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    • 3. 发明授权
    • Phosphorus-nitrogen-based intumescent flame retardant and synthetic method and use thereof
    • US10301548B2
    • 2019-05-28
    • US15032537
    • 2014-05-23
    • Institute of Advanced Technology, University of Science and Technology of China
    • Zhiyong Wang
    • C09K21/12C09D7/63D21H17/07D21H17/00D06M13/282D21H17/10D21H17/28D21H17/25D21H21/34C09D5/18C08K5/00
    • This disclosure provides high-efficiency and low-energy-consumption synthetic methods of a series of phosphorus-nitrogen-based intumescent flame retardants and the use thereof in paint flame retarding. 1 part by weight of a phosphorization agent and 0.5-4.0 parts by weight of a nitrogen-containing foaming agent are uniformly mixed and stirred at room temperature, and an amount of water is further added to emit heat and initiate reaction. 0.5-3.0 parts by weight of a charring agent and 0.5-4.0 parts by weight of a hydroxy-containing polyfuctional crosslinking agent are then added, and reacted with stirring. An amine compound is finally added for neutralization until pH value is 5-8, and solid liquid separation is performed. The solid portion is dried to obtain a main body portion of a phosphorus-nitrogen-based intumescent flame retardant. The resultant filtrate is diluted with ⅓-⅔ volume of water, and a flame retardant product is obtained. This flame retardant product is mainly used in the flame retarding of paper and cotton fabrics. The main body and different proportions of other nitrogen-containing foaming agents and charring agents are uniformly mixed and pulverized into nano- and micro-scale, and a phosphorus-nitrogen-based intumescent flame retardant is obtained. The nano- and micro-scale phosphorus-nitrogen intumescent flame retardant is mixed into a paint at a weight ratio of 15-30%, to obtain a flame-retardant paint which is capable of maintaining mechanical and physical properties of the paint. The phosphorus-nitrogen-based intumescent flame retardant of this disclosure is an intumescent flame retardant having a synergistic effect of phosphorus and nitrogen.