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1. 发明申请

US20120219854A1 NONAQUEOUS ELECTROLYTIC SOLUTION AND NONAQUEOUS-ELECTROLYTE BATTERY 有权
标题翻译：非电解电解液和非电解电池电池
公开(公告)号：US20120219854A1
公开(公告)日：2012-08-30
申请号：US13466621
申请日：2012-05-08
申请人： Yumiko NAKAGAWA , Minoru KOTATO , Daisuke NODA , Shinichi KINOSHITA
发明人： Yumiko NAKAGAWA , Minoru KOTATO , Daisuke NODA , Shinichi KINOSHITA
IPC分类号： H01M10/056
CPC分类号： H01M10/0567 , H01M4/131 , H01M4/133 , H01M10/0525 , H01M10/0569 , H01M2300/0042 , Y02E60/122
摘要： Disclosed is a nonaqueous electrolytic solution which enables formation of a nonaqueous-electrolyte battery having high capacity and excellent storage characteristics at high temperatures, while sufficiently enhancing safety at the time of overcharge. A nonaqueous-electrolyte battery produced by using the nonaqueous electrolytic solution is also disclosed. The nonaqueous electrolytic solution comprises an electrolyte and a nonaqueous solvent, and includes any of specific nonaqueous electrolytic solutions (A) to (D).
摘要翻译：公开了一种非水电解液，其能够在充分提高过充电时的安全性的同时，能够形成高容量，优异的高温保存特性的非水电解质电池。还公开了通过使用非水电解液制造的非水电解质电池。非水电解液包含电解质和非水溶剂，并且包括任何特定的非水电解液（A）至（D）。

2. 发明申请

US20130216918A1 NONAQUEOUS ELECTROLYTE FOR SECONDARY BATTERY AND NONAQUEOUS-ELECTROLYTE SECONDARY BATTERY EMPLOYING THE SAME 有权
公开(公告)号：US20130216918A1
公开(公告)日：2013-08-22
申请号：US13846254
申请日：2013-03-18
申请人： Hiroyuki TOKUDA , Takashi FUJII , Minoru KOTATO , Masahiro TAKEHARA , Masamichi ONUKI , Youichi OHASHI , Shinichi KINOSHITA
发明人： Hiroyuki TOKUDA , Takashi FUJII , Minoru KOTATO , Masahiro TAKEHARA , Masamichi ONUKI , Youichi OHASHI , Shinichi KINOSHITA
IPC分类号： H01M10/0569 , H01M10/052
CPC分类号： H01M10/0567 , H01M4/133 , H01M4/134 , H01M4/587 , H01M10/052 , H01M10/0525 , H01M10/056 , H01M10/0569 , H01M2300/0025 , H01M2300/004 , Y02E60/122
摘要： An object is to provide a nonaqueous electrolyte and a nonaqueous-electrolyte secondary battery which have excellent discharge load characteristics and are excellent in high-temperature storability, cycle characteristics, high capacity, continuous-charge characteristics, storability, gas evolution inhibition during continuous charge, high-current-density charge/discharge characteristics, discharge load characteristics, etc. The object has been accomplished with a nonaqueous electrolyte which comprises: a monofluorophosphate and/or a difluorophosphate; and further a compound having a specific chemical structure or specific properties.

3. 发明申请

US20120244426A1 NONAQUEOUS ELECTROLYTE SOLUTION AND LITHIUM SECONDARY BATTERY USING SAME 有权
标题翻译：非电解电解液和锂二次电池使用相同
公开(公告)号：US20120244426A1
公开(公告)日：2012-09-27
申请号：US13489038
申请日：2012-06-05
申请人： Minoru KOTATO , Kunihisa Shima , Shinichi Kinoshita , Asao Kominato , Takashi Fujii , Teppei Yamada
发明人： Minoru KOTATO , Kunihisa Shima , Shinichi Kinoshita , Asao Kominato , Takashi Fujii , Teppei Yamada
IPC分类号： H01M10/26
CPC分类号： H01M10/056 , H01M4/131 , H01M4/133 , H01M4/525 , H01M4/587 , H01M10/0525 , H01M10/0567 , H01M10/0568 , H01M2300/004 , Y02E60/122
摘要： A non-aqueous electrolyte solution is provided that realizes a large capacity, exhibits high storage characteristics and cycle characteristics, and is capable of inhibiting gas generation.The non-aqueous electrolyte solution comprises a lithium salt and a non-aqueous solvent, and further comprises: a cyclic carbonate compound having an unsaturated bond in a concentration of 0.01 weight % or higher and 8 weight % or lower; and a compound expressed by general formula (Ia) in a concentration of 0.01 weight % or higher and 5 weight % or lower. (in the formula (Ia), R11 and R12 represent, independently of each other, an organic group that is composed of one or more carbon atoms and hydrogen atoms and may optionally contain one or more oxygen atoms but excludes unsaturated bonds, provided that at least either R11 or R12 has an ether linkage. The total number of carbon atoms of R11 and R12 is between 3 and 18, and the total number of oxygen atoms contained in R11 and R12 is between 1 and 6.)
摘要翻译：提供了一种实现大容量的非水电解质溶液，具有高储存特性和循环特性，并且能够抑制气体产生。非水电解质溶液包含锂盐和非水溶剂，并且还包含：具有浓度为0.01重量％以上且8重量％以下的不饱和键的环状碳酸酯化合物; 和由通式（Ia）表示的浓度为0.01重量％以上且5重量％以下的化合物。（式（Ia）中，R 11和R 12彼此独立地表示由一个或多个碳原子和氢原子组成的有机基团，并且可以任选地含有一个或多个氧原子，但不包括不饱和键，条件是在 R11和R12中的至少一个具有醚键，R11和R12的总碳原子数在3和18之间，R11和R12中所含的氧原子总数在1和6之间）

4. 发明申请

US20120115042A1 NONAQUEOUS ELECTROLYTIC SOLUTIONS AND NONAQUEOUS-ELECTROLYTE BATTERIES 有权
标题翻译：非电解电解液和非电解电池
公开(公告)号：US20120115042A1
公开(公告)日：2012-05-10
申请号：US13353803
申请日：2012-01-19
申请人： Minoru KOTATO , Shinichi Kinoshita
发明人： Minoru KOTATO , Shinichi Kinoshita
IPC分类号： H01M10/0569
CPC分类号： H01M10/0567 , H01M6/168 , H01M10/052 , H01M10/0525 , H01M10/0566 , H01M2300/0025 , Y02E60/122
摘要： Nonaqueous electrolytes which can produce a battery of high capacity and excellent storability and cycle characteristics are provided, as are batteries produced with the electrolytes. The electrolytes include ones with (i) an aromatic compound having 7-18 carbon atoms in total and a fluorinated cyclic carbonate having two or more fluorine atoms, (ii) diethyl carbonate and a fluorinated cyclic carbonate having two or more fluorine atoms, (iii) at least one of a cyclic sulfonic acid ester compound, disulfonic acid ester compound, nitrile compound, and a compound of formula (1) and a fluorinated cyclic carbonate having two or more fluorine atoms, or (iv) a nonaqueous electrolyte solution for use in a high-voltage battery having a final charge voltage of 4.3 V or higher and having a fluorinated cyclic carbonate with two or more fluorine atoms.
摘要翻译：提供了可以生产高容量电池和优异的储存性和循环特性的非水电解质，电解质产生的电池也是如此。电解质包括（i）总共具有7-18个碳原子的芳族化合物和具有两个或更多个氟原子的氟化环状碳酸酯，（ii）碳酸二乙酯和具有两个或更多个氟原子的氟化环状碳酸酯的（i））环状磺酸酯化合物，二磺酸酯化合物，腈化合物和式（1）化合物中的至少一种和具有两个或更多个氟原子的氟化环状碳酸酯，或（iv）使用的非水电解质溶液在具有4.3V或更高的最终充电电压的高压电池中，并具有具有两个或更多个氟原子的氟化环状碳酸酯。

5. 发明申请

US20130011728A1 NONAQUEOUS ELECTROLYTE FOR SECONDARY BATTERY AND NONAQUEOUS-ELECTROLYTE SECONDARY BATTERY EMPLOYING THE SAME 有权
公开(公告)号：US20130011728A1
公开(公告)日：2013-01-10
申请号：US13619147
申请日：2012-09-14
申请人： Hiroyuki TOKUDA , Takashi FUJII , Minoru KOTATO , Masahiro TAKEHARA , Masamichi ONUKI , Youichi OHASHI , Shinichi KINOSHITA
发明人： Hiroyuki TOKUDA , Takashi FUJII , Minoru KOTATO , Masahiro TAKEHARA , Masamichi ONUKI , Youichi OHASHI , Shinichi KINOSHITA
IPC分类号： H01M10/056
CPC分类号： H01M10/0567 , H01M4/133 , H01M4/134 , H01M4/587 , H01M10/052 , H01M10/0525 , H01M10/056 , H01M10/0569 , H01M2300/0025 , H01M2300/004 , Y02E60/122
摘要： An object is to provide a nonaqueous electrolyte and a nonaqueous-electrolyte secondary battery which have excellent discharge load characteristics and are excellent in high-temperature storability, cycle characteristics, high capacity, continuous-charge characteristics, storability, gas evolution inhibition during continuous charge, high-current-density charge/discharge characteristics, discharge load characteristics, etc. The object has been accomplished with a nonaqueous electrolyte which comprises: a monofluorophosphate and/or a difluorophosphate; and further a compound having a specific chemical structure or specific properties.

6. 发明申请

US20120264010A1 NONAQUEOUS ELECTROLYTES AND NONAQUEOUS-ELECTROLYTE SECONDARY BATTERIES EMPLOYING THE SAME 有权
标题翻译：使用非电解电解质和非电解电解质二次电池
公开(公告)号：US20120264010A1
公开(公告)日：2012-10-18
申请号：US13536254
申请日：2012-06-28
申请人： Ryoichi KATO , Hiroyuki TOKUDA , Takashi FUJII , Minoru KOTATO , Masahiro TAKEHARA , Masamichi ONUKI , Youichi OHASHI , Shinichi KINOSHITA
发明人： Ryoichi KATO , Hiroyuki TOKUDA , Takashi FUJII , Minoru KOTATO , Masahiro TAKEHARA , Masamichi ONUKI , Youichi OHASHI , Shinichi KINOSHITA
IPC分类号： H01M10/056
CPC分类号： H01M10/0567 , H01M4/133 , H01M4/583 , H01M4/587 , H01M4/62 , H01M10/052 , H01M10/0525 , H01M10/0569 , H01M2300/0022 , Y02E60/122
摘要： A nonaqueous electrolyte containing a monofluorophosphate and/or a difluorophosphate and a compound having a specific chemical structure or specific properties. The nonaqueous electrolyte can contain at least one of a saturated chain hydrocarbon, a saturated cyclic hydrocarbon, an aromatic compound having a halogen atom and an ether having a fluorine atom.
摘要翻译：含有单氟磷酸盐和/或二氟磷酸盐的非水电解质和具有特定化学结构或具体特性的化合物。非水电解质可以含有饱和链烃，饱和环状烃，具有卤素原子的芳香族化合物和具有氟原子的醚中的至少一种。

7. 发明申请

US20110300453A1 NONAQUEOUS ELECTROLYTE SOLUTION AND LITHIUM SECONDARY BATTERY USING SAME 有权
公开(公告)号：US20110300453A1
公开(公告)日：2011-12-08
申请号：US13209149
申请日：2011-08-12
申请人： Minoru KOTATO , Kunihisa Shima , Shinichi Kinoshita , Asao Kominato , Takashi Fujii , Teppei Yamada
发明人： Minoru KOTATO , Kunihisa Shima , Shinichi Kinoshita , Asao Kominato , Takashi Fujii , Teppei Yamada
IPC分类号： H01M10/056
CPC分类号： H01M10/056 , H01M4/131 , H01M4/133 , H01M4/525 , H01M4/587 , H01M10/0525 , H01M10/0567 , H01M10/0568 , H01M2300/004 , Y02E60/122
摘要： A non-aqueous electrolyte solution is provided that realizes a large capacity, exhibits high storage characteristics and cycle characteristics, and is capable of inhibiting gas generation.The non-aqueous electrolyte solution comprises a lithium salt and a non-aqueous solvent, and further comprises: a cyclic carbonate compound having an unsaturated bond in a concentration of 0.01 weight % or higher and 8 weight % or lower; and a compound expressed by general formula (Ia) in a concentration of 0.01 weight % or higher and 5 weight % or lower. (in the formula (Ia), R11 and R12 represent, independently of each other, an organic group that is composed of one or more carbon atoms and hydrogen atoms and may optionally contain one or more oxygen atoms but excludes unsaturated bonds, provided that at least either R11 or R12 has an ether linkage. The total number of carbon atoms of R11 and R12 is between 3 and 18, and the total number of oxygen atoms contained in R11 and R12 is between 1 and 6.)

8. 发明申请

US20190252672A1 LITHIUM SECONDARY BATTERIES AND NONAQUEOUS ELECTROLYTE FOR USE IN THE SAME 审中-公开
公开(公告)号：US20190252672A1
公开(公告)日：2019-08-15
申请号：US16394100
申请日：2019-04-25
申请人： Hidekazu MIYAGI , Ryoichi KATO , Masakazu YOKOMIZO , Hiroyuki UONO , Hitoshi MATSUMOTO , Tomohiro SATOU , Minoru KOTATO , Takayuki NAKAJIMA , Hitoshi SUZUKI , Hiroyuki OSHIMA
发明人： Hidekazu MIYAGI , Ryoichi KATO , Masakazu YOKOMIZO , Hiroyuki UONO , Hitoshi MATSUMOTO , Tomohiro SATOU , Minoru KOTATO , Takayuki NAKAJIMA , Hitoshi SUZUKI , Hiroyuki OSHIMA
IPC分类号： H01M4/131 , B60L50/64 , H01M4/587 , H01M10/0567 , H01M10/0569 , H01M10/052 , H01M4/583 , H01M4/505 , H01M2/16 , H01M2/08 , H01M2/02 , H01M10/625 , H01M10/0525 , H01M10/0568 , H01M4/133 , H01M4/1391 , H01M4/1393 , H01M4/485 , H01M4/525 , H01M4/04 , H01M10/613
CPC分类号： H01M4/131 , B60L50/64 , H01M2/0262 , H01M2/0287 , H01M2/08 , H01M2/1673 , H01M4/0428 , H01M4/0471 , H01M4/133 , H01M4/134 , H01M4/1391 , H01M4/1393 , H01M4/364 , H01M4/485 , H01M4/505 , H01M4/525 , H01M4/583 , H01M4/587 , H01M10/052 , H01M10/0525 , H01M10/0567 , H01M10/0568 , H01M10/0569 , H01M10/0587 , H01M10/613 , H01M10/625 , H01M2004/021 , H01M2004/027 , H01M2220/20 , H01M2300/0025 , H01M2300/004 , Y02E60/122 , Y02T10/7011
摘要： Provided is a lithium secondary battery having a nonaqueous electrolyte which contains at least one compound selected from the group consisting of monofluorophosphoric acid salts, and difluorophosphoric acid salts, in an amount of 10 ppm or more of the whole nonaqueous electrolyte, and a negative electrode selected from [1], [2], [3] and [6]: [1]: a negative electrode containing two or more carbonaceous substances differing in crystallinity; [2]: a negative electrode containing an amorphous carbonaceous substance which, when examined by wide-angle X-ray diffractometry, has an interplanar spacing (d002) for the (002) planes of 0.337 nm or larger and a crystallite size (Lc) of 80 nm or smaller and which, in an examination by argon ion laser Raman spectroscopy, has a Raman. R value of 0.2 or higher defined as the ratio of the peak intensity at 1,360 cm−1 to the peak intensity at 1,580 cm−1; [3]: a negative-electrode active material a titanium-containing metal oxide capable of occluding and releasing lithium; [6]: as a negative-electrode active material, graphitic carbon particles which have a roundness of 0.85 or higher and an interplanar spacing (d002) for the (002) planes of smaller than 0.337 nm as determined by wide-angle X-ray diffractometry and which, in an examination by argon ion laser Raman spectroscopy, have a Raman R value of from 0.12 to 0.8 defined as the ratio of the peak intensity at 1,360 cm−1 to the peak intensity at 1,580 cm−1.

9. 发明申请

US20170040593A1 LITHIUM SECONDARY BATTERIES AND NONAQUEOUS ELECTROLYTE FOR USE IN THE SAME 审中-公开
标题翻译：锂二次电池和非电解电解质用于同一电池
公开(公告)号：US20170040593A1
公开(公告)日：2017-02-09
申请号：US15291314
申请日：2016-10-12
申请人： Hidekazu MIYAGI , Ryoichi KATO , Masakazu YOKOMIZO , Hiroyuki UONO , Hitoshi MATSUMOTO , Tomohiro SATOU , Minoru KOTATO , Takayuki NAKAJIMA , Hitoshi SUZUKI , Hiroyuki OSHIMA
发明人： Hidekazu MIYAGI , Ryoichi KATO , Masakazu YOKOMIZO , Hiroyuki UONO , Hitoshi MATSUMOTO , Tomohiro SATOU , Minoru KOTATO , Takayuki NAKAJIMA , Hitoshi SUZUKI , Hiroyuki OSHIMA
IPC分类号： H01M4/131 , H01M10/0568 , H01M4/133 , H01M4/04 , H01M4/1393 , H01M4/525 , H01M4/485 , H01M4/587 , H01M10/0525 , H01M4/1391
摘要： Provided is a lithium secondary battery having a nonaqueous electrolyte which contains at least one compound selected from the group consisting of monofluorophosphoric acid salts; and difluorophosphoric acid salts, in an amount of 10 ppm or more of the whole nonaqueous electrolyte, and a negative electrode selected from [1], [2], [3] and [6]: [1]: a negative electrode containing two or more carbonaceous substances differing in crystallinity; [2]: a negative electrode containing an amorphous carbonaceous substance which, when examined by wide-angle X-ray diffractometry, has an interplanar spacing (d002) for the (002) planes of 0.337 nm or larger and a crystallite size (Lc) of 80 nm or smaller and which, in an examination by argon ion laser Raman spectroscopy, has a Raman. R value of 0.2 or higher defined as the ratio of the peak intensity at 1,360 cm−1 to the peak intensity at 1,580 cm−1; [3]: a negative-electrode active material a titanium-containing metal oxide capable of occluding and releasing lithium; [6]: as a negative-electrode active material, graphitic carbon particles which have a roundness of 0.85 or higher and an interplanar spacing (d002) for the (002) planes of smaller than 0.337 nm as determined by wide-angle X-ray diffractometry and which, in an examination by argon ion laser Raman spectroscopy, have a Raman R value of from 0.12 to 0.8 defined as the ratio of the peak intensity at 1,360 cm−1 to the peak intensity at 1,580 cm−1.
摘要翻译：一种锂二次电池，包括：正极和负极，它们各自具有特定的组成和特定性能; 和含有通式（1）表示的环状硅氧烷化合物，通式（2）表示的氟硅烷化合物，通式（3）表示的化合物，分子中具有SF键的化合物，硝酸盐，亚硝酸盐，单氟磷酸盐，二氟磷酸盐，乙酸盐或丙酸盐，其量为全部非水电解质的10ppm以上。该锂二次电池具有容量大，寿命长，输出高的特点。 [通式（1）中，R 1和R 2为碳原子数1〜12的有机基团，n为3-10的整数。通式（2）中，R 3〜R 5为具有1-12个碳原子的有机基团， x是1-3的整数; 并且p，q和r各自为0-3的整数，条件是1‰p + q + r‰3.在通式（3）中，R 6至R 8为具有1-12个碳原子的有机基团符号A是由H，C，N，O，F，S，Si和/或P构成的基团。

10. 发明申请

US20150243936A1 LITHIUM SECONDARY BATTERIES AND NONAQUEOUS ELECTROLYTE FOR USE IN THE SAME 审中-公开
标题翻译：锂二次电池和非电解电解质用于同一电池
公开(公告)号：US20150243936A1
公开(公告)日：2015-08-27
申请号：US14660517
申请日：2015-03-17
申请人： Hidekazu MIYAGI , Ryoichi KATO , Masakazu YOKOMIZO , Hiroyuki UONO , Hitoshi MATSUMOTO , Tomohiro SATOU , Minoru KOTATO , Takayuki NAKAJIMA , Hitoshi SUZUKI , Hiroyuki OSHIMA
发明人： Hidekazu MIYAGI , Ryoichi KATO , Masakazu YOKOMIZO , Hiroyuki UONO , Hitoshi MATSUMOTO , Tomohiro SATOU , Minoru KOTATO , Takayuki NAKAJIMA , Hitoshi SUZUKI , Hiroyuki OSHIMA
IPC分类号： H01M2/02 , H01M10/0567 , H01M2/08 , B60L11/18 , H01M10/0587 , H01M4/583 , H01M4/505 , H01M10/0525 , H01M2/16
摘要： A lithium secondary battery comprising a battery case and an electrode group is provided. The electrode group comprises a positive electrode, a negative electrode, a microporous film separator and a nonaqueous electrolyte comprising a lithium salt. The electrode group and the nonaqueous electrolyte are held in the battery case and the electrodes each comprise a current collector and an active-material layer containing an active material capable of occluding/releasing a lithium ion. The nonaqueous electrolyte comprises a difluorophosphoric acid salt in an amount of 10 ppm or more of the whole nonaqueous electrolyte. The battery case comprises a casing material in which at least part of the battery inner side comprises a sheet formed from a thermoplastic resin and with which the electrode group can be enclosed by placing the electrode group in the casing material and heat sealing layers of the thermoplastic resin to each other.
摘要翻译：提供了包括电池壳体和电极组的锂二次电池。电极组包括正极，负极，微孔膜分离器和包含锂盐的非水电解质。电极组和非水电解质保持在电池壳体中，电极各自包含集流体和含有能够吸留/释放锂离子的活性物质的活性物质层。非水电解质包含全部非水电解质的10ppm以上的二氟磷酸盐。电池壳体包括壳体材料，其中电池内侧的至少一部分包括由热塑性树脂形成的片材，并且可以通过将电极组放置在外壳材料中并且可以封闭电极组，并且热塑性塑料的热封层树脂彼此。

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