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    • 2. 发明授权
    • Process for preparation of thiocyanato-bearing organoalkoxysilanes
    • 含硫氰酸酯的有机烷氧基硅烷的制备方法
    • US06867319B2
    • 2005-03-15
    • US10487639
    • 2002-09-20
    • Keiji Wakita
    • Keiji Wakita
    • C07F7/18G07F7/04
    • C07F7/1892
    • A process for the preparation of (D) thiocyanato-bearing organoalkoxysilanes represented by the general formula (3) NCS—R1—Si(OR2)nR33-n wherein R1 is a divalent hydrocarbon group having 1 to 6 carbon atoms, R2 and R3 are monovalent hydrocarbon groups, and the subscript n has a value of from 0 to 3, in which (A) a thiocyanic acid salt represented by the general formula (1) MSCN, wherein M is an alkali metal and (B) a halogenated alkylalkoxysilane represented by the general formula (2) XR1Si(OR2)nR33-n wherein X is a halogen atom, and R1, R2, R3, and the subscript n are the same as above, are reacted in the presence of (C) a phase transfer catalyst.
    • 用于制备由通式(3)NCS-R 1 -Si(OR 2)n R 3-n表示的(D)含硫氰酸酯的有机烷氧基硅烷的方法,其中R 1是二价 具有1至6个碳原子的烃基,R 2和R 3是一价烃基,并且下标n具有0至3的值,其中(A)由通式表示的硫氰酸盐 (1)MSCN,其中M是碱金属和(B)由通式(2)表示的卤代烷基烷氧基硅烷XR 1 Si(OR 2)n R 3-n其中X是卤素原子 ,R 1,R 2,R 3和下标n与上述相同,在(C)相转移催化剂存在下反应。