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    • 3. 发明申请
    • Use Of An Ammonia Storage Device In Production Of Energy
    • 在能源生产中使用氨储存装置
    • US20070207351A1
    • 2007-09-06
    • US10593519
    • 2005-03-22
    • Claus ChristensenTue JohannessenJens NorskovUlrich Quaade
    • Claus ChristensenTue JohannessenJens NorskovUlrich Quaade
    • H01M8/04
    • C01C1/006C01F5/00C01F5/26C01P2002/72H01M8/04216H01M8/0606H01M8/22
    • An electric power generating unit comprising (i) an ammonia storage device in the form of a container comprising an ammonia absorbing and releasing salt of the general formula: Ma(NH3)nXz, wherein M is one or more cations selected from alkali metals, alkaline earth metals, and transition metals such as Li, K, Mg, Ca, V, Cr, Mn, Fe, Co, Ni, Cu or Zn, X is one or more anions selected from fluoride, chloride, bromide, iodide, nitrate, thiocyanate, sulphate, molybdate, phosphate, and chlorate ions, a is the number of cations per salt molecule, Z is the number of anions per salt molecule, and n is the coordination number of 2 to 12. (ii) means for heating said container and ammonia absorbing and releasing salt for releasing ammonia gas and (iiia) a fuel cell for converting ammonia directly into electric power; or (iiib1) a reactor for dissociating ammonia into hydrogen and nitrogen and (iiib2) a fuel cell for converting hydrogen into electric power is useful for large stationary energy producing facilities, but also for use for is useful for large stationary energy producing facilities, but also for use for small rechargeable and/or replaceable power supply units for micro-fabricated or miniaturized ammonia decomposition reactors for use in mobile units and portable devices may be used for large energy producing facilities, and by use of small rechargeable and/or replaceable ammonia storage decomposition reactors, it is also possible to provide energy for mobile units and portable devices.
    • 一种发电单元,包括(i)包含氨吸收和释放盐的容器形式的氨储存装置,其具有以下通式:Ma(NH 3)n N 其中M是选自碱金属,碱土金属和过渡金属如Li,K,Mg,Ca,V,Cr,Mn,Fe,Co中的一种或多种阳离子, Ni,Cu或Zn,X是选自氟化物,氯化物,溴化物,碘化物,硝酸盐,硫氰酸盐,硫酸盐,钼酸盐,磷酸盐和氯酸根离子中的一种或多种阴离子,a是每个盐分子的阳离子数,Z是数 的阴离子,n是2〜12的配位数。(ii)加热所述容器和氨吸收和释放氨以释放氨气的装置和(iiia)用于将氨直接转化为电力的燃料电池的装置; 或(iiib1)用于将氨离解成氢和氮的反应器和(iib2)用于将氢转化为电力的燃料电池对于大型固定能量生产设备是有用的,但也用于大型固定能量生产设施,但是 也可用于用于移动单元和便携式设备的微型或微型氨分解反应堆的小型可再充电和/或可更换电源单元,可用于大型能源生产设备,并可使用小型可再充电和/或可更换氨 存储分解反应器,还可以为移动单元和便携式设备提供能量。