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    • 7. 发明授权
    • Manufacture and use of polymer modified aluminum hydroxide and basic
aluminum sulfate
    • 聚合物改性氢氧化铝和碱式硫酸铝的制造和使用
    • US4826606A
    • 1989-05-02
    • US47425
    • 1987-05-06
    • Larry W. BeckerJohn B. Lukas
    • Larry W. BeckerJohn B. Lukas
    • C01F7/00C01F7/34C01F7/74C02F1/54C02F1/56
    • C01F7/74C01F7/007C01F7/34C02F1/54C01P2002/02
    • Utilization of a cationic polymer as a settling aid in the recovery of the aluminum hydroxide and an anionic polymer to dewater the aluminum hydroxide prior to redissolution not only improves the process of making basic aluminum compounds by speeding settling and improving filterability, but also unexpectedly yields a product that has superior effectiveness as a water treatment chemical.According to the invention, a dilute solution of alum is neutralized with a base to a pH below about 6.0, preferably below 5.5, to form a suspension of aluminum hydroxide. A cationic polymer is then added to the suspension to assist in the settling of the aluminum hydroxide. When settling is substantially complete, the solution is decanted from the aluminum hydroxide and an anionic polymer is added to dewater the aluminum hydroxide. The dewatered material is collected as a filter cake containing amorphous aluminum hydroxide, the cationic polymer and the anionic polymer.The filter cake formed in this manner can be combined with aluminum sulfate or other aluminum species to form basic aluminum complexes. Surprisingly, however, the basic aluminum compounds formed from the filter cake are more effective in the reduction of water turbidity than comparable basic aluminum compounds formed without the use of the cationic and anionic polymers.
    • 利用阳离子聚合物作为沉淀助剂来回收氢氧化铝和阴离子聚合物以在再溶解之前脱水氢氧化铝不仅改善了通过加速沉降和改善过滤性而制备碱性铝化合物的方法,而且还意外地产生 作为水处理化学品具有优异的有效性的产品。 根据本发明,将明矾的稀溶液用碱中和至pH低于约6.0,优选低于5.5,以形成氢氧化铝的悬浮液。 然后将阳离子聚合物加入到悬浮液中以有助于氢氧化铝的沉降。 当沉降基本上完成时,将溶液从氢氧化铝中倾出,并加入阴离子聚合物以使氢氧化铝脱水。 收集脱水的材料作为含有无定形氢氧化铝,阳离子聚合物和阴离子聚合物的滤饼。 以这种方式形成的滤饼可以与硫酸铝或其它铝物质组合以形成碱性铝络合物。 然而,令人惊奇的是,与不使用阳离子和阴离子聚合物形成的相当的碱性铝化合物相比,由滤饼形成的碱性铝化合物在降低水浊度方面更有效。
    • 8. 发明授权
    • Process for producing a flocculating agent
    • 絮凝剂的制造方法
    • US4654201A
    • 1987-03-31
    • US797887
    • 1985-11-14
    • Olof Carlsson
    • Olof Carlsson
    • C01F7/00C02F1/52C01B17/46
    • C02F1/5245C01F7/007
    • A process of producing a flocculating agent useful for water purification technology and as a substitute for aluminium sulphate in the rosin sizing of paper is described. In this process, about 100-150 parts by weight, preferably about 130 parts by weight of hydrochloric acid, calculated as 100% HCl, and 140-200, preferably 160-190 parts by weight of a sulphate-containing, aluminium hydroxide-containing sludge, calculated on the solids content of the sludge, are mixed. To obtain the sludge, alkaline pickles used in the pickling of aluminium profiles in connection with the anodization of aluminium are neutralized with sulphuric acid or aluminium sulphate. The sludge may also contain up to about 10% by weight of aluminium hydroxide. The mixture is heated and stirred at a temperature of from about 80.degree. C. to the boiling point of the mixture, preferably 95.degree.-100.degree. C., for a combined time of about 3-15 hours, preferably about 4-6 hours. The reaction product is a substantially saturated aqueous solution of polyaluminium chloride having the presumed formulaAl.sub.a (OH).sub.b (SO.sub.4).sub.c Cl.sub.3a-b-2cwherein a, b and c may have the values 13, 34 and 1, respectively.
    • 描述了一种生产用于水净化技术的絮凝剂和用于纸松香施胶中硫酸铝的替代物的方法。 在该方法中,约100-150重量份,优选约130重量份以100%HCl计算的盐酸和140-200重量份,优选160-190重量份含硫酸氢铝氢氧化物 按污泥固体含量计算的污泥混合。 为了获得污泥,用于阳极氧化铝的铝型材酸洗中使用的碱性泡菜用硫酸或硫酸铝中和。 污泥还可以含有高达约10重量%的氢氧化铝。 将混合物在约80℃至该混合物的沸点,优选95℃-100℃的温度下加热搅拌约3-15小时,优选约4-6小时的组合时间 。 反应产物是具有假定式Ala(OH)b(SO 4)cCl 3 a-b-2c的基本饱和的聚氯化铝水溶液,其中a,b和c分别具有13,34和1的值。