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    • 3. 发明申请
    • CARBON PARTICLE HAVING DEPOSITED FINE PARTICLES, PROCESS FOR PRODUCING THE SAME, AND ELECTRODE FOR FUEL CELL
    • 具有沉积精细颗粒的碳颗粒,其生产方法和用于燃料电池的电极
    • US20090202869A1
    • 2009-08-13
    • US12304462
    • 2007-06-12
    • Yuko SawakiMikio KishimotoHaruyuki NakanishiShigeaki MurataMasahiro Imanishi
    • Yuko SawakiMikio KishimotoHaruyuki NakanishiShigeaki MurataMasahiro Imanishi
    • H01M4/02B05D7/24B32B5/16
    • C01G49/0054B82Y30/00C01B32/05C01G51/003C01G51/006C01P2002/34C01P2002/60C01P2002/72C01P2002/74C01P2002/80C01P2002/85C01P2004/04C01P2004/64C01P2004/80C01P2006/40H01M4/8647H01M4/885H01M4/9033H01M4/92H01M4/921H01M4/923H01M4/925H01M4/926H01M2008/1095Y10T428/2991
    • Carbon particles having fine particles deposited thereon which can be used as a substitute for the carbon particles having platinum deposited thereon and metallic platinum particles which are presently in general use as, e.g., a catalyst for electrodes in fuel cells. Compared to the conventional carbon particles having platinum deposited thereon, etc., the carbon particles are effective in greatly reducing the amount of platinum to be used. The carbon particles are characterized by comprising carbon particles and, deposited on the surface of the carbon particles, fine particles of a perovskite type composite metal oxide in each of which fine noble-metal particles are present throughout the whole particle. Also provided is a process for producing the carbon particles.The carbon particles having deposited fine particles have a constitution in which fine particles of a perovskite type composite metal oxide each having fine noble-metal particles present throughout the whole perovskite type oxide particle and having a crystallite size of 1-20 nm are deposited on carbon particles. The process for producing such carbon particles having fine particles deposited thereon comprises preparing a solution containing fine perovskite type composite oxide particles and complex ions of a metal for constituting fine noble-metal particles, subsequently repeating the step of impregnating the solution into carbon particles and dried the particles to thereby adsorb complex ions of the metal onto the carbon particles, and then subjecting the resultant particles to heat treatment.
    • 具有沉积在其上的细颗粒的碳颗粒可以用作其上沉积有铂的碳颗粒的替代物和目前通常用作燃料电池中的电极催化剂的金属铂颗粒。 与其上沉积有铂的常规碳颗粒相比,碳颗粒有效地大大降低了所用的铂的量。 碳颗粒的特征在于包含碳颗粒,并且在碳颗粒的表面上沉积有细小的贵金属颗粒存在于整个颗粒中的钙钛矿型复合金属氧化物的细颗粒。 还提供了用于生产碳颗粒的方法。 具有沉积细小颗粒的碳颗粒具有这样一种构造,即,在整个钙钛矿型氧化物颗粒中存在细小的贵金属微粒并且具有1-20nm的微晶尺寸的钙钛矿型复合金属氧化物的微粒沉积在碳上 粒子。 制备这种沉积有微细颗粒的碳颗粒的方法包括制备含有细钙钛矿型复合氧化物颗粒和用于构成细贵金属颗粒的金属的配合离子的溶液,随后重复将溶液浸渍到碳颗粒中并干燥 从而将金属的复合离子吸附到碳颗粒上,然后对所得颗粒进行热处理。
    • 5. 发明申请
    • Microparticle-Supported Carbon Particle, Method for Production Thereof, and Fuel Cell Electrode
    • 微颗粒载体碳颗粒,其制备方法和燃料电池电极
    • US20090246602A1
    • 2009-10-01
    • US11992545
    • 2006-09-25
    • Yuko SawakiYoshinori SatoMikio KishimotoHaruyuki NakanishiMasahiro Imanishi
    • Yuko SawakiYoshinori SatoMikio KishimotoHaruyuki NakanishiMasahiro Imanishi
    • H01M4/90B05D7/00H01B1/08H01B1/06
    • H01M4/8652H01M4/8842H01M4/8882H01M4/9016H01M4/9083
    • There are provided fine particle-carrying carbon particles, which can be used as a substitute for the existing platinum-carrying carbon particles or platinum metal particles commonly used in electrocatalysts for fuel cells or the like, and which are significantly reduced in the amount of platinum to be used in comparison with the existing platinum-carrying carbon particles, and an electrode for a fuel cell using the same carbon particles.The fine particle-carrying carbon particle comprises a carbon particle with an average particle diameter of from 20 to 70 nm, and fine particles of a metal oxide with an average crystallite size of from 1 to 20 nm, carried on the carbon particle, wherein the metal oxide contains a noble metal element such as a platinum element, and is represented by the formula: MOx in which the metal element M is partially substituted by the noble metal element. To manufacture such fine particle-carrying carbon particles, a solution containing complex ions of a metal which constitutes the fine metal oxide particle is firstly prepared; then, carbon particles are dispersed in the resulting solution to adsorb the complex ions of the metal onto the carbon particles; and the resulting dispersion is subjected to a hydrothermal treatment.
    • 提供了能够用于代替燃料电池等的电极催化剂中通常使用的现有的携带铂的碳粒子或铂金属粒子的微粒子载体碳粒子,其显着降低了铂 与现有的携带铂的碳颗粒相比使用,以及使用相同碳颗粒的燃料电池用电极。 所述微粒子载体碳粒子包含平均粒径为20〜70nm的碳粒子和平均微晶尺寸为1〜20nm的金属氧化物的微粒,承载在碳粒子上,其中, 金属氧化物含有贵金属元素如铂元素,并且由金属元素M部分被贵金属元素取代的式为MOx表示。 为了制造这种微粒子载体碳粒子,首先制备含有构成金属微细氧化物粒子的金属的络合离子的溶液, 然后将碳颗粒分散在所得溶液中以将金属的复合离子吸附到碳颗粒上; 并将所得分散体进行水热处理。
    • 8. 发明申请
    • Fuel Cell
    • 燃料电池
    • US20080138695A1
    • 2008-06-12
    • US11795872
    • 2006-02-03
    • Haruyuki NakanishiShigeaki MurataMasahiro ImanishiYoshihisa Tamura
    • Haruyuki NakanishiShigeaki MurataMasahiro ImanishiYoshihisa Tamura
    • H01M8/02H01M8/24
    • H01M8/0202H01M8/004H01M8/0252H01M8/0278H01M8/241H01M8/2475
    • A fuel cell comprising cell module assemblies connected in series, each of which gathers two or more cell modules comprising a hollow electrolyte membrane in which an electrode is disposed on a bore side and a shell side thereof respectively, wherein each cell module assembly comprises: a cell module array in which two or more cell modules are aligned in parallel; a partition which separates a space outside of the cell module between the open end and a body of the cell module; a bore side gas passage and a shell side gas passage provided by the partition; a current collector for positive electrode provided in the vicinity of one end of the cell module in the cell module array so that the current collector for positive electrode integrally collects power from each current collector on the positive electrode side of each cell module; a current collector for negative electrode provided in the vicinity of the other end so that the current collector for negative electrode integrally collects power from each current collector on the negative electrode side of each cell module; and a positive or negative electrode output connected with the current collector for positive or negative electrode and provided on a contacting surface of an adjacent cell module assembly; and wherein cell module assemblies are attached having the current collector of the same pole in the same direction, in which, as for adjacent cell module assemblies, the positive electrode output is arranged on the contacting surface of one cell module assembly and the negative electrode output is arranged on the contacting surface of the other cell module assembly, and the cell module assemblies are connected in series.
    • 一种燃料电池,包括串联连接的电池模块组件,每个电池模块组件分别收集两个或更多个电池模块,所述电池组件包括中空电解质膜,其中电极分别设置在孔侧和壳侧,其中每个电池模块组件包括: 单元模块阵列,其中两个或多个单元模块并行对准; 将所述单元模块外部的空间与所述单元模块的开口端和主体分开的隔板; 一个孔侧气体通道和一个壳侧气体通道,由该隔板提供; 设置在电池模块阵列中的电池模块的一端附近的正极集电体,使得正极集电体从各电池模块的正极侧的集电体一体地收集电力; 设置在另一端附近的负极用集电体,使得负极集电体从各电池模块的负极侧的集电体一体地收集电力; 以及正极或负极输出端,与用于正或负极的集电器连接并设置在相邻电池模块组件的接触表面上; 并且其中连接电池模块组件,其具有相同方向的相同磁极的集电器,其中,对于相邻的电池模块组件,正电极输出设置在一个电池模块组件的接触表面上,负电极输出 布置在另一个电池模块组件的接触表面上,并且电池模块组件串联连接。