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1. 发明授权

US3922322A Process for dry polymerization of olefins 失效
标题翻译：烯烃干聚合方法
公开(公告)号：US3922322A
公开(公告)日：1975-11-25
申请号：US41604573
申请日：1973-11-15
申请人： NAPHTACHIMIE SA
发明人： ROGER DORMENVAL , LASZLO HAVAS , PIERRE MANGIN
IPC分类号： C08F2/00 , B01J8/00 , B01J8/24 , C08F2/34 , C08F4/00 , C08F4/60 , C08F4/6192 , C08F10/00 , C08L23/26 , C08F255/02
CPC分类号： C08F10/00 , B01J8/0015 , Y10S526/904 , Y10S526/905 , C08F2/34 , C08F4/6292 , C08F4/69
摘要： A dry process for polymerizing olefins to produce polymers having a molecular weight above 50,000 wherein the olefin or olefins to be polymerized are circulated with hydrogen upwardly through a reaction vessel for reaction in the presence of a solid catalyst which has been separately introduced into the reaction vessel with a stream of hydrogen and in which the catalyst is formed of a catalytically active solid compound of a transition metal of sub-groups IVa, Va and VIa of the periodic table of elements, and at least one co-catalyst formed of an organometallic compound of a metal of groups II or III of the periodic table.
摘要翻译：用于聚合烯烃以生产分子量高于50,000的聚合物的干法，其中待聚合的烯烃或烯烃在氢气中向上循环通过反应容器进行反应，在固体催化剂存在下分别引入反应容器和氢气流，其中催化剂由元素周期表第IVa，Va和VIa族过渡金属的催化活性固体化合物形成，以及至少一种由有机 - 元素周期表II或III族金属的金属化合物。

2. 发明授权

US3180837A Polymerization catalyst containing polymeric diene-aluminum compounds 失效
标题翻译：含聚合二烯 - 铝化合物的聚合催化剂
公开(公告)号：US3180837A
公开(公告)日：1965-04-27
申请号：US23937762
申请日：1962-11-21
申请人： DU PONT
发明人： BRUCE JR JOHN MACMILLAN , MAXWELL ROBINSON IVAN
IPC分类号： B60L15/34 , C07F5/06 , C08F10/00 , C08F36/00
CPC分类号： C08F10/00 , B60L15/34 , C07F5/063 , C08F36/00 , C08F4/602 , C08F4/6292
摘要： Unsaturated aluminium-containing polymers containing on average 8 to 20 aluminium atoms per molecule and having the formula where R represents alkyl or alkenyl groups, X represents an alkylene group, Y represents an alkyl or alkenyl group or an p alkylene group attached to a monovalent aluminium hydrocarbon radical and n is at least 4, may be prepared by reacting an aluminium trialkyl with isoprene in an inert atmosphere until at least two-thirds but not all of the alkyl groups are displaced by isoprene and heating the reaction product in an inert atmosphere until at least 80% but not all of the isoprene is saturated. The preferred aluminium trialkyl is aluminium triisobutyl. The products may be employed with metal halides in the formation of olefin polymerization catalysts, e.g. for the polymerization of ethylene, propylene and butene-1. Specified metal halides are titanium tetrachloride, titanium trichloride, titanium tetrabromide, zirconium tetrachloride, zirconium tetrabromide, vanadium tetrachloride, vanadium trichloride and vanadium oxytrichloride. The catalysts are preferably heated, e.g. to 100 DEG to 300 DEG C., prior to or during use. Polymerization is preferably effected in the presence of an inert hydrocarbon solvent such as heptane, cyclohexane, benzene and toluene. Examples describe the preparation of an aluminium polymer by heating aluminium triisobutyl and isoprene in decahydronaphthalene in the presence of nickel acetyl acetonate and the use thereof with (I) titanium tetrachloride in the polymerization of ethylene and (II) titanium trichloride, prepared by the reduction of titanium tetrachloride with aluminium triisobutyl, in the polymerization of propylene.

3. 发明授权

US08669339B2 Polybutadiene, modified polybutadiene, method for producing both, and rubber-reinforced styrene resin composition using same 有权
标题翻译：聚丁二烯，改性聚丁二烯，二者的制造方法，以及使用其的橡胶增强苯乙烯树脂组合物
公开(公告)号：US08669339B2
公开(公告)日：2014-03-11
申请号：US13579531
申请日：2011-02-21
申请人： Yasuyoshi Okabe , Yuuji Matsudaira , Chaiyaket Vichuta , Toshiyuki Sakaguchi
发明人： Yasuyoshi Okabe , Yuuji Matsudaira , Chaiyaket Vichuta , Toshiyuki Sakaguchi
IPC分类号： C08F136/06 , C08F136/00 , C08F2/38
CPC分类号： C08C19/00 , C08F4/63908 , C08F4/63912 , C08F136/06 , C08L9/00 , C08L55/02 , C08F4/6392 , C08F4/6292
摘要： Disclosed are a polybutadiene having a controlled microstructure, a narrow molecular weight distribution, minimal gel content, and a low APHA color, a modified polybutadiene, producing methods for both, and a rubber-reinforced styrene resin composition using the same. The polybutadiene of the present invention is characterized in that the ratio (Tcp/ML1+4) of a 5% toluene melting viscosity (Tcp) measured at 25° C. and the Mooney viscosity (ML1+4) at 100° C. is 2.0 or higher, the molecular weight distribution (Mw/Mn) is 2.80 or less, the gel content is 0.06 wt % or less, and the APHA color is 20 or less.
摘要翻译：公开了具有可控微观结构，窄分子量分布，最小凝胶含量和低APHA颜色，改性聚丁二烯，二者的制备方法和使用其的橡胶增强苯乙烯树脂组合物的聚丁二烯。本发明的聚丁二烯的特征在于，在25℃下测定的5％甲苯熔融粘度（Tcp）与100℃下门尼粘度（ML1 + 4）的比例（Tcp / ML1 + 4）为 2.0以上时，分子量分布（Mw / Mn）为2.80以下，凝胶含量为0.06重量％以下，APHA颜色为20以下。

4. 发明申请

US20080021180A1 CHROMIUM CATALYSTS ACTIVE IN OLEFIN POLYMERIZATION 审中-公开
标题翻译：在烯烃聚合中活化的铬催化剂
公开(公告)号：US20080021180A1
公开(公告)日：2008-01-24
申请号：US11842323
申请日：2007-08-21
申请人： Luis Llatas , Encarna Gil , Jose Royo , Miguel Rodrigo , Ana De Lama , Montserrat Esco , Enrique Rodriguez
发明人： Luis Llatas , Encarna Gil , Jose Royo , Miguel Rodrigo , Ana De Lama , Montserrat Esco , Enrique Rodriguez
IPC分类号： C08F4/06
CPC分类号： C08F10/02 , C07F11/005 , C08F4/63904 , C08F4/63912 , C08F4/63916 , C08F4/63927 , C08F4/65927 , C08F10/00 , C08F110/02 , C08F210/16 , C08F4/6292 , C08F2500/03 , C08F2500/23 , C08F2500/02 , C08F2500/20 , C08F210/14 , C08F4/69224
摘要： The present invention relates to chromium(III) complexes defined by following formula: wherein: each R1 is independently selected from hydrogen, C1-C20 alkyl, C3-C20 cycloalkyl, C6-C20 aryl, C2-C20 alkenyl, optionally comprising 1 to 5 heteroatoms such as Si, N, P, O, F, Cl, B; each R2 is independently selected from hydrogen, C1-C20 alkyl, C3-C20 cycloalkyl, silyl, C6-C20 aryl, C2-C20 alkenyl, optionally comprising 1 to 5 heteroatoms such as Si, N, P, O, F, Cl, B; R1 and R2 can join together forming one or more aromatic or aliphatic rings optionally containing heteroatoms; each A is independently selected from nitrogen, phosphorous, As, Sb; each E is independently selected from carbon, phosphorus, nitrogen; Z is a group comprising at least a nitrogen, phosphorous, oxygen or sulfur atom which is able to coordinate to the chromium atom; Z can join one or more R2 groups to form one or more rings; each p is independently 1 or 2; each n is independently 0, 1 or 2; each X is independently an atom or group covalently or ionically attached to the chromium atom. This invention further relates to olefin polymerization catalysts obtainable by treating a chromium complex with an organoaluminium compound. The catalyst preparation and its use in polymerization are described.
摘要翻译：本发明涉及由下式定义的铬（III）络合物：其中：每个R 1独立地选自氢，C 1 -C 20， C 1 -C 6烷基，C 3 -C 20环烷基，C 6 -C 20芳基，C 1 -C 20烷基，任选地包含1至5个杂原子，例如Si，N，P，O，F，Cl，B; 每个R 2独立地选自氢，C 1 -C 20烷基，C 3 -C 20亚烷基，C 3 -C 20 > 20个环烷基，甲硅烷基，C 6 -C 20芳基，C 2 -C 20芳基，C 1 -C 20烷基，烯基，任选地包含1至5个杂原子，例如Si，N，P，O，F，Cl，B; R 1和R 2可以连接在一起形成一个或多个任选地含有杂原子的芳族或脂族环; 每个A独立地选自氮，磷，As，Sb; 每个E独立地选自碳，磷，氮; Z是至少包含能与铬原子配位的氮，磷，氧或硫原子的基团; Z可以连接一个或多个R 2 2个基团以形成一个或多个环; 每个p独立地为1或2; 每个n独立地为0,1或2; 每个X独立地是与铬原子共价或离子键连接的原子或基团。本发明还涉及通过用有机铝化合物处理铬络合物而获得的烯烃聚合催化剂。描述了催化剂制备及其在聚合中的用途。

5. 发明授权

UST951009I4 失效
公开(公告)号：UST951009I4
公开(公告)日：1976-10-05
申请号：US63266475
申请日：1975-11-17
IPC分类号： C08F2/00 , C08F4/00 , C08F4/60 , C08F4/62 , C08F4/64 , C08F4/72 , C08F10/00
CPC分类号： C08F10/00 , Y10S526/903 , C08F4/6292

6. 发明申请

US20090311453A1 Molding compostion comprsing polyethlene for preparing films and process for preparing the molding composition in the presence of a mixed catalyst 审中-公开
标题翻译：用于制备膜的聚乙烯的成型组合物和在混合催化剂存在下制备模塑组合物的方法
公开(公告)号：US20090311453A1
公开(公告)日：2009-12-17
申请号：US11919166
申请日：2006-04-15
申请人： Shahram Mihan , Dieter Lilge , Heinz Vogt , Jennifer Kipke , Rainer Karer
发明人： Shahram Mihan , Dieter Lilge , Heinz Vogt , Jennifer Kipke , Rainer Karer
IPC分类号： B32B1/02 , C08F110/02 , C08L23/06 , C08F2/00 , C07F17/00 , B01J31/12 , B29C47/00
CPC分类号： C08J5/18 , C08F4/65912 , C08F4/65925 , C08F10/00 , C08F10/02 , C08F110/02 , C08F210/16 , C08J2323/08 , C08L23/06 , C08L23/0815 , C08L2205/02 , C08L2314/04 , C08L2314/06 , Y02P20/52 , Y10T428/1352 , C08F4/69 , C08F4/025 , C08F4/65916 , C08L2666/06 , C08F2500/17 , C08F2500/12 , C08F2500/04 , C08F2500/26 , C08F2500/09 , C08F2500/18 , C08F210/14 , C08F4/6292 , C08F4/63904
摘要： Molding composition comprising polyethylene and having a density in the range from 0.915 to 0.955 g/cm, an MI in the range from 0 to 3.5 g/10 min, an MFR in the range from 5 to 50, a polydispersity Mw/Mn in the range from 5 to 20, and a z-average moiar mass Mz of less than 1 million g/mol, a process for preparing such a composition, a catalyst suitable for the preparation of the same, as well as films comprising this molding composition.
摘要翻译：包含聚乙烯并且密度在0.915至0.955g / cm 3，MI在0至3.5g / 10min范围内的MFR，5至50范围内的MFR，5分钟内的多分散性Mw / Mn 范围为5至20，z平均摩尔质量Mz小于100万g / mol，制备这种组合物的方法，适用于其制备的催化剂以及包含该模塑组合物的薄膜。

7. 发明授权

UST949006I4 失效
公开(公告)号：UST949006I4
公开(公告)日：1976-08-03
申请号：US54975075
申请日：1975-02-13
IPC分类号： C08F10/00
CPC分类号： C08F10/00 , Y10S526/911 , C08F4/6292 , C08F4/635

8. 发明授权

US3347840A Polymerization process 失效
公开(公告)号：US3347840A
公开(公告)日：1967-10-17
申请号：US37564464
申请日：1964-06-16
申请人： UNION CARBIDE CORP
发明人： MANYIK ROBERT M , WALKER WELLINGTON E , WILSON THOMAS P
IPC分类号： C08F10/00 , C08G79/10
CPC分类号： C08G79/10 , C08F10/00 , Y10S526/903 , C08F4/626 , C08F4/6028 , C08F4/6292 , C08F4/6228

9. 发明授权

US3149136A Aluminum diene polymers 失效
标题翻译：铝二烯聚合物
公开(公告)号：US3149136A
公开(公告)日：1964-09-15
申请号：US1852060
申请日：1960-03-30
申请人： DU PONT
发明人： BRUCE JR JOHN MACMILLAN , MAXWELL ROBINSON IVAN
IPC分类号： B60L15/34 , C07F5/06 , C08F10/00 , C08F36/00
CPC分类号： C08F36/00 , B60L15/34 , C07F5/063 , C08F10/00 , C08F4/6292 , C08F4/602

10. 发明申请

US20120309902A1 Polybutadiene, Modified Polybutadiene, Method for Producing Both, and Rubber-Reinforced Styrene Resin Composition Using Same 有权
标题翻译：聚丁二烯，改性聚丁二烯，二者的制造方法以及使用其的橡胶强化苯乙烯树脂组合物
公开(公告)号：US20120309902A1
公开(公告)日：2012-12-06
申请号：US13579531
申请日：2011-02-21
申请人： Yasuyoshi Okabe , Yuuji Matsudaira , Chaiyaket Vichuta , Toshiyuki Sakaguchi
发明人： Yasuyoshi Okabe , Yuuji Matsudaira , Chaiyaket Vichuta , Toshiyuki Sakaguchi
IPC分类号： C08F136/06 , C08F2/00 , C08F4/42 , C08L9/00 , C08F8/00
CPC分类号： C08C19/00 , C08F4/63908 , C08F4/63912 , C08F136/06 , C08L9/00 , C08L55/02 , C08F4/6392 , C08F4/6292
摘要： Disclosed are a polybutadiene having a controlled microstructure, a narrow molecular weight distribution, minimal gel content, and a low APHA color, a modified polybutadiene, producing methods for both, and a rubber-reinforced styrene resin composition using the same. The polybutadiene of the present invention is characterised in that the ratio (Tcp/ML1+4) of a 5% toluene melting viscosity (Tcp) measured at 25° C. and the Mooney viscosity (ML1+4) at 100° C. is 2.0 or higher, the molecular weight distribution (Mw/Mn) is 2.80 or less, the gel content is 0.06 wt % or less, and the APHA color is 20 or less.
摘要翻译：公开了具有可控微观结构，窄分子量分布，最小凝胶含量和低APHA颜色，改性聚丁二烯，二者的制备方法和使用其的橡胶增强苯乙烯树脂组合物的聚丁二烯。本发明的聚丁二烯的特征在于，在25℃下测定的5％甲苯熔融粘度（Tcp）与100℃下门尼粘度（ML1 + 4）的比例（Tcp / ML1 + 4）为 2.0以上时，分子量分布（Mw / Mn）为2.80以下，凝胶含量为0.06重量％以下，APHA颜色为20以下。

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