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    • 4. 发明授权
    • Process for manufacturing boron nitride fiber felt using a Fourdrinier
machine
    • 使用长网机制造氮化硼纤维毡的工艺
    • US4309245A
    • 1982-01-05
    • US134903
    • 1980-03-28
    • John L. TworekGordon R. Rignel
    • John L. TworekGordon R. Rignel
    • D04H1/42B29C67/24D04H1/72H01M2/14D21H5/18
    • H01M2/14D21H13/36D21H5/18
    • A process is disclosed for producing a non-woven boron nitride (BN) fiber felt. Boron nitride fibers are blended with a lesser amount of boron oxide fibers and a nondissolving, anhydrous liquid medium to form a homogeneous slurry. The slurry is deposited on the moving screen of a Fourdrinier machine where the liquid content is gradually reduced until sufficient fiber to fiber contact is made to provide internal cohesiveness, to form a felt. The felt may be further treated by heating it in an anhydrous gas atmosphere at a sufficient temperature to soften the boron oxide binder to fuse the BN fibers together, and then converting the interstitial boron oxide into boron nitride. The resulting boron nitride-bonded boron nitride felt may be used as an electric cell separator in a lithium sulfide battery.
    • 公开了用于生产无纺布氮化硼(BN)纤维毡的方法。 将氮化硼纤维与较少量的氧化硼纤维和非溶解的无水液体介质共混以形成均匀的浆料。 将浆料沉积在长网机的移动筛上,其中液体含量逐渐降低,直到足够的纤维与纤维接触以提供内部粘结性以形成毡。 可以通过在足够的温度下在无水气体气氛中加热毡来进一步处理毛毡,以软化氧化硼粘合剂以将BN纤维熔合在一起,然后将间隙氧化硼转变成氮化硼。 得到的氮化硼结合氮化硼毡可以用作硫化锂电池中的电池隔膜。
    • 5. 发明授权
    • Process for manufacturing boron nitride fiber mats
    • 氮化硼纤维毡的制造方法
    • US4309244A
    • 1982-01-05
    • US134765
    • 1980-03-28
    • John L. TworekGordon R. Rignel
    • John L. TworekGordon R. Rignel
    • D01F9/08B29C67/24C04B35/583C04B35/622D04H1/42D04H1/54H01M2/14D21H5/18D21H5/26
    • C04B35/583C04B35/62227D21H13/36D21H5/18H01M2/14
    • A process is disclosed for producing a non-woven, boron nitride-bonded boron nitride fiber mat, suitable for use as an electric cell separator in a lithium-sulfide battery. Molten boron oxide is centrifugally spun into strands and attenuated by an annular gas stream into fibers which are compacted at a controlled relative humidity into a bundle and heated in an anhydrous ammonia atmosphere to convert boron oxide in the fibers to boron nitride (BN). The BN fibers are blended with a lesser amount of boron oxide fibers and a nonaqueous liquid medium to form a slurry. The slurry is processed through a Fourdrinier machine to form a felt; and, the felt is calendered by passing it through the nip of a pair of calender rolls at an appropriate temperature and pressure to soften the boron oxide binder to fuse the BN fibers together. The interstitial boron oxide then is converted to boron nitride.
    • 公开了用于生产适合用作硫化锂电池中的电池隔板的无纺布氮化硼结合氮化硼纤维垫的方法。 将熔融的氧化硼离心旋转成股线,并通过环形气流减压成纤维,将纤维在受控的相对湿度下压成束,并在无水氨气氛中加热,将纤维中的氧化硼转化为氮化硼(BN)。 将BN纤维与较少量的氧化硼纤维和非水液体介质共混以形成浆料。 通过长网机加工浆料以形成毡; 并且通过在适当的温度和压力下将其通过一对压延辊的辊隙来使毡被压延,以软化氧化硼粘合剂以将BN纤维熔合在一起。 然后将间隙氧化硼转化为氮化硼。
    • 10. 发明授权
    • High-temperature zirconia insulation and method for making same
    • 高温氧化锆绝缘及其制作方法
    • US4743340A
    • 1988-05-10
    • US810899
    • 1985-12-20
    • George E. Wrenn, Jr.Cressie E. Holcombe, Jr.John Lewis, Jr.
    • George E. Wrenn, Jr.Cressie E. Holcombe, Jr.John Lewis, Jr.
    • D21J7/00D21H5/18
    • D21H5/18D21H13/36
    • The present invention is directed to a highly pure, partially stabilized, fibrous zirconia composite for use as thermal insulation in environments where temperatures up to about 2000.degree. C. are utilized. The composite of the present invention is fabricated into any suitable configuration such as a cone, cylinder, dome or the like by vacuum molding an aqueous slurry of partially stabilized zirconia fibers into a desired configuration on a suitably shaped mandrel. The molded fibers are infiltrated with zirconyl nitrate and the resulting structure is then dried to form a rigid structure which may be removed and placed in a furnace. The structure is then heated in air to a temperature of about 600.degree. C. for driving off the nitrate from the structure and for oxidizing the zirconyl ion to zirconia. Thereafter, the structure is heated to about 950.degree. to 1,250.degree. C. to fuse the zirconia fibers at their nexi in a matrix of zirconia. The composite produced by the present invention is self-supporting and can be readily machined to desired final dimensions. Additional heating to about 1800.degree. to 2000.degree. C. further improves structural rigidity.
    • 本发明涉及一种高纯度,部分稳定的纤维状氧化锆复合材料,用于在高达约2000℃的温度下使用的绝热材料。 通过将部分稳定的氧化锆纤维的含水浆料真空成型为合适形状的心轴上所需的构型,将本发明的复合材料制成任何合适的构型,例如锥体,圆筒,圆顶等。 模制的纤维用硝酸氧锆渗透,然后将所得结构物干燥以形成可以去除并置于炉中的刚性结构。 然后将结构在空气中加热到约600℃的温度,以从结构中排除硝酸盐,并将氧化锆氧化成氧化锆。 此后,将结构加热至约950℃至1250℃,以将氧化锆纤维在其氧化锆基体中熔化。 由本发明生产的复合材料是自支撑的并且可以容易地加工成所需的最终尺寸。 另外加热至约1800°至2000℃,进一步提高了结构刚度。