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    • 1. 发明授权
    • High-temperature zirconia insulation and method for making same
    • 高温氧化锆绝缘及其制作方法
    • US4743340A
    • 1988-05-10
    • US810899
    • 1985-12-20
    • George E. Wrenn, Jr.Cressie E. Holcombe, Jr.John Lewis, Jr.
    • George E. Wrenn, Jr.Cressie E. Holcombe, Jr.John Lewis, Jr.
    • D21J7/00D21H5/18
    • D21H5/18D21H13/36
    • The present invention is directed to a highly pure, partially stabilized, fibrous zirconia composite for use as thermal insulation in environments where temperatures up to about 2000.degree. C. are utilized. The composite of the present invention is fabricated into any suitable configuration such as a cone, cylinder, dome or the like by vacuum molding an aqueous slurry of partially stabilized zirconia fibers into a desired configuration on a suitably shaped mandrel. The molded fibers are infiltrated with zirconyl nitrate and the resulting structure is then dried to form a rigid structure which may be removed and placed in a furnace. The structure is then heated in air to a temperature of about 600.degree. C. for driving off the nitrate from the structure and for oxidizing the zirconyl ion to zirconia. Thereafter, the structure is heated to about 950.degree. to 1,250.degree. C. to fuse the zirconia fibers at their nexi in a matrix of zirconia. The composite produced by the present invention is self-supporting and can be readily machined to desired final dimensions. Additional heating to about 1800.degree. to 2000.degree. C. further improves structural rigidity.
    • 本发明涉及一种高纯度,部分稳定的纤维状氧化锆复合材料,用于在高达约2000℃的温度下使用的绝热材料。 通过将部分稳定的氧化锆纤维的含水浆料真空成型为合适形状的心轴上所需的构型,将本发明的复合材料制成任何合适的构型,例如锥体,圆筒,圆顶等。 模制的纤维用硝酸氧锆渗透,然后将所得结构物干燥以形成可以去除并置于炉中的刚性结构。 然后将结构在空气中加热到约600℃的温度,以从结构中排除硝酸盐,并将氧化锆氧化成氧化锆。 此后,将结构加热至约950℃至1250℃,以将氧化锆纤维在其氧化锆基体中熔化。 由本发明生产的复合材料是自支撑的并且可以容易地加工成所需的最终尺寸。 另外加热至约1800°至2000℃,进一步提高了结构刚度。
    • 3. 发明授权
    • Process for producing a uniform fiber dispersion and machine made light
weight glass fiber web material
    • 制造均匀的纤维分散体和机器制造轻质玻璃纤维网材料的方法
    • US4234379A
    • 1980-11-18
    • US910881
    • 1978-06-02
    • Bernard W. ConwayNelson L. FegleyJames Moran
    • Bernard W. ConwayNelson L. FegleyJames Moran
    • D21B1/12D21F1/00D21H5/18D21F11/00
    • D21F1/0018D21B1/12
    • A process of producing a uniform fiber dispersion involves the use of an in-line dispersing chamber to provide an average fiber dwell time of only about ten minutes and less. The chamber is provided with a plurality of weedless, nonthrusting impellers that generate regions of reduced pressure and flow disruptive turbulence of high intensity, the turbulence being of sufficient intensity to rapidly open fiber bundles and disperse the individual long fibers during said dwell time within said chamber. The process produces a machine-made light weight glass fiber web material of exceptionally uniform fiber distribution. The web is comprised of micron diameter glass fibers having a fiber length of about 1/4 inch or more and a basis weight of about 5-30 grams/square meter. The web material exhibits an isolated multi-fiber defect count of less than 10 per 100 square feet and a visually perceptible overall uniform fiber distribution essentially devoid of "cloud effect" fiber density variations.
    • 制造均匀的纤维分散体的方法包括使用在线分散室,以提供仅约10分钟和更短的平均纤维停留时间。 该室设置有多个无杂草的非推力叶轮,其产生具有高强度的减压和流动破坏性湍流的区域,湍流具有足够的强度以快速打开纤维束并且在所述室内的所述停留时间内分散各个长纤维 。 该工艺生产出机械制造的轻质玻璃纤维网材料,其纤维分布特别均匀。 纤维网由具有约1/4英寸或更大的纤维长度和约5-30克/平方米的基重的微米直径的玻璃纤维组成。 纤维网材料表现出小于10每100平方英尺的孤立多纤维缺陷计数,并且基本上没有“云效应”纤维密度变化的视觉上可察觉的整体均匀纤维分布。
    • 4. 发明授权
    • Highly filled sheets and method of preparation thereof
    • 高填充片材及其制备方法
    • US4225383A
    • 1980-09-30
    • US969749
    • 1978-12-14
    • Kent B. McReynolds
    • Kent B. McReynolds
    • D21H17/35D21H17/43D21H17/67D21H23/76D21H5/18
    • D21H17/67D21H17/35D21H17/43D21H17/675D21H23/765
    • A sheet which is a composite of (A) from about 1 percent to about 30 percent of a water-dispersible fiber such as wood fiber, (B) from about 2 percent to about 30 percent of a film-forming, water-insoluble, organic polymer such as a copolymer of styrene and butadiene and (C) from about 60 percent to about 95 percent of a finely-divided, substantially water-insoluble, non-fibrous, inorganic filler such as magnesium hydroxide is prepared by steps comprising:(I) providing an aqueous dispersion of the fiber;(II) mixing therewith (A) the inorganic filler and (B) the organic polymer in the form of an ionically stabilized latex;(III) colloidally destabilizing the resulting mixture to form a fibrous agglomerate in aqueous suspension;(IV) distributing and draining the aqueous dispersion on a porous substrate such as a wire to form a wet web; and(V) drying the web.
    • 作为(A)约1%至约30%的水分散性纤维如木纤维的复合材料(B),约2%至约30%的成膜水不溶性的复合材料, 有机聚合物如苯乙烯和丁二烯的共聚物和(C)约60%至约95%的细分的基本上不溶于水的非纤维状无机填料如氢氧化镁的步骤包括:( I)提供纤维的水性分散体; (II)与(A)无机填料和(B)离子稳定的胶乳形式的有机聚合物混合; (III)使所得混合物胶体化不稳定以在水悬浮液中形成纤维附聚物; (IV)将水分散体分散并排出在多孔基材如丝线上以形成湿网; 和(V)干燥纤维网。