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1. 发明授权

US09561483B2 Process and reactor for producing synthesis gas 有权
标题翻译：用于生产合成气的工艺和反应器
公开(公告)号：US09561483B2
公开(公告)日：2017-02-07
申请号：US14116596
申请日：2012-05-07
申请人： Matthias Mueller-Hagedorn , Katja Bartels , Frederic Judas
发明人： Matthias Mueller-Hagedorn , Katja Bartels , Frederic Judas
IPC分类号： B01J7/00 , C01B3/36 , B01J4/00 , B01J8/02 , C01B3/38 , C10J3/50
CPC分类号： B01J7/00 , B01J4/002 , B01J8/0278 , B01J8/0285 , B01J2208/00504 , C01B3/363 , C01B3/382 , C01B2203/0244 , C01B2203/025 , C10J3/506 , C10J2200/152
摘要： For producing synthesis gas by autothermal reformation of gaseous, liquid and/or solid fuels, the fuel is reacted with an oxidizing agent in a reaction space at a pressure of 10 to 120 bar and a reaction space temperature of 800 to 2,000° C. to obtain synthesis gas, wherein the oxidizing agent is introduced centrally in the upper region of the reaction space and wherein a flame is formed in the reaction space. The oxidizing agent is introduced into the reaction space separate from the fuel.
摘要翻译：为了通过气体，液体和/或固体燃料的自热改造来生产合成气，燃料与反应空间中的氧化剂在10至120巴的压力和800至2,000℃的反应空间温度下反应至获得合成气，其中氧化剂中心地引入反应空间的上部区域，并且其中在反应空间中形成火焰。将氧化剂引入到与燃料分开的反应空间中。

2. 发明授权

US09481573B2 Steam reformer based hydrogen plant scheme for enhanced carbon dioxide recovery 有权
标题翻译：基于蒸汽重整器的氢气方案，用于增强二氧化碳回收
公开(公告)号：US09481573B2
公开(公告)日：2016-11-01
申请号：US13396229
申请日：2012-02-14
申请人： Tarun D. Vakil , Ulrich Wolf
发明人： Tarun D. Vakil , Ulrich Wolf
IPC分类号： C01B3/36 , C01B3/38 , C01B3/48 , C01B3/52 , C01B3/56
CPC分类号： C01B3/382 , C01B3/384 , C01B3/48 , C01B3/52 , C01B3/56 , C01B2203/0233 , C01B2203/0283 , C01B2203/0288 , C01B2203/0405 , C01B2203/0415 , C01B2203/043 , C01B2203/0475 , C01B2203/141 , C01B2203/146 , C01B2203/147 , Y02C10/04 , Y02P20/129 , Y02P30/30
摘要： A novel steam reformer unit design, a novel hydrogen PSA unit design, a novel hydrogen/nitrogen enrichment unit design, and novel processing scheme application are presented.
摘要翻译：提出了一种新型的蒸汽重整单元设计，新型氢PSA单元设计，新型氢/氮浓缩单元设计和新型加工方案应用。

3. 发明申请

US20150076410A1 REFORMER TUBE HAVING INTERNAL HEAT EXCHANGE 有权
标题翻译：具有内部热交换器的改装管
公开(公告)号：US20150076410A1
公开(公告)日：2015-03-19
申请号：US14356608
申请日：2012-11-07
申请人： L'AIR LIQUIDE, SOCIÉTÉ ANONYME POUR L'ETUDE ET L'EXPLOITATION DES PROCÉDÉS GERGES CLAUDE , LURGI GMBH
发明人： Holger Schlichting , Ulrich Wolf , Sven Pohl , Dieter Ulber , Udo Zolnowski , Antonio Coscia , Julien Cances , Frederic Camy-Peyret , Fabrice Mathey
IPC分类号： B01J8/06 , C01B3/38 , B01J8/00
CPC分类号： B01J8/062 , B01J8/0005 , B01J8/065 , B01J8/067 , B01J2208/00141 , B01J2208/0053 , B01J2208/027 , B01J2208/065 , C01B3/384 , C01B3/388 , C01B2203/0233 , C01B2203/0816 , C01B2203/0866 , C01B2203/0883 , C01B2203/1235
摘要： A reformer tube for producing synthesis gas by steam reforming of hydrocarbon-containing feed gases, preferably natural gas, includes one or more helically coiled heat exchanger tubes which are arranged within a catalyst bed of a reforming catalyst and are helically coiled over part of their length located within the catalyst bed and are otherwise straight are present, where the straight proportion of the heat exchanger tubes and/or the helix pitch of the helically coiled part alters within the catalyst bed and matching to requirements of the pressure drop, the heat exchange properties, and the corrosion resistance.
摘要翻译：用于通过含烃进料气体（优选天然气）的蒸汽重整生产合成气的重整管包括一个或多个螺旋盘旋的热交换器管，它们布置在重整催化剂的催化剂床内，并在其一部分长度上被螺旋卷绕位于催化剂床内并且以其它方式直线存在，其中热交换器管的直线比例和/或螺旋卷绕部分的螺旋节距在催化剂床内改变并与压力降的要求相匹配，热交换性能，耐腐蚀性。

4. 发明授权

US08524922B2 Process and plant for recovering solid reaction products from solutions 有权
标题翻译：从溶液中回收固体反应产物的工艺和设备
公开(公告)号：US08524922B2
公开(公告)日：2013-09-03
申请号：US13062006
申请日：2009-08-13
申请人： Thomas Gutermuth , Robert Szabo
发明人： Thomas Gutermuth , Robert Szabo
IPC分类号： C07D307/34 , C07C51/16
CPC分类号： B01D9/0022 , B01D9/004 , C07C51/43 , C07C63/16
摘要： A process for recovering solid reaction products during partial oxidation of hydrocarbons in a liquid solvent as a reaction medium by multi-stage evaporative crystallization includes determining a final temperature of the multi-stage evaporative crystallization based on a melting point of the solvent. The pressure and temperature of the solvent is reduced in steps via successive crystallization stages until the final temperature is reached. Each of the crystallization stages includes a compressor configured to perform the reducing of the pressure and to withdraw vapors formed. The vapors from the compressor of a lower expansion pressure crystallization stage are introduced into a vapor discharge conduit of a next successive higher expansion pressure crystallization stage upstream of the compressor of the higher expansion pressure crystallization stage.
摘要翻译：在通过多级蒸发结晶作为反应介质的液体溶剂中烃的部分氧化期间回收固体反应产物的方法包括基于溶剂的熔点确定多级蒸发结晶的最终温度。溶剂的压力和温度通过连续的结晶阶段逐步降低，直到达到最终温度。每个结晶阶段包括被配置为执行压力降低并且抽出形成的蒸气的压缩机。来自较低膨胀压力结晶阶段的压缩机的蒸汽被引入到在较高膨胀压力结晶阶段的压缩机上游的下一个连续的较高膨胀压力结晶阶段的蒸气排放管道中。

5. 发明申请

US20130206577A1 PROCESS AND PLANT FOR THE DISTILLATION OF TEMPERATURE-SENSITIVE LIQUIDS 审中-公开
标题翻译：温度敏感液体蒸馏的工艺和设备
公开(公告)号：US20130206577A1
公开(公告)日：2013-08-15
申请号：US13809621
申请日：2011-06-08
申请人： Jochen Bauer , Frank Castillo-Welter , Klaus Kirsten , Markus Kreich , Christoph Steden , Dominic Walter , Rudolf Zeyen
发明人： Jochen Bauer , Frank Castillo-Welter , Klaus Kirsten , Markus Kreich , Christoph Steden , Dominic Walter , Rudolf Zeyen
IPC分类号： B01D3/26
CPC分类号： B01D3/26 , B01D3/14 , B01D5/0015 , B01D5/006 , C07C51/44 , C07C67/54 , C07C69/54 , C07C57/04
摘要： For the distillation of temperature-sensitive liquids, in particular acrylic acid and its esters, the liquid is heated in a column and at least partly evaporated. The vapor is guided through a condenser provided inside the column, in which the vapor is at least partly condensed. The condensed liquid is at least partly withdrawn from the column. The distillation is characterized in that the vapor not condensed yet is guided through the condenser cocurrently to the condensed liquid.
摘要翻译：对于温度敏感液体，特别是丙烯酸及其酯的蒸馏，将液体在塔中加热并至少部分蒸发。蒸汽被引导通过设置在塔内部的冷凝器，其中蒸气至少部分地冷凝。冷凝的液体至少部分地从塔中取出。蒸馏的特征在于未冷凝的蒸气被引导通过冷凝器并流至冷凝液体。

6. 发明申请

US20130137051A1 BURNER AND METHOD FOR PARTIALLY OXIDIZING LIQUID, CARBON-CONTAINING FUEL 审中-公开
标题翻译：用于部分氧化液体的燃烧器和方法，含碳的燃料
公开(公告)号：US20130137051A1
公开(公告)日：2013-05-30
申请号：US13639938
申请日：2011-03-24
申请人： Christoph Beyer , Lothar Brehm , Holger Schlichting , Guenter Heinz , Dieter Ulber , Jürgen Bohle
发明人： Christoph Beyer , Lothar Brehm , Holger Schlichting , Guenter Heinz , Dieter Ulber , Jürgen Bohle
IPC分类号： F23D11/00
CPC分类号： F23D11/002 , C01B3/36 , C01B3/363 , F23D11/10 , F23D11/386 , F23D2212/20 , F23D2214/00 , F23D2900/00018
摘要： A burner for the partial oxidation of liquid, carbonaceous fuel with steam and an oxygen-containing gas a well as the process in which this burner is used, wherein the parts of the outlet orifice of the burner directed towards the combustion chamber are wholly or partly provided with a coating or with a diffusion layer for protection against thermal load and/or corrosion.
摘要翻译：用于使用蒸汽和含氧气体部分氧化液体，含碳燃料的燃烧器以及使用该燃烧器的方法，其中燃烧器的出口孔部分指向燃烧室的部分全部或部分地设置有涂层或具有用于防止热负荷和/或腐蚀的扩散层。

7. 发明授权

US08444940B2 Reactor for producing C2- to C8- olefins from a material flow containing oxygenate, water vapor and one or more hydrocarbons 有权
标题翻译：用于从含有氧化物，水蒸气和一种或多种烃的物料流中生产C2-至C8-烯烃的反应器
公开(公告)号：US08444940B2
公开(公告)日：2013-05-21
申请号：US12303227
申请日：2007-04-21
申请人： Hermann Bach , Lothar Brehm , Jurgen Bohle , Gunter Quass , Gunther Heinz , Katja Bartels , Heinrich Dörr , Harald Kömpel
发明人： Hermann Bach , Lothar Brehm , Jurgen Bohle , Gunter Quass , Gunther Heinz , Katja Bartels , Heinrich Dörr , Harald Kömpel
IPC分类号： B01J8/02
CPC分类号： B01J8/0496 , B01J4/002 , B01J8/0453 , B01J8/0492 , B01J19/26 , B01J19/30 , B01J19/32 , B01J2208/00176 , B01J2208/00212 , B01J2208/00362 , B01J2208/00663 , B01J2208/00672 , B01J2208/00805 , B01J2208/00814 , B01J2208/00884 , B01J2208/025 , B01J2219/185 , B01J2219/1943 , B01J2219/30207 , B01J2219/30416 , B01J2219/32286 , C07C1/20 , C07C2529/40 , C07C2529/70 , F28D9/00 , Y02P30/42 , C07C11/06 , C07C11/02
摘要： A reactor is described for the production of C2 to C8 olefins from gaseous oxygenate and H2O and one or more material flows containing C2 C4, C5, C6, C7, C8 olefin and paraffin at 400° to 470° C., wherein several reaction stages which the material flow can pass through from the top to the bottom, each consisting of a support base with a catalyst layer situated on it, are arranged in a closed, upright container. In order to be able in each case to lower the temperature of the reaction mixture leaving the reaction stages before it enters into the next reaction stage, it is provided that each support base consists of cells which are placed closely next to each other with no gaps and which are securely attached to each other and filled with catalyst, and in the space formed by two neighboring reaction stages, respectively, an assembly of nozzle tubes is installed for spraying a liquid phase containing H2O and DME and/or MEOH, using a water-saturated gas phase containing mainly DME and/or MEOH, in the direction of the following reaction stage downstream.
摘要翻译：描述了一种用于从气态含氧化合物和H 2 O生产C 2至C 8烯烃的反应器和在400℃至470℃下含有C 2 -C 4，C 5，C 6，C 7，C 8烯烃和石蜡的一种或多种物料流，其中几个反应阶段材料流可以从顶部到底部通过，每个由位于其上的具有催化剂层的支撑基底组成，设置在封闭的直立容器中。为了能够在每种情况下降低在进入下一个反应阶段之前留下反应级的反应混合物的温度，条件是每个载体基底由彼此紧密相邻放置而没有间隙的细胞组成并且彼此牢固地连接并填充有催化剂，并且在由两个相邻反应段形成的空间中分别安装喷嘴管的组件，以使用水喷射含有H 2 O和DME和/或MEOH的液相主要含有DME和/或MEOH的饱和气相，在下游反应段的方向。

8. 发明申请

US20120141368A1 NOVEL STEAM REFORMER BASED HYDROGEN PLANT SCHEME FOR ENHANCED CARBON DIOXIDE RECOVERY 审中-公开
标题翻译：新型蒸汽改造厂基于加氢二氧化碳回收的氢气设备方案
公开(公告)号：US20120141368A1
公开(公告)日：2012-06-07
申请号：US13396229
申请日：2012-02-14
申请人： Tarun D. Vakil , Ulrich Wolf
发明人： Tarun D. Vakil , Ulrich Wolf
IPC分类号： C01B3/26
CPC分类号： C01B3/382 , C01B3/384 , C01B3/48 , C01B3/52 , C01B3/56 , C01B2203/0233 , C01B2203/0283 , C01B2203/0288 , C01B2203/0405 , C01B2203/0415 , C01B2203/043 , C01B2203/0475 , C01B2203/141 , C01B2203/146 , C01B2203/147 , Y02C10/04 , Y02P20/129 , Y02P30/30
摘要： A novel steam reformer unit design, a novel hydrogen PSA unit design, a novel hydrogen/nitrogen enrichment unit design, and novel processing scheme application are presented.
摘要翻译：提出了一种新型的蒸汽重整单元设计，新型氢PSA单元设计，新型氢/氮浓缩单元设计和新型加工方案应用。

9. 发明申请

US20120101312A1 METHOD AND SYSTEM FOR PRODUCING METHANOL AND DIMETHYL ETHER 有权
标题翻译：用于生产甲醇和二甲醚的方法和系统
公开(公告)号：US20120101312A1
公开(公告)日：2012-04-26
申请号：US13379332
申请日：2010-06-12
申请人： Bernd Ahlers , Waldemar Liebner
发明人： Bernd Ahlers , Waldemar Liebner
IPC分类号： C07C41/18 , B01J8/00
CPC分类号： C07C29/80 , C07C41/09 , C07C31/04 , C07C43/04 , C07C43/043
摘要： In the production of purified methanol and/or dimethyl ether from crude methanol, the crude methanol is processed in at least one prepurification stage, a first partial stream of the prepurified methanol is supplied to a final methanol purification and a second partial stream of the prepurified methanol is supplied to a reactor and at least partly converted to dimethyl ether. The dimethyl ether recovered is purified in at least one purification stage, wherein non-reacted methanol is withdrawn from the dimethyl ether purification stage and at least partly supplied to the final methanol purification. In this way, both purified methanol and dimethyl ether can be produced in parallel, wherein the quantities of both products obtained are flexibly adjustable.
摘要翻译：在从粗甲醇中生产纯化的甲醇和/或二甲醚的过程中，将粗甲醇在至少一个预纯化阶段进行处理，将第一部分流的预纯化甲醇供应至最终的甲醇纯化和第二部分流将甲醇供应至反应器并至少部分转化为二甲醚。回收的二甲醚在至少一个纯化阶段被纯化，其中从二甲醚纯化阶段取出未反应的甲醇，并至少部分地供应到最终的甲醇纯化。以这种方式，可以并行生产纯化的甲醇和二甲醚，其中获得的两种产物的量都是可调节的。

10. 发明申请

US20120051993A1 Mitigation System In A Steam Methane Reformer Plant 审中-公开
标题翻译：蒸汽甲烷改造厂的减排系统
公开(公告)号：US20120051993A1
公开(公告)日：2012-03-01
申请号：US12868406
申请日：2010-08-25
申请人： William D. Lindberg , Alexander Rösch , Michael B. Wakim
发明人： William D. Lindberg , Alexander Rösch , Michael B. Wakim
IPC分类号： B01D53/72
CPC分类号： C01B3/34 , C01B2203/0233 , C01B2203/0816 , C01B2203/0827 , C01B2203/148 , Y02P20/129
摘要： A method for volatile compound (VC) mitigation in a syngas production process is provided. This method includes providing a hydrocarbon reforming syngas production plant, this plant includes a reformer system comprising a primary fuel and oxidant stream, where part of this system is at low pressure, a steam inlet stream, and a primary combustion system for providing heat to the reformer system and producing a reformer flue gas stream, and a gaseous vent stream mainly composed of water and containing VC. This method also includes introducing at least a portion of the vent stream into one or more of the following: the primary fuel and oxidant stream; the steam inlet stream; the reformer flue gas stream.
摘要翻译：提供了合成气生产过程中挥发性化合物（VC）缓解方法。该方法包括提供烃重整合成气生产设备，该设备包括重整器系统，该重整器系统包括初级燃料和氧化剂流，其中该系统的一部分处于低压状态，蒸汽入口流和用于向重整器系统，生产重整器烟气，以及主要由水和VC组成的排气流。该方法还包括将排气流的至少一部分引入以下一个或多个：主燃料和氧化剂流; 蒸汽入口流; 改性烟气流。

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