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    • 2. 发明授权
    • Microporous membrane and process for the production thereof
    • 微孔膜及其生产方法
    • US6126825A
    • 2000-10-03
    • US126713
    • 1998-07-31
    • Yukio ShinagawaSumio Ohtani
    • Yukio ShinagawaSumio Ohtani
    • B01D67/00B01D71/44C08G61/06B01D39/14
    • C08G61/06B01D67/0027B01D67/003B01D71/44B01D2325/30
    • The present invention relates to a microporous membrane and a process for producing thereof, especially a microporous membrane which can be used for microfiltration, has excellent resistance to chemicals, and a process for producing thereof.The present invention provides a microporous membrane having excellent resistance to chemicals, and a microporous membrane which facilitates waste disposal, and a process for producing thereof.The microporous membrane has a bubble point value measured by the use of ethanol (by the test method of JIS K3832) falling in the range of from 10 kPa to 1000 kPa and comprises a polymer prepared by ring opening polymerization of a compound represented by chemical formula (I) or a polymer which is a ring opening polymer or ring opening copolymer represented by chemical formula (II). An example of the ring opening ring polymer or ring opening copolymer is a norbornene resin.The process for producing the microporous membrane is as follows: A polymer prepared by ring opening polymerization of a compound represented by chemical formula (I) is heated and dissolved in a solvent (a) in which the polymer is soluble, and casted to form a solution membrane, which is rapidly cooled, and extracted with a washing solvent (b) in which the polymer is insoluble to remove the solvent (a), whereby the microporous membrane having a bubble point value measured by the use of ethanol (by the test method of JIS K3832) falling in the range from 10 kPa to 1000 kPa is obtained.
    • 本发明涉及微多孔膜及其制造方法,特别是可用于微量过滤的微多孔膜,其耐化学性优异,其制造方法。 本发明提供了具有优异的抗化学药品性的微多孔膜和便于废物处理的微多孔膜及其制造方法。 微孔膜具有通过使用乙醇(通过JIS K3832的测试方法)测量的起泡点值,其范围为10kPa至1000kPa,并且包含通过化学式表示的化合物的开环聚合制备的聚合物 (I)或由化学式(II)表示的开环聚合物或开环共聚物的聚合物。 开环聚合物或开环共聚物的实例是降冰片烯树脂。 制造微多孔膜的方法如下:将由化学式(I)表示的化合物的开环聚合制备的聚合物加热溶解在聚合物可溶的溶剂(a)中,并浇铸形成 溶液膜快速冷却,并用其中不溶聚合物的洗涤溶剂(b)萃取以除去溶剂(a),由此通过使用乙醇测定具有起泡点值的微孔膜(通过试验 获得了从10kPa到1000kPa的范围内的JIS K3832的方法。
    • 3. 发明授权
    • Fine porous membrane and process for producing the same
    • 细多孔膜及其制造方法
    • US4840733A
    • 1989-06-20
    • US127304
    • 1987-12-02
    • Jun SasakiAtsushi AdachiKyoichi NaruoYukio ShinagawaSumio Ohtani
    • Jun SasakiAtsushi AdachiKyoichi NaruoYukio ShinagawaSumio Ohtani
    • B01D67/00B01D69/02B01D69/06
    • B01D69/06B01D67/0009B01D67/0013B01D67/0016B01D69/02B01D2323/08B01D2323/12B01D2325/022
    • A fine porous membrane having a pore size distribution in the thickness direction and having a layer having a minimum pore size in the interior thereof, wherein the ratio of maximum pore size to the average pore size, each as determined according to ASTM-316-80, is not more than 1.8. The fine porous membrane is produced by a process comprising casting a film-forming solution, comprising a polymer in a solvent having incorporated therein a swelling agent and a non-solvent, on a casting carrier while being in a solution state, directing air having a temperature of from 15.degree. to 60.degree. C. and a relative humidity of from 10 to 80% onto the surface of the cast film at a velocity of from 0.2 to 4 m/sec for a period of from 2 to 17 seconds to cause coacervation of the cast film while controlling the evaporation loss of the solvent from the cast film and the absorption of non-solvent vapors in the air, dipping the case film in a coagulating bath to cause phase separation and coagulation to form a fine porous membrane, and stripping off the membrane from the casting carrier. The fine porous membranes has a low filtration resistance, a great filtration flow rate, a high efficiency in trapping fine particles and bacteria, and a long life.
    • 一种细孔多孔膜,其在厚度方向上具有孔径分布,并且在其内部具有最小孔径的层,其中最大孔径与平均孔径的比值各自根据ASTM-316-80测定 ,不超过1.8。 微细多孔膜是通过以下方法生产的,该方法包括在处于溶液状态的流延载体上将含有溶剂的溶剂中包含聚合物的成膜溶液浇铸在溶液中,引导具有 温度为15〜60℃,相对湿度为10〜80%,以0.2〜4m /秒的速度在流延膜的表面上进行2〜17秒的时间,使凝聚 的流延膜,同时控制溶剂从流延膜的蒸发损失和非溶剂蒸气在空气中的吸收,将壳膜浸入凝固浴中以引起相分离和凝结以形成细多孔膜,以及 从铸造载体剥离膜。 细多孔膜具有低的过滤阻力,大的过滤流速,捕获细颗粒和细菌的高效率和长寿命。
    • 9. 发明授权
    • Filtration system
    • 过滤系统
    • US5221479A
    • 1993-06-22
    • US834801
    • 1992-02-13
    • Masahiro EtohSumio Ohtani
    • Masahiro EtohSumio Ohtani
    • B01D61/14B01D65/02C12H1/07C12N1/02
    • B01D61/147B01D65/02C12H1/063C12N1/02B01D2321/04
    • A dead-end type filtration system wherein a bulk (or bulk suspension) comprising a fluid containing suspended matters is filtered through a micro-filter membrane to separate the fluid form the suspended matters, back wash is periodically carried out under such conditions that pressure on the transmitted fluid side of the filter membrane is higher than pressure on the bulk side thereof, and back wash liquid together with the suspended matters desorbed form the liter membrane is discharged from the filtration system to the outside, characterized by that said filter membrane has an anisotropic structure where the pore diameters of the filter membrane are changed continuously or discontinuously in the thickness direction of the filter membrane, and the pore diameters on one side of the filter membrane are different from those on other side thereof.
    • 一种死端型过滤系统,其中包含含有悬浮物质的流体的本体(或本体悬浮液)通过微过滤膜过滤以从悬浮物中分离出流体,反冲洗在这样的条件下周期性地进行: 过滤膜的透过流体侧高于其主体侧的压力,并且从清洗膜离开的悬浮物与反洗液一起从过滤系统排出到外部,其特征在于,所述过滤膜具有 过滤膜的孔径在过滤膜的厚度方向上连续或不连续地变化,并且过滤膜一侧的孔径与其另一侧的孔径不同的各向异性结构。