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    • 10. 发明授权
    • Method for treating zinc-containing sulfate solution
    • 含硫硫酸盐溶液的处理方法
    • US5084180A
    • 1992-01-28
    • US603082
    • 1990-10-25
    • Daniel A. D. Boateng
    • Daniel A. D. Boateng
    • B01D61/24B01D61/44B01D61/58C01B17/90C02F1/469C02F9/00
    • B01D61/243B01D61/44B01D61/58C01B17/902C01B17/903C22B19/26B01D61/422Y02P10/234
    • There is provided a method for treating zinc-containing sulfate solutions which comprises an acid removal for the recovery of a substantially pure sulfuric acid solution and a solution low in acid and containing the zinc and metal impurities from the sulfate solution. The acid removal is carried out by a membrane process that consists of dialysis, electrodialysis or dialysis integrated with electrodialysis. The dialyzate or diluate is subjected to a dual-circuit, side-by-side, simultaneous solvent extraction of zinc and sulfuric acid. In one circuit sulfuric acid is extracted from the dialyzate or diluate and the raffinate from the zinc extraction with an amine-containing extractant. Acid is stripped from the loaded organic with water or an alkaline substance, and is recovered as sulfuric acid or as a sulfate, preferably as ammonium sulfate. In the other circuit, zinc is extracted from the raffinate from the acid extraction with an organic phosphoric-, phosphinic-, phosphonic- or thiophosphinic acid-containing extractant. The zinc is stripped from the loaded organic with acid, and is recovered as a concentrated zinc sulfate solution. A residual solution substantially containing the impurities is removed from the process. The extraction and stripping may be carried out in one or more stages.
    • 提供了一种处理含锌硫酸盐溶液的方法,其包括用于回收基本上纯的硫酸溶液的酸去除和酸性低的溶液,并且含有来自硫酸盐溶液的锌和金属杂质。 酸的除去是通过透析,电渗析或电透析一体化的膜工艺进行的。 透析液或稀释液经受双电路,并排的同时溶剂萃取锌和硫酸。 在一个回路中,使用含胺萃取剂从透析液中提取硫酸或从锌萃取中稀释残液和萃余液。 用水或碱性物质从负载有机物中除去酸,并以硫酸或硫酸盐的形式回收,优选硫酸铵。 在另一回路中,使用有机磷酸,次膦酸,膦酸或含次膦酸的萃取剂从萃取液中提取锌。 用酸从负载的有机物中除去锌,并以浓缩的硫酸锌溶液回收锌。 从该方法中除去基本上含有杂质的残余溶液。 萃取和汽提可以在一个或多个阶段进行。