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    • 3. 发明授权
    • Process for the manufacture of catalysts used for producing para-xylene by toluene shape selective alkylation
    • 制备用于通过甲苯选择性烷基化生产对二甲苯的催化剂的方法
    • US07494951B2
    • 2009-02-24
    • US11503184
    • 2006-08-14
    • Zhirong ZhuDejin KongWeimin YangQingling ChenWei ZouWei LiMin HouDeqin Yang
    • Zhirong ZhuDejin KongWeimin YangQingling ChenWei ZouWei LiMin HouDeqin Yang
    • B01J29/06
    • B01J29/40B01J31/0274B01J37/0209B01J2229/12B01J2229/32B01J2229/42
    • The present invention relates to a process for the manufacture of catalysts used for producing para-xylene by toluene shape selective alkylation. The invention is primarily used for solving the problems in the old technology, e.g., high requirements on the environment and great treatment of waste water containing organic amines when synthesizing ZSM-5 molecular sieves by using an organic amine as the template agent; small and non-homogeneous particles of the molecular sieves when synthesizing ZSM-5 molecular sieves by using an alcohol or ether as the template agent, such that the catalyst prepared thereby has low catalytic selectivity and low toluene conversion rate, etc. Said problems are better solved in the present invention by synthesizing ZSM-5 molecular sieves using the combination of organic amines and alcohols or ethers as the template agents (having a weight ratio of organic amines/alcohols=0.05-150, and organic amines/ethers=0.05-150), and modifying with organosilicon so as to obtain the catalysts. Said catalysts can be used in the industrial production of para-xylene manufactured by toluene shape selective alkylation.
    • 本发明涉及制备用于通过甲苯选择性烷基化生产对二甲苯的催化剂的方法。 本发明主要用于解决老技术中的问题,例如对于通过使用有机胺作为模板剂合成ZSM-5分子筛时对环境的高要求和含有有机胺的废水的大量处理; 通过使用醇或醚作为模板剂合成ZSM-5分子筛时,分子筛的小而非均匀的颗粒,使得由此制备的催化剂具有低催化选择性和低甲苯转化率等。所述问题更好 通过使用有机胺和醇或醚的组合作为模板剂(具有有机胺/醇的重量比= 0.05-150,有机胺/醚= 0.05-150)合成ZSM-5分子筛来解决本发明 ),并用有机硅改性以获得催化剂。 所述催化剂可用于通过甲苯选择性烷基化制造的对二甲苯的工业生产。
    • 4. 发明申请
    • Process for the manufacture of catalysts used for producing para-xylene by toluene shape selective alkylation
    • 制备用于通过甲苯选择性烷基化生产对二甲苯的催化剂的方法
    • US20070037693A1
    • 2007-02-15
    • US11503184
    • 2006-08-14
    • Zhirong ZhuDejin KongWeimin YangQingling ChenWei ZouWei LiMin HouDeqin Yang
    • Zhirong ZhuDejin KongWeimin YangQingling ChenWei ZouWei LiMin HouDeqin Yang
    • B01J29/04
    • B01J29/40B01J31/0274B01J37/0209B01J2229/12B01J2229/32B01J2229/42
    • The present invention relates to a process for the manufacture of catalysts used for producing para-xylene by toluene shape selective alkylation. The invention is primarily used for solving the problems in the old technology, e.g., high requirements on the environment and great treatment of waste water containing organic amines when synthesizing ZSM-5 molecular sieves by using an organic amine as the template agent; small and non-homogeneous particles of the molecular sieves when synthesizing ZSM-5 molecular sieves by using an alcohol or ether as the template agent, such that the catalyst prepared thereby has low catalytic selectivity and low toluene conversion rate, etc. Said problems are better solved in the present invention by synthesizing ZSM-5 molecular sieves using the combination of organic amines and alcohols or ethers as the template agents (having a weight ratio of organic amines/alcohols=0.05-150, and organic amines/ethers=0.05-150), and modifying with organosilicon so as to obtain the catalysts. Said catalysts can be used in the industrial production of para-xylene manufactured by toluene shape selective alkylation.
    • 本发明涉及制备用于通过甲苯选择性烷基化生产对二甲苯的催化剂的方法。 本发明主要用于解决老技术中的问题,例如对于通过使用有机胺作为模板剂合成ZSM-5分子筛时对环境的高要求和含有有机胺的废水的大量处理; 通过使用醇或醚作为模板剂合成ZSM-5分子筛时,分子筛的小而非均匀的颗粒,使得由此制备的催化剂具有低催化选择性和低甲苯转化率等。所述问题更好 通过使用有机胺和醇或醚的组合作为模板剂(具有有机胺/醇的重量比= 0.05-150,有机胺/醚= 0.05-150)合成ZSM-5分子筛来解决本发明 ),并用有机硅改性以获得催化剂。 所述催化剂可用于通过甲苯选择性烷基化制造的对二甲苯的工业生产。