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1. 发明授权

US11753356B2 Methods for operating ethylene oligomerization reactor systems with an integrated ultrasonic flow meter 有权
公开(公告)号：US11753356B2
公开(公告)日：2023-09-12
申请号：US18057803
申请日：2022-11-22
申请人： Chevron Phillips Chemical Company LP
发明人： Bruce E. Kreischer , Kendall M. Hurst , Eric D. Schwerdtfeger , Steven M. Bischof , Jared Fern , Kent E. Mitchell , James Hillier
IPC分类号： C07C2/32 , B01J8/10 , B01J8/18 , C12M1/34 , B01J8/00 , B01J19/00
CPC分类号： C07C2/32 , B01J8/10 , B01J8/1809 , B01J8/1854 , C12M41/30 , C12M41/32 , B01J8/001 , B01J19/0006 , B01J19/0013 , B01J2208/00548 , B01J2208/00663 , B01J8/001 , B01J19/0006 , B01J19/0013
摘要： Methods for determining ethylene concentration in an ethylene oligomerization reactor using an ultrasonic flow meter are described, and these methods are integrated into ethylene oligomerization processes and related oligomerization reactor systems.

2. 发明授权

US11682754B2 Methods and apparatuses for energy storage device electrode fabrication 有权
公开(公告)号：US11682754B2
公开(公告)日：2023-06-20
申请号：US17589697
申请日：2022-01-31
申请人： Tesla, Inc.
发明人： Porter Mitchell , Jeffrey Nelson , Robert Crawford , Mohammed-Yazid Saidi
IPC分类号： H01M4/04 , H01M4/485 , H01M4/62 , B01J2/16 , H01M4/1391 , H01M4/60 , H01M4/88 , H01M10/052 , B01J8/38 , B01J8/18 , B01J2/00 , B01J8/44 , B01J8/34 , C25D17/10
CPC分类号： H01M4/0457 , B01J2/006 , B01J2/16 , B01J8/1818 , B01J8/1854 , B01J8/34 , B01J8/386 , B01J8/44 , C25D17/10 , H01M4/0435 , H01M4/1391 , H01M4/485 , H01M4/602 , H01M4/622 , H01M4/623 , H01M4/8875 , H01M10/052
摘要： An apparatus for forming an electrode film mixture can have a first source including a polymer dispersion comprising a liquid and a polymer, a second source including a second component of the electrode film mixture, and a fluidized bed coating apparatus including a first inlet configured to receive from the first source the dispersion, and a second inlet configured to receive from the second source the second component.

3. 发明申请

US20190077727A1 Methods for the Preparation and Use of Suspensions of Chemically-Treated Solid Oxides in an Olefin-Derived Liquid Medium 审中-公开
公开(公告)号：US20190077727A1
公开(公告)日：2019-03-14
申请号：US15701577
申请日：2017-09-12
申请人： Chevron Phillips Chemical Company LP
发明人： Graham R. Lief , Eric J. Haschke , Pasquale Iacono
IPC分类号： C07C2/32 , C07C5/05 , B01J31/14 , B01J31/22 , B01J8/18 , B01J21/12
CPC分类号： C07C2/32 , B01J8/02 , B01J8/06 , B01J8/10 , B01J8/1836 , B01J8/1854 , B01J21/12 , B01J27/053 , B01J27/12 , B01J31/143 , B01J31/2295 , B01J2231/20 , B01J2531/48 , B01J2531/49 , C07C2/34 , C07C5/05 , C07C2527/12 , C07C2531/14 , C07C2531/16 , C07C2531/22 , C07C11/02
摘要： The present invention discloses processes for oligomerizing an olefin feedstock containing C4 to C20 alpha olefins using a catalyst system containing a metallocene compound, an organoaluminum compound, and a suspension of a chemically-treated solid oxide. The liquid medium for the suspension of the chemically-treated solid oxide can be an alpha-olefin oligomer product formed by the oligomerization process.

4. 发明申请

US20170320036A1 REACTOR AND MULTIFUNCTIONAL RISER AND DOWNER SIMULATOR INCORPORATING THE SAME 审中-公开
公开(公告)号：US20170320036A1
公开(公告)日：2017-11-09
申请号：US15585780
申请日：2017-05-03
申请人： THE UNIVERSITY OF WESTERN ONTARIO
发明人： Hugo de Lasa
IPC分类号： B01J8/18
CPC分类号： B01J8/1836 , B01J8/1827 , B01J8/1854 , B01J8/382 , B01J8/386 , B01J2208/00212 , B01J2208/00884 , B01J2208/00893 , B01J2208/00964 , B01J2219/00011 , G01N31/10
摘要： A reactor comprises a reactor vessel defining a confined reactor volume, a support assembly extending about a periphery of the confined reactor volume, a basket positioned within the reactor vessel and supported by the support assembly, the basket having an interior surface and an exterior surface, a downflow zone being defined between the exterior surface of the basket and an interior surface of the confined reactor volume, an inlet screen positioned adjacent to one end of the interior surface and an outlet screen positioned adjacent to an opposite end of the interior surface, an upflow zone defined between the inlet screen and outlet screen, the inlet screen and the outlet screen containing a quantity of particulate catalyst, and a circulating device positioned above said upflow zone and configured to continuously circulate fluid upwardly though said upflow zone and downwardly through said downflow zone, the support assembly and the basket configured to promote the formation of a fluid vortex within a portion of the downflow zone.

5. 发明申请

US20170120211A1 PLUG FLOW REACTOR WITH INTERNAL RECIRCULATION FLUIDIZED BED 审中-公开
公开(公告)号：US20170120211A1
公开(公告)日：2017-05-04
申请号：US15317416
申请日：2015-05-08
申请人： HATCH LTD.
发明人： Kamal Adham , Christopher Thomas Harris , Alexandre Kokourine
IPC分类号： B01J8/24 , B01J8/22 , C22B1/10 , F26B3/084 , C10B49/10 , C10B53/02 , C10B57/12 , B01J8/18 , C02F3/30
CPC分类号： B01J8/24 , B01J8/1854 , B01J8/1872 , B01J8/20 , B01J8/226 , B01J8/26 , B01J8/34 , B01J2208/00752 , B01J2208/0084 , B01J2208/00893 , B01J2208/00938 , C02F3/301 , C10B49/10 , C10B53/02 , C10B57/12 , C22B1/10 , F26B3/084 , Y02E50/14
摘要： A reactor comprises an outer sidewall and a bottom wall enclosing a hollow chamber comprising a lower fluidized bed zone and an upper freeboard zone. A plurality of inlets is provided for injecting at least one fluidizing medium into the fluidized bed zone and creating a swirling flow. At least one feed inlet communicates with the fluidized bed zone; and at least one product outlet is provided for removing a product from the chamber, the outlet(s) communicating with either the fluidized bed zone or the freeboard zone. The reactor has at least one internal barrier located inside the hollow chamber, and at least partly located in the fluidized bed zone. The internal barrier(s) have at least one opening within the fluidized bed zone, such as an underflow opening, to permit internal recirculation of material from the product zone to the feed zone, thereby simplifying reactor structure.

6. 发明授权

US08058368B1 Gas-phase polymerization of alpha-olefin 有权
标题翻译： α-烯烃的气相聚合
公开(公告)号：US08058368B1
公开(公告)日：2011-11-15
申请号：US13090973
申请日：2011-04-20
申请人： Sung Woo Kang , Nam Kyu Kim , Young Jae Jun , Man Jung Kim , Kil Su Kim
发明人： Sung Woo Kang , Nam Kyu Kim , Young Jae Jun , Man Jung Kim , Kil Su Kim
IPC分类号： C08F2/00 , C08F210/00 , C08G85/00 , B01J8/18
CPC分类号： B01J8/44 , B01J8/1827 , B01J8/1854 , B01J8/1863 , B01J2208/00274 , B01J2208/0092 , B01J2208/00929 , C08F210/16 , C08F2/34 , C08F210/14 , C08F2500/07 , C08F2500/18 , C08F2500/08
摘要： A method for preparing polyolefin from alpha-olefin with high productivity using an internal circulating fluidized bed polymerization reactor is disclosed. The method for gas-phase polymerization of alpha-olefin comprising the steps of: supplying circulation gas including one or more alpha-olefins and inert gas into a polymerization reactor; polymerizing the alpha-olefin to polyolefin in two separated polymerization areas in the polymerization reactor; and discharging produced polyolefin from the polymerization reactor. The polymerization reactor is divided into the two polymerization areas by a draft tube, and an inside of the draft tube forms a riser where growing polyolefin polymers move up in fast fluidization, and an outside of the draft tube forms an annulus where the polyolefin polymers passing the riser move down by gravity, and the polyolefin polymers passing the annulus are introduced to a lower part of the riser again, so that the polyolefin polymers are polymerized during circulating between the riser and the annulus.
摘要翻译：公开了一种使用内部循环流化床聚合反应器以高生产率从α-烯烃制备聚烯烃的方法。包括以下步骤的α-烯烃气相聚合方法：将包括一种或多种α-烯烃和惰性气体的循环气体供应到聚合反应器中; 在聚合反应器中的两个分离的聚合区域中将α-烯烃聚合成聚烯烃; 并从聚合反应器中排出生产的聚烯烃。聚合反应器通过引流管分成两个聚合区域，引流管的内部形成提升管，其中生长的聚烯烃聚合物在快速流化中向上移动，并且引流管的外部形成环状物，其中聚烯烃聚合物通过立管通过重力向下移动，并且通过环的聚烯烃聚合物再次被引入提升管的下部，使得聚烯烃聚合物在提升管和环之间循环期间聚合。

7. 发明授权

US07655822B2 Reactor with two fluidized reaction zones with an integrated gas/solid separation system 有权
标题翻译：具有两个流化反应区的反应器，其具有集成的气体/固体分离系统
公开(公告)号：US07655822B2
公开(公告)日：2010-02-02
申请号：US11641113
申请日：2006-12-19
申请人： Joseph Ross , Thierry Gauthier , Régis Andreux
发明人： Joseph Ross , Thierry Gauthier , Régis Andreux
IPC分类号： C07C1/00 , F27B15/08
CPC分类号： B01J8/1845 , B01J8/003 , B01J8/0055 , B01J8/0065 , B01J8/1809 , B01J8/1818 , B01J8/1827 , B01J8/1836 , B01J8/1854 , B01J8/1863 , B01J8/28 , B01J8/34 , B01J8/386 , B01J8/388 , B01J2208/00141 , B01J2208/00362 , B01J2208/00371 , B01J2208/00557 , B01J2208/00584 , B01J2208/0084 , B01J2208/00849 , B01J2219/00166 , B01J2219/00247 , C10G1/08 , C10G3/49 , C10G3/57 , C10G3/62 , C10G11/18 , C10G2300/1011 , C10G2300/1037 , C10G2300/708 , C10G2400/20 , Y02P30/40 , Y02P30/42 , Y02P30/446
摘要： A gas-solid reactor and method including two fluidized reaction zones having an integrated gas-solid separation system which achieves rigorously controlled residence times in the reactor.
摘要翻译：一种气固反应器和方法，包括两个具有整体气固分离系统的流化反应区，其在反应器中实现严格控制的停留时间。

8. 发明申请

US20090163756A1 Reactor cooler 审中-公开
标题翻译：反应堆冷却器
公开(公告)号：US20090163756A1
公开(公告)日：2009-06-25
申请号：US12002814
申请日：2007-12-19
申请人： Peter R. Pujado
发明人： Peter R. Pujado
IPC分类号： C07C1/00 , B01J19/00 , F28D15/00
CPC分类号： B01J8/1854 , B01J8/1836 , B01J2208/00132 , C07C1/20 , C10G2400/20 , F28D7/06 , F28D13/00 , C07C11/02
摘要： A reactor for converting a feedstream having one or more oxygenated compounds to a product containing olefins is provided. The reactor comprises a fluidized reaction zone defined by a reactor wall and a feedstream inlet located adjacent the reaction zone. The feedstream inlet is operative to feed the reaction zone with said feedstream. A riser extends from said reaction zone and carries a vaporized combination of said feedstream and said catalyst from said reaction zone to a disengaging zone fed by the riser. At least one cooling tube is disposed within the reactor and extends substantially vertically and substantially parallel to the reactor wall. The cooling tube is located adjacent the reactor wall and extends from an upper portion of the reaction zone towards a lower portion of the reaction zone. Also provided is a cooling system for a methanol to olefin reactor. Finally, a method of producing olefins from a feedstream having an oxygenate is provided. The method includes cooling the reaction which produces olefins from the oxygenate feedstream.
摘要翻译：提供了一种用于将具有一种或多种含氧化合物的进料流转化为含有烯烃的产物的反应器。反应器包括由反应器壁和邻近反应区定位的进料流入口限定的流化反应区。进料流入口可操作以与所述原料流一起进料反应区。提升管从所述反应区延伸并将所述进料流和所述催化剂的蒸发组合从所述反应区运送到由提升管供给的分离区。至少一个冷却管设置在反应器内并基本上垂直且基本平行于反应器壁延伸。冷却管位于反应器壁附近并且从反应区的上部朝向反应区的下部延伸。还提供了用于甲醇至烯烃反应器的冷却系统。最后，提供了从具有含氧化合物的原料流生产烯烃的方法。该方法包括冷却从含氧物进料流产生烯烃的反应。

9. 发明授权

US07514508B2 Process for the polymerization of ethylene 有权
标题翻译：乙烯聚合方法
公开(公告)号：US07514508B2
公开(公告)日：2009-04-07
申请号：US10568739
申请日：2004-07-19
申请人： Gerben Meier , Massimo Covezzi , Pietro Baita , Gabriele Mei
发明人： Gerben Meier , Massimo Covezzi , Pietro Baita , Gabriele Mei
IPC分类号： C08F2/38 , C08F2/34 , C08F210/02
CPC分类号： B01J8/0055 , B01J8/1854 , B01J8/24 , B01J19/2435 , B01J2208/00619 , B01J2219/00006 , B01J2219/0004 , B01J2219/00184 , C08F210/16 , C08L23/06 , C08L23/0815 , C08L2205/02 , Y10S526/905 , C08F2/34 , C08F2/001 , C08L2666/06 , C08F210/14 , C08F2500/04 , C08F2500/07 , C08F2500/12 , C08F2500/17 , C08F210/08
摘要： Process for preparing a broad molecular weight polyethylene by polymerizing ethylene in the presence of a polymerization catalyst, the process comprising the following steps, in any mutual order: a) polymerizing ethylene, optionally together with one or more α-olefinic comonomers having from 3 to 12 carbon atoms, in a gas-phase reactor in the presence of hydrogen, b) copolymerizing ethylene with one or more α-olefinic comonomers having from 3 to 12 carbon atoms in another gas-phase reactor in the presence of an amount of hydrogen less than step a), where in at least one of said gas-phase reactors the growing polymer particles flow upward through a first polymerization zone under fast fluidization or transport conditions, leave said first polymerization zone and enter a second polymerization zone through which they flow downward under the action of gravity.
摘要翻译：通过在聚合催化剂存在下聚合乙烯来制备宽分子量聚乙烯的方法，该方法包括以下步骤：a）聚合乙烯，任选地与一种或多种α-烯烃共聚单体一起聚合，所述α-烯烃共聚单体具有3〜 12个碳原子，在氢气存在下的气相反应器中，b）在另一种气相反应器中在一定量的氢气存在下使乙烯与一种或多种具有3至12个碳原子的α-烯烃共聚单体共聚其中在至少一个所述气相反应器中，生长的聚合物颗粒在快速流化或运输条件下通过第一聚合区向上流动，留下所述第一聚合区并进入第二聚合区，通过它们向下流动在重力的作用下。

10. 发明申请

US20070093621A1 Process and apparatus for the polymerization of ethylene 有权
标题翻译：用于乙烯聚合的方法和装置
公开(公告)号：US20070093621A1
公开(公告)日：2007-04-26
申请号：US10568739
申请日：2004-07-19
申请人： Gerben Meier , Massimo Covezzi , Pietro Baita , Gabriele Mei
发明人： Gerben Meier , Massimo Covezzi , Pietro Baita , Gabriele Mei
IPC分类号： C08G85/00
CPC分类号： B01J8/0055 , B01J8/1854 , B01J8/24 , B01J19/2435 , B01J2208/00619 , B01J2219/00006 , B01J2219/0004 , B01J2219/00184 , C08F210/16 , C08L23/06 , C08L23/0815 , C08L2205/02 , Y10S526/905 , C08F2/34 , C08F2/001 , C08L2666/06 , C08F210/14 , C08F2500/04 , C08F2500/07 , C08F2500/12 , C08F2500/17 , C08F210/08
摘要： Process for preparing a broad molecular weight polyethylene by polymerizing ethylene in the presence of a polymerization catalyst, the process comprising the following steps, in any mutual order: a) polymerizing ethylene, optionally together with one or more α-olefinic comonomers having from 3 to 12 carbon atoms, in a gas-phase reactor in the presence of hydrogen, b) copolymerizing ethylene with one or more α-olefinic comonomers having from 3 to 12 carbon atoms in another gas-phase reactor in the presence of an amount of hydrogen less than step a), where in at least one of said gas-phase reactors the growing polymer particles flow upward through a first polymerization zone under fast fluidization or transport conditions, leave said first polymerization zone and enter a second polymerization zone through which they flow downward under the action of gravity.
摘要翻译：通过在聚合催化剂存在下聚合乙烯来制备宽分子量聚乙烯的方法，该方法包括以下步骤：a）聚合乙烯，任选地与一种或多种α-烯烃共聚单体一起聚合，所述α-烯烃共聚单体具有3〜 12个碳原子，在氢气存在下的气相反应器中，b）在另一种气相反应器中在一定量的氢气存在下使乙烯与一种或多种具有3至12个碳原子的α-烯烃共聚单体共聚其中在至少一个所述气相反应器中，生长的聚合物颗粒在快速流化或运输条件下通过第一聚合区向上流动，留下所述第一聚合区并进入第二聚合区，通过它们向下流动在重力的作用下。

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