppo, III , Laurie Elizabeth Austin
发明人： Adel Farhan Halasa , Wen-Liang Hsu , Chad Aaron Jasiunas , John Robert Zuppo, III , Laurie Elizabeth Austin
IPC分类号： C08F450
CPC分类号： B01J31/143 , B01J31/0212 , B01J31/04 , B01J31/122 , B01J31/128 , B01J31/14 , C08F36/04 , C08F297/04 , C08F297/06 , C08F4/52 , C08F4/44 , C08F4/54
摘要： The group IIa metal containing catalyst system of this invention can be utilized to synthesize rubbery polymers having a high trans microstructure by solution polymerization. Such rubbery polymers having a high trans microstructure content, such as polybutadiene rubber, styrene-isoprene-butadiene rubber, styrene-butadiene rubber, can be utilized in tire tread rubbers that exhibit improved wear and tear characteristics. This invention more specifically reveals a catalyst system which is comprised of (a) an organolithium compound, including organolithium functionalized compounds, (b) a group IIa metal salt selected from the group consisting of group IIa metal salts of di(alkylene glycol)alkylethers and group IIa metal salts of tri(alkylene glycol) alkylethers, and (c) an organoaluminum compound, and optionally an organomagnesium compound. The subject invention further discloses a process for synthesizing rubbery polymers having a high trans microstructure by a process that comprises polymerizing a conjugated diolefin monomer in an organic solvent in the presence of a catalyst system that is comprised of (a) an organolithium compound, (b) a group IIa metal salt selected from the group consisting of group IIa metal salts of amino glycols and group IIa metal salts of glycol ethers, and (c) an organoaluminum compound.
摘要翻译：本发明的含IIa族金属的催化剂体系可用于通过溶液聚合合成具有高反相微观结构的橡胶状聚合物。具有高反式显微组织含量的这种橡胶状聚合物，例如聚丁二烯橡胶，苯乙烯 - 异戊二烯 - 丁二烯橡胶，苯乙烯 - 丁二烯橡胶，可用于表现出改善的磨损和撕裂特性的轮胎胎面橡胶。本发明更具体地揭示了一种催化剂体系，其包括（a）有机锂化合物，包括有机锂官能化化合物，（b）选自二（亚烷基二醇）烷基醚的IIa族金属盐和三（亚烷基二醇）烷基醚的IIa族金属盐，和（c）有机铝化合物和任选的有机镁化合物。本发明还公开了一种通过包括在（a）有机锂化合物（b）的催化剂体系存在下在有机溶剂中聚合共轭二烯烃单体的方法来合成具有高反向显微组织的橡胶状聚合物的方法，）选自IIa族氨基二醇金属盐和IIa族二醇醚金属盐的IIa族金属盐，和（c）有机铝化合物。

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