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1. 发明授权

US06664413B1 Process for production of esters 失效
标题翻译：酯类的生产工艺
公开(公告)号：US06664413B1
公开(公告)日：2003-12-16
申请号：US09196266
申请日：1998-11-19
申请人： Michael Charles Milner Cockrem
发明人： Michael Charles Milner Cockrem
IPC分类号： C07C6736
CPC分类号： C07C67/08 , C07C69/68
摘要： A process for producing an ester comprises the steps of: (a) feeding to a first vessel a feed that comprises organic acid, alcohol, and water, whereby organic acid and alcohol react to form monomeric ester and water, and whereby a first liquid effluent is produced that comprises as its components at least some ester, alcohol, and water, the components of the first liquid effluent being substantially in reaction equilibrium; and (b) feeding the first liquid effluent to a second vessel, whereby a vapor product stream and a second liquid effluent stream are produced, the vapor stream comprising ester, alcohol, and water, wherein the second vessel is maintained substantially at vapor-liquid equilibrium but not substantially at reaction equilibrium.
摘要翻译：一种制备酯的方法包括以下步骤：（a）向第一容器供给包含有机酸，醇和水的进料，由此有机酸和醇反应形成单体酯和水，由此第一液体流出物产生，其包含至少一些酯，醇和水作为其组分，第一液体流出物的组分基本上处于反应平衡状态; 和（b）将第一液体流出物供给到第二容器中，由此产生蒸气产物流和第二液体流出物流，所述蒸气流包含酯，醇和水，其中第二容器基本维持在气液平衡但基本上不反应平衡。

2. 发明授权

US06835850B2 Process for the carbonylation of a conjugated diene 失效
标题翻译：共轭二烯的羰基化方法
公开(公告)号：US06835850B2
公开(公告)日：2004-12-28
申请号：US10381040
申请日：2003-08-25
申请人： Eit Drent , Willem Wabe Jager , Otto Erik Sielcken , Imre Toth
发明人： Eit Drent , Willem Wabe Jager , Otto Erik Sielcken , Imre Toth
IPC分类号： C07C6736
CPC分类号： B01J31/04 , B01J31/2428 , B01J31/248 , B01J2231/321 , B01J2531/824 , C07C67/38 , C07C69/533
摘要： Process for the carbonylation of a conjugated diene by reacting the conjugated diene with carbon monoxide and an hydroxyl group containing compound in the presence of a catalyst system based on: (a) a source of palladium cations, (b) a diphosphine ligand, and (c) a source of anions, wherein the diphosphine ligand is a ligand having the general formula I wherein x1 and x2 represent a cyclic group with at least 5 ring atoms, of which one is a phosphorus atom, and R represents a bivalent aliphatic bridging group, connecting both phosphorus atoms, containing from 2 to 4 atoms in the bridge, which is substituted with at least one substituent or R represents a phenyl group with both phosphorus groups bound to the 1,2-position.
摘要翻译：通过在催化剂体系的存在下使共轭二烯与一氧化碳和含羟基的化合物反应来共轭二烯羰基化的方法，其基于：（a）钯阳离子源，（b）二膦配体和（ c）阴离子源，其中二膦配体是具有通式I的配体，其中x 1和x 2表示具有至少5个环原子的环状基团，其中一个是磷原子，R 代表二价脂肪族桥连基团，其连接两个在原子团中含有2至4个原子的磷原子，该原子被至少一个取代基取代，或R表示两个磷键与1,2-位相结合的苯基。

3. 发明授权

US06613938B2 Method for carbonylation of lower aliphatic alcohols using tin promoted platinum catalyst 失效
标题翻译：使用锡促进的铂催化剂羰基化低级脂族醇的方法
公开(公告)号：US06613938B2
公开(公告)日：2003-09-02
申请号：US09884815
申请日：2001-06-19
申请人： Joseph Robert Zoeller , Andy Hugh Singleton , Gerald Charles Tustin , Donald Lee Carver
发明人： Joseph Robert Zoeller , Andy Hugh Singleton , Gerald Charles Tustin , Donald Lee Carver
IPC分类号： C07C6736
CPC分类号： C07C67/36 , C07C51/12 , C07C67/37 , C07C53/08 , C07C69/14
摘要： A vapor-phase carbonylation method for producing esters and carboxylic acids from reactants comprising lower alkyl alcohols, lower alkyl alcohol generating compositions and mixtures thereof. The method includes contacting the reactants and carbon monoxide in a carbonylation zone of a carbonylation reactor under vapor-phase conditions with a catalyst having a catalytically effective amount of platinum and tin associated with a solid carrier material.
摘要翻译：一种用于由包含低级烷基醇，低级烷基醇生成组合物及其混合物的反应物生产酯和羧酸的气相羰基化方法。该方法包括在气相条件下将羰基化反应器的羰基化反应物和一氧化碳与具有催化有效量的与固体载体材料相关的锡和锡的催化剂接触。

4. 发明授权

US06646154B2 Method for carbonylation of lower alkyl alcohols using tungsten promoted group VIII catalyst 失效
公开(公告)号：US06646154B2
公开(公告)日：2003-11-11
申请号：US09884938
申请日：2001-06-20
申请人： Joseph Robert Zoeller , Andy Hugh Singleton , Gerald Charles Tustin , Donald Lee Carver
发明人： Joseph Robert Zoeller , Andy Hugh Singleton , Gerald Charles Tustin , Donald Lee Carver
IPC分类号： C07C6736
CPC分类号： C07C51/12 , C07C67/36 , C07C53/08 , C07C69/14
摘要： A vapor-phase carbonylation method for producing esters and carboxylic acids from reactants comprising lower alkyl alcohols, lower alkyl alcohol generating compounds, and mixtures thereof. The method includes contacting the reactants and carbon monoxide in a carbonylation zone of a carbonylation reactor under vapor-phase carbonylation conditions with a catalyst having a catalytically effective amount of a Group VIII metal selected from platinum or palladium, and tungsten which are associated with a solid catalyst support material.

5. 发明授权

US06617471B2 Method for carbonylation of lower aliphatic alcohols using tin promoted iridium catalyst 失效
标题翻译：使用锡促进的铱催化剂羰基化低级脂族醇的方法
公开(公告)号：US06617471B2
公开(公告)日：2003-09-09
申请号：US09885403
申请日：2001-06-20
申请人： Joseph Robert Zoeller , Andy Hugh Singleton , Gerald Charles Tustin , Donald Lee Carver
发明人： Joseph Robert Zoeller , Andy Hugh Singleton , Gerald Charles Tustin , Donald Lee Carver
IPC分类号： C07C6736
CPC分类号： C07C51/12 , C07C67/36 , C07C53/08 , C07C69/14
摘要： A vapor-phase carbonylation method for producing esters and carboxylic acids from reactants comprising lower alkyl alcohols, lower alkyl alcohol generating compounds, and mixtures thereof. The method includes contacting the reactants and carbon monoxide in a carbonylation zone of a carbonylation reactor under vapor-phase conditions with a catalyst having a catalytically effective amount of iridium and tin associated with a solid carrier material.
摘要翻译：用于由包含低级烷基醇，低级烷基醇产生化合物及其混合物的反应物制备酯和羧酸的气相羰基化方法。该方法包括在气相条件下将羰基化反应器的羰基化反应物和一氧化碳与具有催化有效量的铱和与固体载体材料相关的锡的催化剂接触。

6. 发明授权

US06521783B1 Processes for preparing oxygenates 失效
标题翻译：制备含氧化合物的方法
公开(公告)号：US06521783B1
公开(公告)日：2003-02-18
申请号：US09613275
申请日：2000-07-10
申请人： Richard William Wegman , David McNeill Somerville , Barry Brent Fish , Raymond Edwin Rooks , Chinsoo Stephen Lee , Paul Frank Bryan , William J. Bartley , David Michael Anthony Minahan , Fungau Ho
发明人： Richard William Wegman , David McNeill Somerville , Barry Brent Fish , Raymond Edwin Rooks , Chinsoo Stephen Lee , Paul Frank Bryan , William J. Bartley , David Michael Anthony Minahan , Fungau Ho
IPC分类号： C07C6736
CPC分类号： C07C67/36 , C07C29/1512 , C07C29/153 , C07C51/12 , C07C67/37 , Y02P20/582 , C07C53/08 , C07C69/14 , C07C31/04
摘要： This invention relates in part to a processes for the conversion of a feedstock stream comprising carbon monoxide and hydrogen to a product stream comprising at least one of an ester, acid, acid anhydride and mixtures thereof. This invention also relates in part to processes for converting an alcohol and/or ether feedstock to oxygenated products, e.g., esters, acids, acid anhydrides and mixtures thereof. The processes and catalysts are especially suitable for the production of acetic acid and methyl acetate from a synthesis gas feedstock or from an alcohol and/or ether feedstock.
摘要翻译：本发明部分地涉及将包含一氧化碳和氢气的原料流转化成包含酯，酸，酸酐及其混合物中的至少一种的产物流的方法。本发明还部分涉及将醇和/或醚原料转化为含氧产物，例如酯，酸，酸酐及其混合物的方法。方法和催化剂特别适用于从合成气原料或醇和/或醚原料生产乙酸和乙酸甲酯。

7. 发明授权

US06452043B1 Carbonylation of lower alkyl alcohols and their derivatives using metals supported on carbonized polysulfonated divinylbenzene-styrene copolymers 有权
标题翻译：使用负载在碳化多磺化二乙烯基苯 - 苯乙烯共聚物上的金属羰基化低级烷基醇及其衍生物
公开(公告)号：US06452043B1
公开(公告)日：2002-09-17
申请号：US09544639
申请日：2000-04-05
申请人： Joseph Robert Zoeller , Andy Hugh Singleton , Gerald Charles Tustin , Donald Lee Carver
发明人： Joseph Robert Zoeller , Andy Hugh Singleton , Gerald Charles Tustin , Donald Lee Carver
IPC分类号： C07C6736
CPC分类号： C07C51/12 , C07C67/36 , C07C53/08 , C07C69/14
摘要： A method for producing esters, carboxylic acids and mixtures thereof includes contacting, under carbonylation conditions, lower alkyl alcohols, ethers, lower alkyl alcohol derivatives and mixtures thereof and carbon monoxide with a catalyst having a catalytically effective amount a metal selected from iron, cobalt, nickel, ruthenium, rhodium, palladium, osmium, iridium, platinum, tin and mixtures thereof associated with a carbonized polysulfonated divinylbenzene-styrene copolymer matrix. In a preferred aspect of the invention the method is called out under vapor-phase conditions.
摘要翻译：一种生产酯，羧酸及其混合物的方法包括在羰基化条件下使低级烷基醇，醚，低级烷基醇衍生物及其混合物与一氧化碳与催化有效量的催化剂接触，所述催化剂选自铁，钴，镍，钌，铑，钯，锇，铱，铂，锡及其与碳化多磺化二乙烯基苯 - 苯乙烯共聚物基质相关的混合物。在本发明的优选方面，在气相条件下调出该方法。

8. 发明授权

US06737542B1 Process for the carbonylation of conjugated dienes 失效
标题翻译：共轭二烯的羰基化方法
公开(公告)号：US06737542B1
公开(公告)日：2004-05-18
申请号：US09937122
申请日：2001-09-20
申请人： Eit Drent , Willem Wabe Jager
发明人： Eit Drent , Willem Wabe Jager
IPC分类号： C07C6736
CPC分类号： C07C67/38 , C07C69/533
摘要： The present invention relates to a process for the carbonylation of conjugated dienes, whereby a conjugated diene is reacted with carbon monoxide and a hydroxyl group containing compound in the presence of a catalyst system including: (a) a source of palladium cations, (b) a phosphorus-containing ligand, (c) a source of anions, wherein the phosphorus-containing ligand is a ligand having the general formula (I): X1—R—X2 wherein X1 and X2 represent a substituted or non-substituted cyclic group with at least 5 ring atoms, of which one is a phosphorus atom, and R represents a bivalent organic bridging group, connecting both phosphorus atoms, containing from 1 to 4 atoms in the bridge, whereby the carbonylation process can be performed batch wise, semi-continuously or continuously.
摘要翻译：本发明涉及一种共轭二烯的羰基化方法，其中共轭二烯与一氧化碳和含羟基的化合物在催化剂体系存在下反应，包括：（a）钯阳离子源，（b）含磷配体，（c）阴离子源，其中所述含磷配体是具有通式（I）的配体：X 1 -RX 2其中X 1和X 2均为表示具有至少5个环原子的取代或未取代的环状基团，其中一个是磷原子，R表示在桥中连接含有1至4个原子的两个磷原子的二价有机桥连基团，由此羰基化工艺可以分批，半连续或连续进行。

9. 发明授权

US06653502B2 Process for preparing phenylacetic acid derivatives 失效
标题翻译：制备苯乙酸衍生物的方法
公开(公告)号：US06653502B2
公开(公告)日：2003-11-25
申请号：US10037078
申请日：2001-11-09
申请人： Holger Geissler
发明人： Holger Geissler
IPC分类号： C07C6736
CPC分类号： C07C51/10 , C07C67/36 , C07C57/32 , C07C57/58 , C07C69/612
摘要： A process for preparing phenylacetic acid derivatives of the formula (I) by reacting benzyl chlorides of the formula (II) with a compound of the formula R6OH and with carbon monoxide in a dipolar aprotic solvent in the presence of a catalyst which comprises at least one compound of a transition metal of subgroup VIII of the Periodic Table of the Elements, where R1, R2, R3, R4, and R5 independently of one another are the following radicals: a hydrogen or fluorine atom; a CH2Cl radical; a HO2CCH═CH—, NC— or CF3— group; an alkyl, alkoxy or acyloxy radical having in each case 1 to 18 carbon atoms; or a C6-C18-aryloxy, aryl or heteroaryl radical.
摘要翻译：一种制备式（I）的苯乙酸衍生物的方法，其通过式（II）的苄基氯与式R 6 OH的化合物和一氧化碳在偶极非质子传递溶剂中在催化剂存在下反应，包括至少一种元素周期表第VIII族过渡金属的化合物，其中R 1，R 2，R 3，R 4和R 5彼此独立地是是以下基团：氢或氟原子; CH 2 Cl基; HO 2 CCH = CH-，NC-或CF 3 - 基团;在每种情况下具有1至18个碳原子的烷基，烷氧基或酰氧基; 或C 6 -C 18芳氧基，芳基或杂芳基。

10. 发明授权

US06617472B1 Process for improving the stability and/or preventing the deactivation of the catalyst during the manufacture of acetic acid and/or of methyl acetate 有权
标题翻译：在乙酸和/或乙酸甲酯的制造期间提高稳定性和/或防止催化剂失活的方法
公开(公告)号：US06617472B1
公开(公告)日：2003-09-09
申请号：US09926755
申请日：2001-12-13
申请人： Daniel Thiebaut , Carl Patois , Lise Layeillon , Daniel Marchand
发明人： Daniel Thiebaut , Carl Patois , Lise Layeillon , Daniel Marchand
IPC分类号： C07C6736
CPC分类号： C07C51/353 , C07C51/12 , C07C67/36 , Y02P20/127 , Y02P20/584 , Y10S502/50 , C07C53/08 , C07C69/14
摘要： The present invention relates to process for improving the stability and/or preventing the deactivation of the catalyst in processes of manufacture of acetic acid and/or of methyl acetate according to which processes, in a first step, referred to as the reaction step, at least one methyl formate isomerization reaction is carried out in liquid phase, in the presence of carbon monoxide and of a catalytic system comprising at least one halogenated promoter and at least one iridium-based catalytic compound, and, in a second step, referred to as the flash step, the partial vaporization of the reaction medium originating from the first step is carried out in a separator referred to as the flash separator, characterized in that it consists in maintaining an overall content of formic acid and of methyl formate at least equal to 1% by weight of said liquid fraction, preferably between 1 and 50%, preferably between 1 and 30%, by weight with respect to said liquid fraction, in the non-vaporized liquid fraction originating from said flash separator. The invention also relates to a complete process of manufacture acetic acid and/or of methyl acetate which incorporates this improvement. The invention enables preparing acetic acid and/or methyl acetate with an increased stability of the catalytic system, even in the presence of contents of water which are particularly low, and of particularly low carbon monoxide pressures in the reaction zone, and is applied more particularly to processes of manufacture of acetic acid and/or of methyl acetate in which process the first step further comprises a methanol carbonylation reaction.
摘要翻译：本发明涉及在制备乙酸和/或乙酸甲酯的方法中提高稳定性和/或防止催化剂失活的方法，根据该方法，在第一步骤中称为反应步骤，在在一氧化碳和包含至少一种卤化促进剂和至少一种铱基催化化合物的催化体系的存在下，在液相中至少一种甲酸甲酯异构化反应进行，在第二步中，称为闪蒸步骤，来自第一步骤的反应介质的部分蒸发在称为快速分离器的分离器中进行，其特征在于其保持甲酸和甲酸甲酯的总含量至少等于所述液体馏分的1重量％，优选1至50重量％，优选1至30重量％，相对于所述液体馏分，在未汽化的l 来自所述闪蒸分离器的鱿鱼级分。本发明还涉及制备乙酸和/或乙酸甲酯的完整方法，其包括该改进。本发明能够制备具有提高的催化体系稳定性的乙酸和/或乙酸甲酯，即使在特别低的水含量和反应区中一氧化碳压力特别低的情况下，更具体地使用涉及乙酸和/或乙酸甲酯的制备方法，其中第一步还包括甲醇羰基化反应。

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