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1. 发明授权

US4917773A Process for introducing zirconium tetrachloride, hafnium tetrachloride and mixtures thereof into a column for the continuous extractive distillation under pressure of said chlorides 失效
标题翻译：将四氯化锆，四氯化铪及其混合物引入用于在所述氯化物的压力下进行连续萃取蒸馏的塔中的方法
公开(公告)号：US4917773A
公开(公告)日：1990-04-17
申请号：US319054
申请日：1989-03-06
申请人： Pierre Brun , Jean Guerin
发明人： Pierre Brun , Jean Guerin
IPC分类号： C01G25/00 , C01G25/04 , C01G27/04
CPC分类号： C01G25/04 , C01G27/04 , Y10S203/17
摘要： The process and the device according to the invention relate to the introduction, at a stable, known flow rate, of sublimable tetrachloride into a column for continuous extractive distillation under pressure of the chlorides. The sublimable tetrachloride is dissolved in a hot dissolver in a liquid solvent such as KAlCl.sub.4, and is then recirculated by pump at a stable, known flow rate into an evaporator connected to the column. The solution is then heated in an evaporator in order to sublime the majority of the product which it contains, the sublimed vapors thus passing into the column at a stable, known flow rate. The process according to the invention is adapted, in particular, to a plant for the production of ArCl.sub.4 of nulear purity and of HfCl.sub.4.
摘要翻译：根据本发明的方法和装置涉及以稳定的已知流速将可升华的四氯化钛引入用于在氯化物的压力下进行连续萃取蒸馏的塔中。将升华的四氯化碳溶解在诸如KAlCl 4的液体溶剂中的热溶解器中，然后通过泵以稳定的已知流速再循环到连接到塔的蒸发器中。然后将溶液在蒸发器中加热以使其含有的大部分产物升华，升华的蒸气因此以稳定的已知流速进入塔中。根据本发明的方法特别适用于生产纯净的ArCl4和HfCl4的工厂。

2. 发明授权

US4910009A Ultra high purity halides and their preparation 失效
标题翻译：超高纯度卤化物及其制备方法
公开(公告)号：US4910009A
公开(公告)日：1990-03-20
申请号：US190992
申请日：1988-05-06
申请人： James A. Sommers
发明人： James A. Sommers
IPC分类号： C01B9/00 , C01B9/02 , C01F7/48 , C01F7/50 , C01F7/62 , C01G25/04 , C01G27/04 , C03C3/32
CPC分类号： C01B9/02 , C01B9/00 , C01F7/48 , C01F7/62 , C01G25/04 , C01G27/04 , C01P2006/80
摘要： The process for purifying a contaminated chloro, bromo or iodo precursor salt of zirconium, hafnium or aluminum by means of providing a molten thermal body of one or more alkali or alkaline earth metal halides and the precursor salt containing impurities, maintaining the body at a temperature sufficient to volatilize the precursor salt away from its impurities while effecting a reducing condition in the body by means of a fluid, mobile reducing agent which is non-reducing of said precursor salt, and isolating the purified volatilized precursor salt from the body. The ultra purified isolated volatilized precursor salt can then be reacted with a fluorinating agent to produce the highly purified fluoride for use in optical fiber grade glass or the like.
摘要翻译：通过提供一种或多种碱金属或碱土金属卤化物的熔融热体和含有杂质的前体盐来净化锆，铪或铝的受污染氯，溴或碘前体盐的方法，将身体保持在温度足以使前体盐远离其杂质挥发，同时通过不减少所述前体盐的流体，可移动还原剂并且将纯化的挥发的前体盐与人体分离，从而在体内还原状态。然后可以将超纯化的分离的挥发前体盐与氟化剂反应，生成用于光纤级玻璃等的高纯度氟化物。

3. 发明授权

US4874559A Process and devices for operation of an apparatus which functions by using a flow of a liquid film 失效
标题翻译：用于通过使用液膜流动而起作用的装置的操作的方法和装置
公开(公告)号：US4874559A
公开(公告)日：1989-10-17
申请号：US298896
申请日：1989-01-19
申请人： Pierre Brun
发明人： Pierre Brun
IPC分类号： B01D1/06 , C01G25/04 , C01G27/04
CPC分类号： B01D1/065 , C01G25/04 , C01G27/04
摘要： The invention concerns a process and an apparatus for maintaining a very thin film in an exchanger involving a flowing liquid film. The process wherein the liquid films are fed by gravity from a liquid source is characterised in that: each film is fed at the permanent flow (kd.sub.1) corresponding to the feed flow rate (d.sub.1) of the source; then for a short period of time the flow rate is increased to a transient value (kd.sub.2) for establishing a continuous film over the whole of the corresponding flow surface; then operation returns to the flow rate (kd.sub.1) for the film in question, the short periods of feeding the different films at their transient flow rates (kd.sub.2) being displaced in respect of time. The apparatus according to the invention comprises at the top of each flow tube a movable sleeve, lifting movement or rotary movement of which opens a supplementary communication between the liquid source and the tube, permitting the film flow rate to assume the transient value (kd.sub.2). The process is applied in particular to the process for separation of tetrachlorides of Zr and Hf.
摘要翻译：本发明涉及一种用于在涉及流动液体膜的交换器中保持非常薄的薄膜的方法和装置。其中液体膜通过重力从液体源进料的过程的特征在于：每个膜以对应于源的进料流速（d1）的永久流（kd1）进料; 然后在短时间内将流量增加到用于在整个相应流动表面上建立连续膜的瞬时值（kd2）; 那么操作返回到所讨论的膜的流速（kd1），在瞬时流速（kd2）相对于时间被移位的不同膜的短时间段。根据本发明的装置包括在每个流管的顶部，可移动套管，提升运动或其旋转运动打开液体源和管之间的补充连通，允许膜流速呈现瞬态值（kd2）。该方法特别适用于分离Zr和Hf四氯化物的方法。

4. 发明授权

US4749448A Zirconium and hafnium tetrachloride separation by extractive distillation with molten zinc chloride calcium and/or magnesium chloride solvent 失效
标题翻译：通过采用熔融氯化锌钙和/或氯化镁溶剂的萃取蒸馏分离锆和四氯化铪
公开(公告)号：US4749448A
公开(公告)日：1988-06-07
申请号：US943112
申请日：1986-12-18
申请人： Richard A. Stoltz , David F. McLaughlin
发明人： Richard A. Stoltz , David F. McLaughlin
IPC分类号： B01D3/00 , B01D3/40 , B01D11/04 , C01G25/04 , C01G27/04 , C22B34/14
CPC分类号： C01G27/04 , B01D3/40 , C01G25/04 , C22B34/14
摘要： This is a molten salt extractive distillation process for separating hafnium from zirconium. It utilizes at least principally a ZnCl.sub.2 --Ca/MgCl.sub.2 molten salt solvent, and preferably ZnCl.sub.2 --Ca/MgCl.sub.2 in a near 95-15 mixture. The extraction column is preferably run about 380.degree.-420.degree. C. at about one atmosphere and stripping is preferably done at about 385.degree.-450.degree. C. utilizing an inert gas carrier.
摘要翻译：这是一种用于从锆中分离铪的熔盐萃取蒸馏方法。它至少主要在近95-15混合物中使用ZnCl2-Ca / MgCl2熔融盐溶剂，优选使用ZnCl 2 -Ca / MgCl 2。萃取塔优选在大约一个大气压下流动约380-420℃，优选在约385°-450℃下使用惰性气体载体进行汽提。

5. 发明授权

US4578252A Method for preparing ultra-pure zirconium and hafnium tetrafluorides 失效
标题翻译：制备超纯锆和四氟化铪的方法
公开(公告)号：US4578252A
公开(公告)日：1986-03-25
申请号：US734008
申请日：1985-05-14
申请人： Ricardo C. Pastor , Morton Robinson
发明人： Ricardo C. Pastor , Morton Robinson
IPC分类号： C01B9/08 , C01G1/06 , C01G25/04 , C01G27/04
CPC分类号： C01G27/04 , C01B9/08 , C01G1/06 , C01G25/04
摘要： A method for preparing ultra-pure metal tetrafluorides in which 3d such as Fe impurities are separated from impure material by a combined vaporization-electrolytic separation procedure. Sublimation and distillation methods are disclosed in combination with electrolytic separation by both emf-series displacement (ESD) and direct melt electrolysis (DME).
摘要翻译：制备超纯四氟化金属的方法，其中通过组合的蒸发 - 电解分离方法将诸如Fe杂质的3d与不纯物质分离。公开了升华和蒸馏方法结合电动分离（emf-series displacement）（ESD）和直接熔融电解（DME）两种方法。

6. 发明授权

US3966458A Separation of zirconium and hafnium 失效
标题翻译：分离锆和铪
公开(公告)号：US3966458A
公开(公告)日：1976-06-29
申请号：US503724
申请日：1974-09-06
申请人： Donald R. Spink
发明人： Donald R. Spink
IPC分类号： C01G27/04 , C22B34/14 , C22B61/02
CPC分类号： C22B34/14 , C01G27/04
摘要： A process is provided for separating zirconium and hafnium tetrachlorides by the direct distillation from their solution in an eutectic mixture of sodium and potassium chlorides. Hafnium tetrachloride and zirconium tetrachloride are provided in adequate purity for direct introduction into reduction units for the production of the respective metals by virtue of controlled ratios of the salt eutectic solvent to the hafnium and zirconium tetrachlorides and by provision of a reflux of hafnium with added increments of the eutectic solvent salt mixture.
摘要翻译：提供了一种通过直接蒸馏从氯化钠和氯化钾的共晶混合物中的溶液分离锆和四氯化铪的方法。提供四氯化铪和四氯化锆足够的纯度，以便通过盐共晶溶剂与铪和四氯化锆的控制比例和通过提供铪的回流添加增量来直接引入用于生产各种金属的还原单元的共晶溶剂盐混合物。

7. 发明授权

US3098722A Purification of metal halides 失效
标题翻译：金属卤化物的净化
公开(公告)号：US3098722A
公开(公告)日：1963-07-23
申请号：US78728259
申请日：1959-01-16
申请人： NAT DISTILLERS CHEM CORP
发明人： CARLSON EUGENE C , MULLER WERNER C
IPC分类号： C01G25/04 , C01G27/04
CPC分类号： C01G25/04 , C01G27/04

8. 发明授权

US09005556B2 Process for separating zirconium and hafnium tetrachlorides from mixtures 有权
标题翻译：从混合物中分离锆和四氯化铪的方法
公开(公告)号：US09005556B2
公开(公告)日：2015-04-14
申请号：US13813696
申请日：2011-08-02
申请人： Catherine Santini-Scampucci , Yves Chauvin , Paul Campbell
发明人： Catherine Santini-Scampucci , Yves Chauvin , Paul Campbell
IPC分类号： B01D11/00 , C22B3/20 , C01G25/00 , C01G25/04 , C01G27/00 , C01G27/04 , C22B3/42 , C22B34/14
CPC分类号： C22B3/20 , C01G25/003 , C01G25/04 , C01G27/003 , C01G27/04 , C01P2002/86 , C22B3/42 , C22B34/14 , Y02P10/234
摘要： A simple, inexpensive and non-corrosive industrial separation method making it possible to separate zirconium and hafnium tetrachlorides from mixtures thereof, a simple industrial method allowing the zirconium/hafnium separation, and a method making it possible to produce fractions enriched with zirconium and containing hafnium at a trace level are disclosed.
摘要翻译：一种简单，便宜且无腐蚀性的工业分离方法，可以将锆和铪四氯化物与其混合物分离，这是允许锆/铪分离的简单工业方法，以及可以生产富含锆并含有铪的馏分在痕迹水平被公开。

9. 发明授权

US08790508B2 Integrated deasphalting and oxidative removal of heteroatom hydrocarbon compounds from liquid hydrocarbon feedstocks 有权
标题翻译：从液态烃原料中综合脱沥青和氧化除去杂原子烃化合物
公开(公告)号：US08790508B2
公开(公告)日：2014-07-29
申请号：US12893367
申请日：2010-09-29
申请人： Omer Refa Koseoglu , Abdennour Bourane
发明人： Omer Refa Koseoglu , Abdennour Bourane
IPC分类号： C10G53/00 , C10G53/16 , C10G29/00 , C10G29/20 , C01G27/00 , C01G27/04
CPC分类号： C10G27/12 , B01J21/063 , B01J23/22 , B01J23/28 , B01J23/30 , C10G2300/202 , C10G2300/206 , C10G2300/44
摘要： A system and process are provided for integrated deasphalting and desulfurization of hydrocarbon feedstock in which the hydrocarbon feedstock, an oxidant, and an oxidation catalyst are mixed prior to passage into a primary settler of a solvent deasphalting unit. Oxidation products, including oxidized organosulfur compounds, are discharged with the asphalt phase.
摘要翻译：提供了一种用于烃原料的综合脱沥青和脱硫的系统和方法，其中烃原料，氧化剂和氧化催化剂在通入溶剂脱沥青装置的初级沉降器之前混合。包括氧化有机硫化合物在内的氧化产物用沥青相排出。

10. 发明授权

US5171549A Process for decreasing the level of impurities in zirconium chloride, titanium chloride and hafnium chloride 失效
标题翻译：降低氯化锆，氯化钛和氯化铪中杂质含量的方法
公开(公告)号：US5171549A
公开(公告)日：1992-12-15
申请号：US704120
申请日：1991-05-22
申请人： Ronald E. Walsh, Jr. , Peter W. Krag , Roy E. Blackstone , Duane L. Hug
发明人： Ronald E. Walsh, Jr. , Peter W. Krag , Roy E. Blackstone , Duane L. Hug
IPC分类号： C01G23/02 , C01G25/04 , C01G27/04 , C22B34/10 , C22B34/12
CPC分类号： C22B34/1245 , C01G23/024 , C01G25/04 , C01G27/04 , C22B34/10
摘要： An improved halogenator process and system is provided which significantly and economically decreases the level of impurities in the processing of various refractory metals and their halides and particularly hafnium tetrachloride which is condensed from gases produced by the chlorination of Zircon.
摘要翻译：提供了一种改进的卤化物方法和系统，其显着和经济地降低了各种难熔金属及其卤化物的加工中的杂质水平，特别是由通过氯化锆石产生的气体而冷凝的四氯化铪。

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