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    • 3. 发明申请
    • HIGH REGRESSION RATE HYBRID ROCKET PROPELLANTS AND METHOD OF SELECTING
    • 高回弹率混合岩石推进剂和选择方法
    • US20030098107A1
    • 2003-05-29
    • US09359149
    • 1999-07-21
    • M. ARIF KARABEYOGLUDAVID ALTMANBRIAN J. CANTWELL
    • C06B045/10
    • C06D5/00C06B47/02F02K9/72
    • This invention comprises a new process for developing high regression rate propellants for application to hybrid rockets and solid fuel ramjets. The process involves the use of a criterion to identify propellants which form an unstable liquid layer on the melting surface of the propellant. Entrainment of droplets from the unstable liquid-gas interface can substantially increase propellant mass transfer leading to much higher surface regression rates over those that can be achieved with conventional hybrid propellants. The main reason is that entrainment is not limited by heat transfer to the propellant from the combustion zone. The process has been used to identify a new class of non-cryogenic hybrid fuels whose regression rate characteristics can be tailored for a given mission. The fuel can be used as the basis for a simpler hybrid rocket design with reduced cost, reduced complexity and increased performance.
    • 本发明包括用于开发用于混合火箭和固体燃料雷击的高回归率推进剂的新方法。 该方法涉及使用标准来鉴定在推进剂的熔融表面上形成不稳定液体层的推进剂。 来自不稳定液 - 气界面的液滴的夹带可以显着增加推进剂质量传递,导致比常规混合推进剂可以实现的表面回归率高得多的表面回归率。 主要原因是夹带不受限于从燃烧区向推进剂的传热。 该过程已被用于确定一类新一代的非低温混合燃料,其回归率特征可以针对特定任务进行调整。 燃料可以用作更简单的混合火箭设计的基础,降低成本,降低复杂性并提高性能。
    • 7. 发明申请
    • Method for producing nanostructured metal-oxides
    • 生产纳米结构金属氧化物的方法
    • US20020104599A1
    • 2002-08-08
    • US09981076
    • 2001-10-16
    • Thomas M. TillotsonRandall L. SimpsonLawrence W. HrubeshAlexander Gash
    • C06B045/10
    • C01F7/34C01B13/32C01F17/0043C01G1/02C01G15/00C01G19/02C01G25/02C01G27/02C01G33/00C01G37/033C01G41/00C01G43/01C01G49/02C01P2002/82C01P2006/12C01P2006/14C01P2006/16C06B21/0058C06B33/00C06B47/00Y02P20/544
    • A synthetic route for producing nanostructure metal-oxide-based materials using sol-gel processing. This procedure employs the use of stable and inexpensive hydrated-metal inorganic salts and environmentally friendly solvents such as water and ethanol. The synthesis involves the dissolution of the metal salt in a solvent followed by the addition of a proton scavenger, which induces gel formation in a timely manner. Both critical point (supercritical extraction) and atmospheric (low temperature evaporation) drying may be employed to produce monolithic aerogels and xerogels, respectively. Using this method synthesis of metal-oxide nanostructured materials have been carried out using inorganic salts, such as of Fe3null, Cr3null, Al3null, Ga3null, In3null, Hf4null, Sn4null, Zr4null, Nb5null, W6null, Pr3null, Er3null, Nd3null, Ce3null, U3null and Y3null. The process is general and nanostructured metal-oxides from the following elements of the periodic table can be made: Groups 2 through 13, part of Group 14 (germanium, tin, lead), part of Group 15 (antimony, bismuth), part of Group 16 (polonium), and the lanthanides and actinides. The sol-gel processing allows for the addition of insoluble materials (e.g., metals or polymers) to the viscous sol, just before gelation, to produce a uniformly distributed nanocomposites upon gelation. As an example, energetic nanocomposites of FexOy gel with distributed Al metal are readily made. The compositions are stable, safe, and can be readily ignited to thermitic reaction.
    • 使用溶胶 - 凝胶法生产纳米结构金属氧化物基材料的合成路线。 该方法使用稳定且廉价的水合金属无机盐和环境友好的溶剂如水和乙醇。 该合成涉及将金属盐溶解在溶剂中,然后加入质子清除剂,其迅速诱导凝胶形成。 可以采用临界点(超临界萃取)和大气(低温蒸发)干燥来分别制备单片气凝胶和干凝胶。 使用这种方法,使用无机盐如Fe 3+,Cr 3+,Al 3+,Ga 3+,In 3+,Hf 4+,Sn 4+,Zr 4+,Nb 5+,W 6+,Pr 3+,Er 3+,Nd 3+,Ce 3+,U 3+ 和Y3 +。 该方法是通用的,并且可以制备来自周期表的以下元素的纳米结构金属氧化物:组2至13,第14族(锗,锡,铅)的一部分,第15族的一部分(锑,铋),部分 第16组(onium),镧系元素和锕系元素。 溶胶 - 凝胶加工允许在凝胶化之前向粘性溶胶中添加不溶性材料(例如金属或聚合物),以在凝胶化时产生均匀分布的纳米复合材料。 作为示例,容易地制备具有分布的Al金属的FexOy凝胶的高能纳米复合材料。 组合物是稳定的,安全的,并且可以容易地点燃到耐火反应。