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    • 1. 发明申请
    • EPOXY RESIN COMPOSITION FOR FIBER-REINFORCED COMPOSITE MATERIALS, PREPREG, AND FIBER-REINFORCED COMPOSITE MATERIAL
    • 纤维增强复合材料环氧树脂组合物,PREPREG和纤维增强复合材料
    • US20130281573A1
    • 2013-10-24
    • US13978738
    • 2012-01-20
    • Yuko GotoNobuyuki TomiokaYuji EchigoHiroaki SakataShiro HondaHiroshi Taiko
    • Yuko GotoNobuyuki TomiokaYuji EchigoHiroaki SakataShiro HondaHiroshi Taiko
    • C08L63/00
    • C08L63/00C08J5/24C08J2363/00C08L53/02C08L77/06
    • Provided are: a fiber-reinforced composite material which has mode I interlaminar fracture toughness, mode II interlaminar fracture toughness and compressive strength under heat and humidity conditions at the same time; an epoxy resin composition for obtaining the fiber-reinforced composite material; and a prepreg which is obtained using the epoxy resin composition. An epoxy resin composition for fiber-reinforced composite materials, which contains at least the following constituent elements (A), (B), (C) and (D). (A) An epoxy resin (B) Resin particles that satisfy the following conditions (b1)-(b3) and are insoluble in an epoxy resin (b1) The particle size distribution index is 1.0-1.8. (b2) The particle sphericity is 90 or more. (b3) The glass transition temperature of the particles is 80-180° C. (C) At least one elastomer component that is selected from among block copolymers containing a block having a glass transition temperature of 20° C. or less and rubber particles (D) An epoxy resin curing agent
    • 提供:同时在热和湿度条件下具有模式I层间断裂韧性,模式II层间断裂韧性和抗压强度的纤维增强复合材料; 用于获得纤维增强复合材料的环氧树脂组合物; 和使用该环氧树脂组合物得到的预浸料坯。 至少含有以下组成元素(A),(B),(C)和(D)的纤维增强复合材料用环氧树脂组合物。 (A)环氧树脂(B)满足以下条件(b1) - (b3)并且不溶于环氧树脂(b1)的树脂颗粒粒径分布指数为1.0-1.8。 (b2)粒子球形度为90以上。 (b3)颗粒的玻璃化转变温度为80-180℃。(C)选自含有玻璃化转变温度为20℃以下的嵌段的嵌段共聚物和橡胶粒子中的至少一种弹性体成分 (D)环氧树脂固化剂
    • 2. 发明申请
    • EPOXY RESIN COMPOSITION FOR FIBER-REINFORCED COMPOSITE MATERIAL, PREPREG, AND FIBER-REINFORCED COMPOSITE MATERIAL
    • 纤维增强复合材料环氧树脂组合物,PREPREG和纤维增强复合材料
    • US20130202873A1
    • 2013-08-08
    • US13823905
    • 2011-09-22
    • Maki MizukiYuko GotoNobuyuki TomiokaHiroaki SakataHiroshi Taiko
    • Maki MizukiYuko GotoNobuyuki TomiokaHiroaki SakataHiroshi Taiko
    • C08L63/00
    • C08L63/00C08G59/28C08G59/38C08G59/4246C08G59/5033C08G59/504C08G2261/126C08J5/24C08J2363/00C08J2433/08Y10T428/249942Y10T428/249945C08L33/08
    • Provided are a fiber-reinforced composite material excellent in heat resistance and strength properties, an epoxy resin composition to obtain the fiber-reinforced composite material, and a prepreg obtained by using the epoxy resin composition. Further provided are a fiber-reinforced composite material having less volatile matters during the curing time, and having excellent heat resistance and strength properties, an epoxy resin composition to obtain the fiber-reinforced composite material, and a prepreg obtained by using the epoxy resin composition. Provided are: an epoxy resin composition for a fiber-reinforced composite material, comprising an amine type epoxy resin [A], an aromatic amine curing agent [B], and a block copolymer [C] having a reactive group capable of reacting with an epoxy resin; a prepreg obtained by impregnating a reinforced fiber with the epoxy resin composition; and a fiber-reinforced composite material obtained by curing the prepreg. Further provided are: an epoxy resin composition comprising an epoxy resin [A] having two or more of four- or more-membered ring structures, and having either one of a glycidyl amino group directly bonded to the ring structure or a glycidyl ether group directly bonded to the ring structure, epoxy resin [B] having three or more of functional groups, a curing agent [C], and an elastomer component [D]; a prepreg obtained by impregnating a reinforced fiber with the epoxy resin composition; and a fiber-reinforced composite material obtained by curing the prepreg.
    • 提供耐热性和强度特性优异的纤维增强复合材料,获得纤维增强复合材料的环氧树脂组合物和使用该环氧树脂组合物得到的预浸料。 还提供了一种在固化时间内具有较少挥发性物质并具有优异的耐热性和强度特性的纤维增强复合材料,获得纤维增强复合材料的环氧树脂组合物和通过使用环氧树脂组合物获得的预浸料 。 提供:用于纤维增强复合材料的环氧树脂组合物,其包含胺型环氧树脂[A],芳香族胺固化剂[B]和具有能与其反应的反应性基团的嵌段共聚物[C] 环氧树脂; 通过用环氧树脂组合物浸渍增强纤维而获得的预浸料坯; 以及通过固化预浸料获得的纤维增强复合材料。 进一步提供:环氧树脂组合物,其包含具有两个或更多个四元或多元环结构的环氧树脂[A],并且直接与环结构直接键合的缩水甘油氨基或缩水甘油醚基团中的任一个 结合到环结构上,具有三个或更多个官能团的环氧树脂[B],固化剂[C]和弹性体组分[D]; 通过用环氧树脂组合物浸渍增强纤维而获得的预浸料坯; 以及通过固化预浸料获得的纤维增强复合材料。
    • 5. 发明授权
    • Epoxy resins, curing agent and (Co)poly(methyl methacrylate) block copolymer
    • 环氧树脂,固化剂和(Co)聚(甲基丙烯酸甲酯)嵌段共聚物
    • US08338535B2
    • 2012-12-25
    • US12306629
    • 2007-06-25
    • Hiroaki SakataNobuyuki TomiokaShiro Honda
    • Hiroaki SakataNobuyuki TomiokaShiro Honda
    • B29D23/00B32B1/08B32B27/04B32B27/12C08L63/02
    • C08J5/24C08J2363/00C08L53/00C08L63/00Y10T428/1372Y10T428/24994Y10T428/24995C08L2666/22
    • The present invention relates to an epoxy resin composition comprising the following [A], [A′], [B], and [C]: [A] a bisphenol-type epoxy resin having a glass transition temperature or melting point of 50° C. or higher; [A′] an epoxy resin which is in a liquid state at 25° C.; [B] an epoxy resin curing agent; and [C] at least one block copolymer selected from the group consisting of S-B-M, B-M, and M-B-M, wherein the blocks are linked to each other by a covalent bond or by an intermediate molecule bound to one of the blocks via one covalent bond formation and to the other block via another covalent bond formation; the block M is a methyl methacrylate homopolymer or a copolymer comprising at least 50% by weight of methyl methacrylate; the block B is incompatible with the block M and has a glass transition temperature of 20° C. or lower; and the block S is incompatible with the blocks B and M and has a glass transition temperature higher than that of the block B, a prepreg obtained by impregnating a fiber base with the epoxy resin composition, and a fiber-reinforced composite material obtained by curing the prepreg.
    • 本发明涉及包含以下[A],[A'],[B]和[C]的环氧树脂组合物:[A]玻璃化转变温度或熔点为50℃的双酚型环氧树脂 C.或更高; [A']在25℃处于液态的环氧树脂; [B]环氧树脂固化剂; 和[C]选自SBM,BM和MBM的至少一种嵌段共聚物,其中所述嵌段通过共价键彼此连接或通过经由一个共价键形成与一个嵌段结合的中间分子连接 并通过另一个共价键形成另一个嵌段; 嵌段M是甲基丙烯酸甲酯均聚物或包含至少50重量%甲基丙烯酸甲酯的共聚物; 块B与块M不相容,玻璃化转变温度为20℃以下; 并且块S与块B和M不相容,玻璃化转变温度高于块B,玻璃化转变温度高于通过用环氧树脂组合物浸渍纤维基材获得的预浸料,以及通过固化获得的纤维增强复合材料 预浸料
    • 6. 发明申请
    • EPOXY RESIN COMPOSITION, PREPREG, AND FIBER-REINFORCED COMPOSITE MATERIAL
    • 环氧树脂组合物,PREPREG和纤维增强复合材料
    • US20090198012A1
    • 2009-08-06
    • US12306629
    • 2007-06-25
    • Hiroaki SakataNobuyuki TomiokaShiro Honda
    • Hiroaki SakataNobuyuki TomiokaShiro Honda
    • C08L77/00C08G18/62
    • C08J5/24C08J2363/00C08L53/00C08L63/00Y10T428/1372Y10T428/24994Y10T428/24995C08L2666/22
    • The present invention relates to an epoxy resin composition comprising the following [A], [A′], [B], and [C]: [A] a bisphenol-type epoxy resin having a glass transition temperature or melting point of 50° C. or higher; [A′] an epoxy resin which is in a liquid state at 25° C.; [B] an epoxy resin curing agent; and [C] at least one block copolymer selected from the group consisting of S-B-M, B-M, and M-B-M, wherein the blocks are linked to each other by a covalent bond or by an intermediate molecule bound to one of the blocks via one covalent bond formation and to the other block via another covalent bond formation; the block M is a methyl methacrylate homopolymer or a copolymer comprising at least 50% by weight of methyl methacrylate; the block B is incompatible with the block M and has a glass transition temperature of 20° C. or lower; and the block S is incompatible with the blocks B and M and has a glass transition temperature higher than that of the block B, a prepreg obtained by impregnating a fiber base with the epoxy resin composition, and a fiber-reinforced composite material obtained by curing the prepreg.
    • 本发明涉及包含以下[A],[A'],[B]和[C]的环氧树脂组合物:[A]玻璃化转变温度或熔点为50℃的双酚型环氧树脂 C.或更高; [A']在25℃处于液态的环氧树脂; [B]环氧树脂固化剂; 和[C]选自SBM,BM和MBM的至少一种嵌段共聚物,其中所述嵌段通过共价键彼此连接或通过经由一个共价键形成与一个嵌段结合的中间分子连接 并通过另一个共价键形成另一个嵌段; 嵌段M是甲基丙烯酸甲酯均聚物或包含至少50重量%甲基丙烯酸甲酯的共聚物; 块B与块M不相容,玻璃化转变温度为20℃以下; 并且块S与块B和M不相容,玻璃化转变温度高于块B,玻璃化转变温度高于通过用环氧树脂组合物浸渍纤维基材获得的预浸料,以及通过固化获得的纤维增强复合材料 预浸料