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1. 发明公开

US20240287343A1 COLOR CHANGE MATERIALS AND COLOR-CHANGING COLORANT 审中-公开
公开(公告)号：US20240287343A1
公开(公告)日：2024-08-29
申请号：US18581699
申请日：2024-02-20
申请人： MATSUI SHIKISO CHEMICAL CO., LTD.
发明人： Yosuke KITAGAWA , Yuto SHIRAMATSU , Tomohiro MIZUHARA
IPC分类号： C09D11/50 , C09D11/033
CPC分类号： C09D11/50 , C09D11/033
摘要： Provided are color change materials and a color-changing colorant which are able to be changed in color by water or a water-containing liquid and which are effectively usable for detecting water or a water-containing liquid. One of the color change materials is a composition comprising three hydrophilic components, that are an electron-donating coloring organic compound, an electron-receiving compound, and a coloring regulator serving to inhibit the coloring attributable to both the electron-donating coloring organic compound and the electron-receiving compound, and a fixing material comprising an oleophilic fixer for fixation to a desired object, the color change material being able to be changed in color by water or a water-containing liquid. The color-changing colorant comprises a given fine object and, held or supported thereon, a color-changing composition comprising the three components and being able to be changed in color by water or a water-containing liquid, the color-changing colorant being able to be changed in color by water or a water-containing liquid. The other color change material comprises the color-changing colorant and the fixing material and is able to be changed in color by water or a water-containing liquid.

2. 发明授权

US06863720B2 Thermosensitive color-changing dry offset ink and a printed material using the same 失效
标题翻译：热敏变色干胶印油墨和使用其的印刷材料
公开(公告)号：US06863720B2
公开(公告)日：2005-03-08
申请号：US10164201
申请日：2002-06-06
申请人： Yosuke Kitagawa , Shozo Suefuku , Masaki Kariya
发明人： Yosuke Kitagawa , Shozo Suefuku , Masaki Kariya
IPC分类号： B65D23/00 , B65D25/20 , C09D11/00 , C09D11/02
CPC分类号： C09D11/50
摘要： The problem is to provide a thermosensitive color-changing dry offset ink, having no problem in an ink transferability and an excellent printing characteristics. As a thermosensitive color-changing dry offset ink is used one composed of thermosensitive, color-changing microcapsules mixed in a vehicle the capsule having two particle size characteristics of (1) particle size distribution: particles of less than 0.5 μm are contained in not less than 10 volume % and those not larger than 3.0 μm are contained in not less than 90 volume % and (2) mean particle diameter: 0.2-1.5 μm.
摘要翻译：问题在于提供一种热敏变色干胶印油墨，在油墨转印性和印刷特性方面没有问题。作为热敏变色干胶印油墨，由混合在车辆中的热敏变色微胶囊组成，具有两种粒径特征（1）粒径分布：小于0.5μm的颗粒的胶囊不少于 10体积％以上，3.0重量％以下，不小于90体积％，（2）平均粒径为0.2-1.5μm。

3. 发明授权

US4961972A Process for producing linear material 失效
标题翻译：线材生产工艺
公开(公告)号：US4961972A
公开(公告)日：1990-10-09
申请号：US018599
申请日：1987-02-25
申请人： Goro Shimizu , Masayasu Kamada , Yoshimi Hayashi
发明人： Goro Shimizu , Masayasu Kamada , Yoshimi Hayashi
IPC分类号： B29C47/02 , B29C41/14 , B29C67/00 , B29K105/00 , C09D127/04 , D06M13/02 , D06M13/152 , D06M13/224 , D06M13/236 , D06M13/322 , D06M13/325 , D06M13/335 , D06M13/402 , D06M15/248 , D06M23/00 , D06M101/00 , D06M101/16 , D06M101/18 , D06M101/30 , D06M101/32 , D06M101/34 , D06Q1/00
CPC分类号： B29C67/0007 , D06M15/248 , D06M23/00 , D06Q1/00 , B29C41/14 , Y10S428/913 , Y10T428/2933 , Y10T428/2938 , Y10T428/294 , Y10T428/2942 , Y10T428/2947 , Y10T428/2964 , Y10T428/2969 , Y10T428/2971 , Y10T428/2989 , Y10T428/2996 , Y10T428/2998
摘要： A process for producing a liner material characterized by dipping a core in the form of a monofilament or multifilament into a vinyl chloride resin sol composition having a thermochromic particulate material incorporated therein, the thermochromic particulate material being prepared by enclosing with the high polymer compound an electron-donating chromogenic substance, an electron-accepting substance for the chromogenic substance and a solvent having a boiling point of at least 150.degree. C. and selected from the group consisting of alcohols, amides, esters and azomethines and further covering the resulting product with a different high polymer compound; withdrawing the core from the sol composition; and heating the core to gel the sol composition and cover the core with the gelled composition.

4. 发明授权

US4957949A Thermochromic color masterbatch 失效
标题翻译：热变色母料
公开(公告)号：US4957949A
公开(公告)日：1990-09-18
申请号：US263755
申请日：1988-10-28
申请人： Masayasu Kamada , Toshihisa Maeda , Tadashi Kobayashi , Goro Shimizu
发明人： Masayasu Kamada , Toshihisa Maeda , Tadashi Kobayashi , Goro Shimizu
IPC分类号： C08J3/22
CPC分类号： C08J3/226 , C08J2425/00 , C08J2491/00
摘要： Disclosed is a thermochromic color masterbatch for use in a thermoplastic resin comprising a wax having substantially homogeneously dispersed therein a thermochromic granular material which is coated with a hydrophilic high-molecular weight substance, said thermochromic granular material being a mixture of a thermochromic composition comprising an electron-donating chromogen, an electron acceptor and a solvent with a thermosetting resin.
摘要翻译：公开了一种用于热塑性树脂的热致变色母料，其包含基本上均匀分散在其中的涂有亲水性高分子量物质的热变色颗粒材料的蜡，所述热变色颗粒材料是包含电子的热变色组合物的混合物电致发光体，溶剂与热固性树脂。

5. 发明申请

US20140186533A1 METHOD FOR INKJET TEXTILE PRINTING 有权
标题翻译：喷墨纺织印花方法
公开(公告)号：US20140186533A1
公开(公告)日：2014-07-03
申请号：US14141880
申请日：2013-12-27
申请人： MATSUI SHIKISO CHEMICAL CO., LTD.
发明人： Yosuke KITAGAWA , Masaki KARIYA , Daisuke INOUE
IPC分类号： D06P3/02
CPC分类号： D06P1/5285 , D06P1/6424 , D06P1/66 , D06P5/30
摘要： Method for inkjet textile printing comprising a printing step for printing an aqueous pigment ink on a specifically pretreated portion of a textile fiber product by an inkjet process, wherein said specific pretreatment is performed by applying at least: (A) a quaternary ammonium salt type cationic surfactant represented by the formula (1) below, and (B) a block isocyanate compound to the entire textile fiber product or a required portion thereof, and said aqueous pigment ink comprises at least a pigment, an aqueous liquid as a solvent or dispersion medium, and: (C) a water-soluble dispersing agent having a crosslinking property, (D) a self-emulsifying type urethane resin, and (E) a block isocyanate compound. [Two of R1 to R4: alkyl having 8 to 18 carbon atoms; the remaining two: methyl or ethyl; X−: anion.]
摘要翻译：喷墨织物印刷方法，包括通过喷墨方法在水性颜料油墨的特定预处理部分上印刷水性颜料油墨的印刷步骤，其中所述特定预处理至少应用：（A）季铵盐型阳离子由下式（1）表示的表面活性剂和（B）整个纺织纤维产品或其所需部分的嵌段异氰酸酯化合物，所述水性颜料油墨至少包含颜料，作为溶剂或分散介质的水性液体和（C）具有交联性的水溶性分散剂，（D）自乳化型聚氨酯树脂，（E）嵌段异氰酸酯化合物。 [R 2〜R 4中的2个：碳原子数8〜18的烷基] 剩下的两个：甲基或乙基; X-：阴离子]

6. 发明申请

US20120306976A1 INKJET PRINTING INK 有权
标题翻译： INKJET印刷墨水
公开(公告)号：US20120306976A1
公开(公告)日：2012-12-06
申请号：US13344725
申请日：2012-01-06
申请人： Yosuke Kitagawa , Daisuke Inoue , Hiroshi Shodai
发明人： Yosuke Kitagawa , Daisuke Inoue , Hiroshi Shodai
IPC分类号： C09D11/10 , B41J2/01
CPC分类号： C09D11/326 , D06P1/5257 , D06P1/54 , D06P5/30
摘要： An inkjet printing ink having properties of crosslinking and being fixed on a fiber by heating, characterized in that in an ink composition consisting of (A) a pigment dispersion having a mean particle diameter of 200 nm or less and a maximum particle diameter of 500 nm or less, consisting of a pigment, a water-soluble pigment dispersant and a hydrophilic solvent, (B) a water-soluble fixing agent, and (C) a crosslinking agent, the water-soluble pigment dispersant in (A) is a specific emulsion polymer neutralized by a basic substance; the water-soluble fixing agent (B) is the one having a crosslinking functional group; and the crosslinking agent (C) is the one having a functional group that crosslinks the crosslinking functional group of the water-soluble pigment dispersant in (A) with the crosslinking functional group of the water-soluble fixing agent (B) at a temperature of 100° C. or more.
摘要翻译：一种具有交联性并通过加热固定在纤维上的喷墨印刷油墨，其特征在于在由（A）平均粒径为200nm以下且最大粒径为500nm的颜料分散体组成的油墨组合物中或更少，由颜料，水溶性颜料分散剂和亲水性溶剂组成，（B）水溶性固定剂和（C）交联剂，（A）中的水溶性颜料分散剂是具体的由碱性物质中和的乳液聚合物; 水溶性固定剂（B）是具有交联官能团的固定剂; 并且交联剂（C）是具有将（A）中的水溶性颜料分散剂的交联官能团与水溶性固定剂（B）的交联官能团交联的官能团的交联剂（C）的温度为 100℃以上。

7. 发明授权

US07985797B2 Aqueous textile printing composition and continuous textile printing method of aqueous textile printing composition 有权
标题翻译：水性纺织印花组合物和连续纺织印花方法的水性纺织印花组合物
公开(公告)号：US07985797B2
公开(公告)日：2011-07-26
申请号：US11737226
申请日：2007-04-19
申请人： Yosuke Kitagawa , Osamu Sasaki , Masaki Kariya
发明人： Yosuke Kitagawa , Osamu Sasaki , Masaki Kariya
IPC分类号： C08L75/00 , C08K3/22 , C08K3/24 , D06M15/00
CPC分类号： D06P1/5271 , D06P1/5221 , D06P1/525 , D06P1/5278 , D06P1/5285 , D06P1/5292 , D06P1/642 , D06P3/82 , D06P7/00
摘要： An aqueous textile printing composition is provided having superior printing characteristics that can be used with multicolor rotating screen printing machines without causing environmental problems.
摘要翻译：提供了具有优异的印刷特性的水性纺织品印刷组合物，其可以与多色旋转丝网印刷机一起使用而不引起环境问题。

8. 发明申请

US20070050914A1 Discharge printing process of fibers dyed with indigo dye and/or sulfide dye 审中-公开
标题翻译：用靛蓝染料和/或硫化染料染色的纤维的放电印刷工艺
公开(公告)号：US20070050914A1
公开(公告)日：2007-03-08
申请号：US11445831
申请日：2006-06-01
申请人： Yosuke Kitagawa , Kenzo Nishizono
发明人： Yosuke Kitagawa , Kenzo Nishizono
IPC分类号： C11D3/00
CPC分类号： D06P5/153 , D06P1/228 , D06P1/30
摘要： The object of the invention is to provide a discharging agent for fibers dyed with an indigo dye and/or a sulfide dye, which enables stable discharge printing treatment to give the fibers soft texture, bright coloration and contours, which also enables printing. The object was achieved by the following: (1) A discharging agent for a fiber dyed with an indigo dye and/or a sulfide dye, consisting of chlorite and a viscosity-increasing nonionic surfactant, (2) a discharging agent according to the item (1), wherein the viscosity-increasing nonionic surfactant is a nonionic surfactant having HLB of 15 or higher, (3) a discharge printing process of a fabric or a sewing product dyed with an indigo dye and/or a sulfide dye, characterized in that a discharging agent having an adjusted pH of 7-12 and consisting of chlorite and a viscosity-increasing nonionic surfactant is printed on or applied to the fabric or the sewing product, followed by the application of a heat treatment, and (4) a discharge printing process according to the item (3), wherein the discharge printing treatment is performed simultaneously with, before, or after a coloring treatment.
摘要翻译：本发明的目的是提供一种用靛蓝染料和/或硫化染料染色的纤维的排出剂，其能够进行稳定的放电印刷处理，以使纤维具有柔软的质感，明亮的着色和轮廓，这也能够进行印刷。该目的通过以下方式实现：（1）用亚氯酸盐和增粘非离子表面活性剂组成的用靛蓝染料和/或硫化物染料染色的纤维的排出剂，（2）根据该项目的排出剂（1），其中增粘非离子表面活性剂为HLB为15以上的非离子表面活性剂，（3）用靛蓝染料和/或硫化染料染色的织物或缝合产品的放电印刷法，其特征在于将调整pH为7-12的由亚氯酸盐和增粘非离子表面活性剂组成的排出剂印刷在织物或缝制产品上或施加到织物或缝合产品上，然后进行热处理，和（4）根据（3）所述的放电印刷方法，其中所述放电印刷处理与着色处理同时进行，之前或之后进行。

9. 发明授权

US5208132A Photochromic materials 失效
标题翻译：光致变色材料
公开(公告)号：US5208132A
公开(公告)日：1993-05-04
申请号：US828951
申请日：1992-02-10
申请人： Masayasu Kamada , Shozo Suefuku
发明人： Masayasu Kamada , Shozo Suefuku
IPC分类号： C09K9/02 , G03C1/00 , G03C1/685
CPC分类号： G03C1/685 , G03C1/002 , Y10T428/2984
摘要： The photochromic material of the invention is such that a composition having an organic photochromic compound dissolved or dispersed in a hindered amine-type compound is microencapsulated. The photochromic material of the invention is not deteriorated in photochromic properties and can be used for a wide range of applications even when coloring or decolorizing repeatedly occurs on intermittent irradiation in air or when it is continuously irradiated with light for a long term.
摘要翻译： PCT No.PCT / JP91 / 00813 Sec。 371日期：1992年2月10日 102（e）日本1992年2月10日PCT 1991年6月18日PCT。本发明的光致变色材料是将具有溶解或分散在受阻胺型化合物中的有机光致变色化合物的组合物微胶囊化。本发明的光致变色材料在光致变色性能上不会劣化，即使当在空气中间歇照射下或长时间连续照射光时也可以重复发生着色或脱色时，可广泛应用。

10. 发明授权

US4851282A Thermochromic particle containing linear material 失效
标题翻译：含有线性材料的热变色颗粒
公开(公告)号：US4851282A
公开(公告)日：1989-07-25
申请号：US197608
申请日：1988-05-23
申请人： Goro Shimizu , Masayasu Kamada , Yoshimi Hayashi
发明人： Goro Shimizu , Masayasu Kamada , Yoshimi Hayashi
IPC分类号： B29C47/02 , B29C41/14 , B29C67/00 , B29K105/00 , C09D127/04 , D06M13/02 , D06M13/152 , D06M13/224 , D06M13/236 , D06M13/322 , D06M13/325 , D06M13/335 , D06M13/402 , D06M15/248 , D06M23/00 , D06M101/00 , D06M101/16 , D06M101/18 , D06M101/30 , D06M101/32 , D06M101/34 , D06Q1/00
CPC分类号： B29C67/0007 , D06M15/248 , D06M23/00 , D06Q1/00 , B29C41/14 , Y10S428/913 , Y10T428/2933 , Y10T428/2938 , Y10T428/294 , Y10T428/2942 , Y10T428/2947 , Y10T428/2964 , Y10T428/2969 , Y10T428/2971 , Y10T428/2989 , Y10T428/2996 , Y10T428/2998
摘要： Thermochromic particle-containing linear material product produced by the process characterized by dipping a core in the form of a monofilament or multifilament into a vinyl chloride resin sol composition having a thermochromic particulate material incorporated therein, the thermochromic particulate material being prepared by enclosing with a high polymer compound an electron-donating chromogenic substance, an electron-accepting substance for the chromogenic substance and a solvent having a boiling point of at least 150.degree. C. and selected from the group consisting of alcohols, amides, esters and azomethines and further covering the resulting product with a different high polymer compound; withdrawing the core from the sol composition; and heating the core to gel the sol composition and cover the core with the gelled composition.
摘要翻译：通过将特征在于将单丝或复丝形式的芯浸渍到其中结合有热变色颗粒材料的氯乙烯树脂溶胶组合物的方法生产的含热铬颗粒的线性材料产品，热变色颗粒材料通过以高高分子化合物，给电子显色物质，显色物质的电子接受物质和沸点至少为150℃的溶剂，选自醇，酰胺，酯和偶氮甲碱，并进一步覆盖得到的产品与不同的高分子化合物; 将核心从溶胶组合物中取出; 并加热核心以凝胶化溶胶组合物并用胶凝组合物覆盖核心。

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