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    • 5. 发明授权
    • Process of manufacturing solid oxygen ion conducting oxide layers
    • 制造固体氧离子传导氧化物层的工艺
    • US5989634A
    • 1999-11-23
    • US882579
    • 1997-06-25
    • Arnold O. Isenberg
    • Arnold O. Isenberg
    • C23C16/40C23C16/44
    • C23C16/4414C23C16/40C23C16/4412
    • Electrochemical vapor deposition (EVD) of oxygen ion conducting and mixed conducting, oxygen-ionic/electronic, oxide layers is achieved at near atmospheric pressure process conditions by employing metals and metal compounds for removal and/or recovery of the free halogen byproduct of the EVD reaction. The metals and metal compounds are employed as solids, vapors, and as oxides in intimate mixture with carbon directly within the deposition zone together with the substrates to be coated. The process leads to significant cost reduction, for instance, in the fabrication of thin layers of solid oxygen ion conducting electrolytes, for fuel cells, gas separators, and gas sensors, when compared to state-of-the-art EVD processes which are conducted under vacuum conditions.
    • 通过使用金属和金属化合物去除和/或回收EVD的游离卤素副产物,在接近大气压工艺条件下实现氧离子传导和混合导电氧离子/电子氧化物层的电化学气相沉积(EVD) 反应。 金属和金属化合物作为固体,蒸气和作为氧化物与碳直接与沉积区域内的碳直接与待涂覆的基底一起使用。 该过程导致显着的成本降低,例如在制造薄层的固体氧离子传导电解质,用于燃料电池,气体分离器和气体传感器时,与进行的现有技术的EVD工艺相比 在真空条件下。
    • 6. 发明授权
    • Fabrication of solid oxide fuel cell by electrochemical vapor deposition
    • 通过电化学气相沉积制备固体氧化物燃料电池
    • US4831965A
    • 1989-05-23
    • US184476
    • 1988-04-21
    • Riley BrianBernard E. Szreders
    • Riley BrianBernard E. Szreders
    • C23C16/44H01M8/12
    • C23C16/4414H01M8/12
    • In a high temperature solid oxide fuel cell (SOFC), the deposition of an impervious high density thin layer of electrically conductive interconnector material, such as magnesium doped lanthanum chromite, and of an electrolyte material, such as yttria stabilized zirconia, onto a porous support/air electrode substrate surface is carried out at high temperatures (approximately 1100.degree.-1300.degree. C.) by a process of electrochemical vapor deposition. In this process, the mixed chlorides of the specific metals involved react in the gaseous state with water vapor resulting in the deposit of an impervious thin oxide layer on the support tube/air electrode substrate of between 20-50 microns in thickness. An internal heater, such as a heat pipe, is placed within the support tube/air electrode substrate and induces a uniform temperature profile therein so as to afford precise and uniform oxide deposition kinetics in an arrangement which is particularly adapted for large scale, commercial fabrication of SOFCs.
    • 在高温固体氧化物燃料电池(SOFC)中,将诸如镁掺杂的亚铬酸镧的导电互连材料的不渗透性高密度薄层和诸如氧化钇稳定的氧化锆的电解质材料沉积到多孔载体上 /空气电极基板表面通过电化学气相沉积的方法在高温(约1100〜-1300℃)下进行。 在这个过程中,所涉及的特定金属的混合氯化物以水蒸汽在气态下反应,导致在支撑管/空气电极基底上沉积厚度在20-50微米之间的不透水薄氧化物层。 诸如热管的内部加热器被放置在支撑管/空气电极基板内并且在其中引起均匀的温度分布,从而在特别适用于大规模,商业制造的布置中提供精确和均匀的氧化物沉积动力学 的SOFCs。