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    • 8. 发明申请
    • Polymer Synthesis
    • 聚合物合成
    • US20130046052A1
    • 2013-02-21
    • US13583557
    • 2011-03-08
    • Steven P. ArmesYuting Li
    • Steven P. ArmesYuting Li
    • C08F265/06C09D153/00C08F259/02C08F275/00C08F265/10
    • C08F2/18C08F2/38C08F293/005C08F2438/03
    • A method of preparing a block copolymer of Formula (B) wherein P1 represents a substantially aqueously soluble polymeric component and P2 represents a substantially aqueously insoluble polymeric component, comprises admixing an aqueously soluble polymer macro-chain transfer agent comprising P1 with a monomer (M2) and initiating an aqueous dispersion-type radical addition fragmentation chain transfer (RAFT) polymerisation. (P1) is derived from a monomer (M1) selected from monomers of the Formulae (M1A), (M1B) and/or (M1C) where R1, R10 and R11 represent a substituent of (M1A) or (M1C) which allows P1 to be at least partially aqueously soluble, R2 represents H, CH3 or CN, RS represents one or more substituents of the aromatic ring effective to allow P1 to be at least partially aqueously soluble, and monomer M2 is selected from: where R3 is a substituent of (M2) which allows P2 to be substantially aqueously insoluble, and R4 and R6 independently represent H or methyl.
    • 制备式(B)的嵌段共聚物的方法,其中P1表示基本上是溶解性的聚合物组分,P2表示基本上不溶于水的聚合物组分,包括将包含P1的水溶性聚合物大分子链转移剂与单体(M2)混合, 并引发水分散型自由基加成断裂链转移(RAFT)聚合。 (P1)衍生自选自式(M1A),(M1B)和/或(M1C)的单体的单体(M1),其中R1,R10和R11表示(M1A)或(M1C)的取代基,其允许P1 至少部分是水溶性的,R 2表示H,CH 3或CN,RS表示芳族环的一个或多个取代基,其有效使P1至少部分可溶于水,单体M2选自:其中R 3为取代基 的(M2),其允许P2基本上不溶解,并且R 4和R 6独立地表示H或甲基。