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    • 1. 发明授权
    • Chelating polymer
    • 凝胶聚合物
    • US3578697A
    • 1971-05-11
    • US3578697D
    • 1968-10-10
    • GRACE W R & CO
    • MARANS MELSON S
    • C08G63/685C08G69/26C07C97/02
    • C08G69/26C08G63/6856
    • IN ABSTRACT THIS INVENTION IS DIRECTED TO A PROCESS FOR PREPARING A FINAL POLYMER HAVING THE FORMULA

      R3-(CH2-N(-R1)-CH2-Z-G-Z-CH2-N(-R2)-Z-G-Z)N-R4

      WHERE (I) N IS 2-4,000; (II) EACH OF R1 AND R2 IS SEPARATELY A MEMBER SELECTED FROM THE GROUP CONSISTING OF

      -CH2-COOH, -CH2-CH2-COOH, -CH2-CO-NH2, -CH2-CH2-CO-NH2

      THE MOLE RATIO OF CARBOXYL GROUPS TO AMIDE GROUPS BEING ABOUT 1:0.1-10; (III) G IS AN ALKYLENE GROUP HAVING ABOUT 2-12 CARBON ATOMS; (IV) R3 IS A MEMBER SELECTED FROM THE GROUP CONSISTING OF

      -COOH, -CO-NH-G-OH, -CO-NH-G-NH2, -COO-G-NH2, -COO-G-OH

      (V) R4 IS A MEMBER SELECTED FROM THE GROUP CONSISTING OF

      -CH2-N(-R5)-CH2-COOH, -CH2-N(-R5)-CH2-Z-G-OH,

      -CH2-N(-R5)-CH2-Z-G-NH2

      WHEREIN R5 IS A MEMBER SELECTED FROM THE GROUP CONSISTING OF

      -CH2-CO-NH2, -CH2-COOH, -CH2-CH2-CO-NH2, -CH2-CH2-COOH

      (VI) Z IS A MEMBER SELECTED FROM THE GROUP CONSISTING OF

      -CO-NH- , -COO-

      COMPRISING REACTING A DIHYDRIC ALCOHOL OR AN AMINO ALCOHOL, OR A DIAMINE WITH AN ACID HAVING THE FORMULA NC-A-N=(CH2COOH)2 WHEREIN A IS AN ALKYLENE GROUP HAVING 1-2 CARBON ATOMS TO FORM A FIRST INTERMEDIATE POLYMER, TREATING THE FIRST INTERMEDIATE POLYMER WITH HOT AQUEOUS ALKALI TO FORM A SECOND INTERMEDIATE POLYMER, AND TREATING THE SECOND AQUEOUS POLYMER WITH A STRONG MINERAL ACID TO FORM THE FINAL POLYMER WHICH IS RECOVERED, ALL AS RECITED HEREINAFTER.
    • 3. 发明授权
    • Process for producing alpha-monochloroacetoacetic acid monomethylamide
    • α-氯代乙酰乙酸单甲酰胺的制备方法
    • US4235818A
    • 1980-11-25
    • US963057
    • 1978-11-22
    • Roland DousseErnst Kagi
    • Roland DousseErnst Kagi
    • C07C233/00C07C103/34C07C97/02
    • C07C233/00
    • A process for the production of .alpha.-monochloroacetoacetic acid monomethylamide is disclosed which comprises chlorinating acetoacetic acid monomethylamide in the presence of urea and a water-soluble alkali metal salt or ammonium salt at a temperature of between -20.degree. and +10.degree. C. with 80-95% of the equivalent amount of chlorine; neutralizing the reaction mixture; separating the precipitated .alpha.-monochloroacetoacetic acid monomethylamide; and partially recycling the mother liquor back into the chlorination process. .alpha.-Chloroacetoacetic acid monomethylamide is a valuable intermediate for producing insecticidal active compounds, for example dimethyl-1-methyl-2-(methylcarbamoyl)-vinyl phosphate.
    • 公开了一种生产α-单氯乙酰乙酸单甲酰胺的方法,其包括在-20℃至+ 10℃的温度下在尿素和水溶性碱金属盐或铵盐的存在下将乙酰乙酸单甲基酰胺氯化, 80-95%当量氯; 中和反应混合物; 分离沉淀的α-单氯乙酰乙酸单甲酰胺; 并将母液部分回收回氯化过程。 α-氯代乙酰乙酸单甲酰胺是生产杀虫活性化合物的有价值的中间体,例如二甲基-1-甲基-2-(甲基氨基甲酰基) - 乙烯基磷酸酯。
    • 5. 发明授权
    • Process for the production of polyurethane foams
    • 生产聚氨酯泡沫的方法
    • US4022720A
    • 1977-05-10
    • US579522
    • 1975-05-21
    • Johannes BlahakHans-Joachim Meiners
    • Johannes BlahakHans-Joachim Meiners
    • C07C271/20C08G18/18C07C97/02
    • C08G18/1841C07C271/20
    • The present invention relates to a process for the production of polyurethane foams by reacting1. organic compounds with at least two hydrogen atoms capable of reacting with isocyanates and having molecular weights in the range from 400 to 10,000,2. polyisocyanates,3. water and/or organic blowing agents in the presence of catalysts containing tertiary nitrogen and, optionally, other additives, the improvement wherein the catalysts used are polyacyl compounds corresponding to the general formula: ##STR1## wherein A represents a C.sub.1 -C.sub.6 alkylene group, preferably a C.sub.2 or C.sub.3 alkylene group;R represents a C.sub.1 -C.sub.5 alkyl group, preferably methyl or ethyl;X represents an acyl group, preferably ##STR2##
    • 本发明涉及一种生产聚氨酯泡沫的方法,该方法是通过使有机化合物与至少两个可与异氰酸酯反应并具有400至10,000的范围内的分子量的氢原子反应而生成的。2.聚异氰酸酯,3.水和 /或有机发泡剂在含有苛性氮的催化剂存在下,以及任选的其它添加剂,所使用的催化剂的改进是与通用公式相关的聚酰胺化合物:其中A表示C1-C6亚烷基,优选为 C2或C3亚烷基; R表示C1-C5烷基,优选甲基或乙基; X表示酰基,优选