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    • 8. 发明授权
    • Process for capturing metal ions
    • 捕获金属离子的方法
    • US3755158A
    • 1973-08-28
    • US3755158D
    • 1971-08-04
    • AJINOMOTO KK
    • INAZUKA STAKEHARA MYOSHIDA R
    • C09K3/00C02F1/52C02F1/54C02F1/62C02B1/26
    • C02F1/54C02F1/5236C02F1/5272
    • Cations of metals other than the alkali metals may be precipitated practically completely from their aqueous solutions at a pH of 4 or higher by N-acylamino acids whose acyl group is alkanoyl or alkenoyl having seven to 25 carbon atoms, the acylamino group being connected with the carboxyl group by divalent alkylene having one to five carbon atoms. The voluminous precipitates include even more of the metal ions originally present and settle faster in the presence of small amounts of polyhydric alcohols, polyethers, alkali metal silicates, or alkali metal borates. Water polluted with heavy metals can be made potable by this method.
    • 碱金属以外的金属的阳离子可以通过其酰基为具有7至25个碳原子的烷酰基或烯酰基的N-酰基氨基酸在pH4或更高的水溶液中几乎完全沉淀,酰氨基与 具有1至5个碳原子的二价亚烷基的羧基。 在少量多元醇,聚醚,碱金属硅酸盐或碱金属硼酸盐的存在下,大量的沉淀物包括甚至更多的最初存在的金属离子和更快地沉降。 用重金属污染的水可以通过这种方法饮用。
    • 9. 发明授权
    • Method for removing heavy metals from aqueous liquids
    • 从含水液体中去除重金属的方法
    • US4278539A
    • 1981-07-14
    • US940837
    • 1978-09-08
    • Chakra J. SanthanamRavindra M. Nadkarni
    • Chakra J. SanthanamRavindra M. Nadkarni
    • C02F1/52C02F9/00C22B3/44C02B1/26C02C5/02
    • C02F9/00C02F1/5236C22B3/44C02F2101/20Y02P10/234
    • Method and apparatus for removing heavy metals as sulfides from aqueous liquids. The aqueous liquid is introduced into a circulating liquid loop wherein there are established a mixing zone, a controlled precipitation initiating zone, a crystal growing zone and a crystal settling zone. The aqueous feed liquid containing H.sub.2 S dissolved therein and at a pH below that at which the sulfide is precipitated is mixed in the loop with a pH-adjusting liquid; and the degree of supersaturation with respect to the metal sulfide is maintained within the controlled precipitation initiating and crystal growing zones in the metastable condition so that the growth rate of the metal sulfide crystals remains greater than under uncontrolled conditions vis-a-vis the nucleation rate to effect the production of metal sulfide crystals of a character which makes it possible to separate them through clarification and filtration.
    • 从含水液体中除去重金属作为硫化物的方法和装置。 将水性液体引入到循环液体回路中,其中建立了混合区,受控沉淀引发区,晶体生长区和晶体沉降区。 将含有H 2 S的含水进料液在pH低于沉淀硫酸的pH下与pH调节液混合, 并且相对于金属硫化物的过饱和度在亚稳态下保持在受控沉淀引发和晶体生长区内,使得金属硫化物晶体的生长速率保持大于在不成对条件下的成核速率 以实现能够通过澄清和过滤分离它们的特性的金属硫化物晶体的生产。